gajanan Muley - Academia.edu (original) (raw)
Papers by gajanan Muley
Indian Journal of Physics
Department of Physics, Acharya Marathe College, Chembur, Mumbai-400 071, India Department of Phys... more Department of Physics, Acharya Marathe College, Chembur, Mumbai-400 071, India Department of Physics, Siddharth College of ASC, Fort, Mumbai-400 023, India Department of Chemistry, Anand College, Pathardi, Ahamednagar-414 102, Maharashtra, India Department of Chemical Technology, Sant Gadge Baba Amravati University, Amravati-444 602, Maharashtra, India Department of Physics, Shri R. R. Lahoti Science College, Morshi, Amravati-444 905, Maharashtra, India Department of Physics, Sant Gadge Baba Amravati University, Amravati-444 602, Maharashtra, India E-mail : gajananggm@yahoo.co.in <strong>CdS</strong> nanoparticles passivated with amino acid L-alanine having spherical hierarchical morphology were synthesized by low temperature wet chemical method. The synthesized nanoparticles were characterized by <strong>UV</strong>-<strong>V</strong>isible spectroscopy to know the variation of band gaps with concentration of surface modifying agents. Indeed, blu...
In this study, silver nanoparticles were synthesized using sodium borohydride (NaBH4) as a reduci... more In this study, silver nanoparticles were synthesized using sodium borohydride (NaBH4) as a reducing agent at different concentrations (1 wt %, 2 wt %, 5 wt %) of poly N-vinylpyrrolidone (PVP) as a stabilizing agent by chemical reduction method.The reaction was carried at room temperature. Resulting nano-sized colloids have been characterized by FT-IR spectroscopy, UV-Visible spectroscopy, X-ray diffraction, and Transmission Electron Microscopy (TEM). Very strong surface Plasmon resonance peak at 410 nm in the UV-Visible is a direct evidence of formation of nano-sized silver colloids. XRD Diffraction pattern reveals the formation of cubic structured crystals.Transmission Electron Microscopy (TEM) confirms average diameter of silver nanoparticles as 9 nm. The non-linear refractive index ( 2) were calculated by Z-Scan technique using CW He-Ne laser (λ=632 nm)and are obtained as high as 3.353 x 10 4 cm 2 /W,8.697 x 10 4 cm 2 /W, and 9.469 x 10 -4 cm 2 /W for 1 wt%,2 wt% and 5wt% of PVP ...
A novel nonlinear optical (NLO) polycrystalline material-lanthanum barium borate (LBB) has been s... more A novel nonlinear optical (NLO) polycrystalline material-lanthanum barium borate (LBB) has been synthesized by the solid-state reaction method. The differential thermal analysis shows the material melts at 898C. The synthesized material exhibits monoclinic crystal structure with the space group C2, which has been confirmed from powder X-ray diffraction study. The second harmonic generation (SHG) in the powder sample was examined by using Nd:YAG laser with a fundamental wavelength of 1064 nm. The test confirms the SHG by the synthesized material. From the Fourier transform infrared analysis, BO3 and BO4 are the ionic groups exist in the materials which are responsible to produce NLO phenomenon in the prepare samples.
Optical Fiber Technology, 2018
Abstract The fabrication and study of cladding modified intrinsic fiber optic urea biosensor has ... more Abstract The fabrication and study of cladding modified intrinsic fiber optic urea biosensor has been reported in the present investigation. A simple cladding modification technique was used to construct the sensor by uncladding the small portion from optical fiber. Further bare core was decorated by supportive porous, chemically and optically sensitive matrix material polyaniline (PANI) as an active cladding for enzyme residency. Enzyme-urease (Urs) was cross-linked on the active cladding region via glutaraldehyde solution. Confirmation of the prepared PANI in proper form determined by ultraviolet-visible and Fourier transform infrared spectroscopic techniques. X-ray diffraction technique was employed for nature and compatibility examination of PANI. Sensor parameters such as sensitivity, selectivity, stability and lower detection limit have been analyzed by absorption variation study in evanescent wave field. The response of prepared sensor was studied towards urea in the wide concentration range 100 nM–100 mM and confirmed its lowest detection limit as 100 nM. The stability of sensor was found 28 days with little variation in response. The fabricated sensor has not shown any response towards interference species like glucose, ascorbic acid, l -alanine, l -arginine and their combination with urea solution and hence found selective for urea solution only.
Science and Technology, 2012
Single crystals of pure and amino acid (L-arginine and L-alanine) doped potassium dihydrogen phos... more Single crystals of pure and amino acid (L-arginine and L-alanine) doped potassium dihydrogen phosphate (KDP) for second harmonic generation have been grown from low temperature solution growth method by employing slow evaporation of the solvent. FT-IR spectrum of pure and doped KDP crystals confirms qualitatively the doping of the L-arginine and L-alanine in the host crystals. UV-visible spectroscopy shows the improvement in the transparency. Crystal structure has been studied by powder X-ray diffraction. Modification in the lattice parameters has been observed. Improvement in the SHG efficiency was studied by the Kurtz and Perry method. Thermal analysis has been performed on the grown crystals.
RSC Advances
Gold nanoparticle (GNP) colloids stabilized with various concentrations of l-ascorbic acid were s... more Gold nanoparticle (GNP) colloids stabilized with various concentrations of l-ascorbic acid were synthesized by the chemical reduction method and characterized by UV-Vis spectroscopy, XRD, FT-IR spectroscopy and TEM.
Crystal Research and Technology
Materials Research Innovations
ABSTRACT In the present investigation, glycine has been doped in bis-thiourea cadmium formate (BT... more ABSTRACT In the present investigation, glycine has been doped in bis-thiourea cadmium formate (BTCF) and single crystal was grown by slow solution evaporation technique. The incorporation of glycine in BTCF crystal was confirmed by Fourier transform infrared (FTIR) analysis. The UV-visible transmittance spectrum of pure and doped BTCF crystals was recorded to comparatively analyse the optical transparency, optical bandgap and other optical constants. The third-order non-linear behaviour of grown crystals has been investigated at 632?8 nm using Z-scan technique, and vital third-order non-linear optical (NLO) constants were calculated. The second harmonic generation (SHG) efficiency of doped BTCF crystal is found to be 2?15 times that of KDP material. The fluorescence studies of doped BTCF crystal confirmed the red colour emission in the visible region. The thermal stability of grown crystals was determined by means of thermogravimetric analysis (TGA). The dielectric measurement studies were performed at room temperature. The surface morphology of doped BTCF crystal was analysed by scanning electron microscopy (SEM) technique.
Materials Technology
ABSTRACT In present studies, L-arginine doped zinc thiourea chloride (LAZTC) crystal has been gro... more ABSTRACT In present studies, L-arginine doped zinc thiourea chloride (LAZTC) crystal has been grown by slow solution evaporation technique. The cell parameters of LAZTC crystal were determined using the single crystal X-ray diffraction technique. The incorporation of L-arginine in ZTC has been confirmed by means of Fourier transform infrared analysis. The high optical transparency of the grown crystal has been examined under the UV-visible study. The wide optical band gap of LAZTC crystal is found to be 5.25 eV. The photoluminescence study of grown crystal has been investigated in the range of 300 to 700 nm. The negative photoconducting nature of LAZTC crystal has been investigated by means of photoconductivity studies. Thermal stability of LAZTC crystal was evaluated by thermogravimetric and differential thermal analysis. The dielectric measurements confirmed the lower dielectric characteristics of LAZTC crystal.
Chinese Journal of Physics
Materials Research Innovations
Indian Journal of Physics
Department of Physics, Acharya Marathe College, Chembur, Mumbai-400 071, India Department of Phys... more Department of Physics, Acharya Marathe College, Chembur, Mumbai-400 071, India Department of Physics, Siddharth College of ASC, Fort, Mumbai-400 023, India Department of Chemistry, Anand College, Pathardi, Ahamednagar-414 102, Maharashtra, India Department of Chemical Technology, Sant Gadge Baba Amravati University, Amravati-444 602, Maharashtra, India Department of Physics, Shri R. R. Lahoti Science College, Morshi, Amravati-444 905, Maharashtra, India Department of Physics, Sant Gadge Baba Amravati University, Amravati-444 602, Maharashtra, India E-mail : gajananggm@yahoo.co.in <strong>CdS</strong> nanoparticles passivated with amino acid L-alanine having spherical hierarchical morphology were synthesized by low temperature wet chemical method. The synthesized nanoparticles were characterized by <strong>UV</strong>-<strong>V</strong>isible spectroscopy to know the variation of band gaps with concentration of surface modifying agents. Indeed, blu...
In this study, silver nanoparticles were synthesized using sodium borohydride (NaBH4) as a reduci... more In this study, silver nanoparticles were synthesized using sodium borohydride (NaBH4) as a reducing agent at different concentrations (1 wt %, 2 wt %, 5 wt %) of poly N-vinylpyrrolidone (PVP) as a stabilizing agent by chemical reduction method.The reaction was carried at room temperature. Resulting nano-sized colloids have been characterized by FT-IR spectroscopy, UV-Visible spectroscopy, X-ray diffraction, and Transmission Electron Microscopy (TEM). Very strong surface Plasmon resonance peak at 410 nm in the UV-Visible is a direct evidence of formation of nano-sized silver colloids. XRD Diffraction pattern reveals the formation of cubic structured crystals.Transmission Electron Microscopy (TEM) confirms average diameter of silver nanoparticles as 9 nm. The non-linear refractive index ( 2) were calculated by Z-Scan technique using CW He-Ne laser (λ=632 nm)and are obtained as high as 3.353 x 10 4 cm 2 /W,8.697 x 10 4 cm 2 /W, and 9.469 x 10 -4 cm 2 /W for 1 wt%,2 wt% and 5wt% of PVP ...
A novel nonlinear optical (NLO) polycrystalline material-lanthanum barium borate (LBB) has been s... more A novel nonlinear optical (NLO) polycrystalline material-lanthanum barium borate (LBB) has been synthesized by the solid-state reaction method. The differential thermal analysis shows the material melts at 898C. The synthesized material exhibits monoclinic crystal structure with the space group C2, which has been confirmed from powder X-ray diffraction study. The second harmonic generation (SHG) in the powder sample was examined by using Nd:YAG laser with a fundamental wavelength of 1064 nm. The test confirms the SHG by the synthesized material. From the Fourier transform infrared analysis, BO3 and BO4 are the ionic groups exist in the materials which are responsible to produce NLO phenomenon in the prepare samples.
Optical Fiber Technology, 2018
Abstract The fabrication and study of cladding modified intrinsic fiber optic urea biosensor has ... more Abstract The fabrication and study of cladding modified intrinsic fiber optic urea biosensor has been reported in the present investigation. A simple cladding modification technique was used to construct the sensor by uncladding the small portion from optical fiber. Further bare core was decorated by supportive porous, chemically and optically sensitive matrix material polyaniline (PANI) as an active cladding for enzyme residency. Enzyme-urease (Urs) was cross-linked on the active cladding region via glutaraldehyde solution. Confirmation of the prepared PANI in proper form determined by ultraviolet-visible and Fourier transform infrared spectroscopic techniques. X-ray diffraction technique was employed for nature and compatibility examination of PANI. Sensor parameters such as sensitivity, selectivity, stability and lower detection limit have been analyzed by absorption variation study in evanescent wave field. The response of prepared sensor was studied towards urea in the wide concentration range 100 nM–100 mM and confirmed its lowest detection limit as 100 nM. The stability of sensor was found 28 days with little variation in response. The fabricated sensor has not shown any response towards interference species like glucose, ascorbic acid, l -alanine, l -arginine and their combination with urea solution and hence found selective for urea solution only.
Science and Technology, 2012
Single crystals of pure and amino acid (L-arginine and L-alanine) doped potassium dihydrogen phos... more Single crystals of pure and amino acid (L-arginine and L-alanine) doped potassium dihydrogen phosphate (KDP) for second harmonic generation have been grown from low temperature solution growth method by employing slow evaporation of the solvent. FT-IR spectrum of pure and doped KDP crystals confirms qualitatively the doping of the L-arginine and L-alanine in the host crystals. UV-visible spectroscopy shows the improvement in the transparency. Crystal structure has been studied by powder X-ray diffraction. Modification in the lattice parameters has been observed. Improvement in the SHG efficiency was studied by the Kurtz and Perry method. Thermal analysis has been performed on the grown crystals.
RSC Advances
Gold nanoparticle (GNP) colloids stabilized with various concentrations of l-ascorbic acid were s... more Gold nanoparticle (GNP) colloids stabilized with various concentrations of l-ascorbic acid were synthesized by the chemical reduction method and characterized by UV-Vis spectroscopy, XRD, FT-IR spectroscopy and TEM.
Crystal Research and Technology
Materials Research Innovations
ABSTRACT In the present investigation, glycine has been doped in bis-thiourea cadmium formate (BT... more ABSTRACT In the present investigation, glycine has been doped in bis-thiourea cadmium formate (BTCF) and single crystal was grown by slow solution evaporation technique. The incorporation of glycine in BTCF crystal was confirmed by Fourier transform infrared (FTIR) analysis. The UV-visible transmittance spectrum of pure and doped BTCF crystals was recorded to comparatively analyse the optical transparency, optical bandgap and other optical constants. The third-order non-linear behaviour of grown crystals has been investigated at 632?8 nm using Z-scan technique, and vital third-order non-linear optical (NLO) constants were calculated. The second harmonic generation (SHG) efficiency of doped BTCF crystal is found to be 2?15 times that of KDP material. The fluorescence studies of doped BTCF crystal confirmed the red colour emission in the visible region. The thermal stability of grown crystals was determined by means of thermogravimetric analysis (TGA). The dielectric measurement studies were performed at room temperature. The surface morphology of doped BTCF crystal was analysed by scanning electron microscopy (SEM) technique.
Materials Technology
ABSTRACT In present studies, L-arginine doped zinc thiourea chloride (LAZTC) crystal has been gro... more ABSTRACT In present studies, L-arginine doped zinc thiourea chloride (LAZTC) crystal has been grown by slow solution evaporation technique. The cell parameters of LAZTC crystal were determined using the single crystal X-ray diffraction technique. The incorporation of L-arginine in ZTC has been confirmed by means of Fourier transform infrared analysis. The high optical transparency of the grown crystal has been examined under the UV-visible study. The wide optical band gap of LAZTC crystal is found to be 5.25 eV. The photoluminescence study of grown crystal has been investigated in the range of 300 to 700 nm. The negative photoconducting nature of LAZTC crystal has been investigated by means of photoconductivity studies. Thermal stability of LAZTC crystal was evaluated by thermogravimetric and differential thermal analysis. The dielectric measurements confirmed the lower dielectric characteristics of LAZTC crystal.
Chinese Journal of Physics
Materials Research Innovations