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Research paper thumbnail of Progress and trends in hydrate based desalination (HBD) technology: A review

Chinese Journal of Chemical Engineering, Sep 1, 2019

The shortage of freshwater boosts the development of seawater desalination technology. As a novel... more The shortage of freshwater boosts the development of seawater desalination technology. As a novel method, the hydrate based desalination technology has been put forward for decades and achieved considerable development in the past years. This review focuses on the experimental progress at the aspects of the hydrate former choice, formation promotion and ion removal efficiency and conceptive innovation of hydrate separation and energy utilization. It should be noted that gaseous hydrate former with low formation pressure and insoluble liquid hydrate former are worthy for further study. Besides, the water migration caused by propane deserves to be investigated much more deeply for the potential value of wide application. Moreover, the utilization proposal of LNG cold energy brings more possibility of commercial application. In a word, the hydrate based desalination technology is hopefully an environment friendly, low-cost and widely used desalination technology in the near future.

Research paper thumbnail of Compression-induced dynamic change in effective permeability of hydrate-bearing sediments during hydrate dissociation by depressurization

Research paper thumbnail of A Fully Coupled Thermo-Hydro-Mechanical-Chemical Model for Methane Hydrate Bearing Sediments Considering the Effect of Ice

Journal of Marine Science and Engineering

The ice generation is one of the challenges facing the methane hydrate depressurization, which, h... more The ice generation is one of the challenges facing the methane hydrate depressurization, which, however, has not been fully addressed by existing numerical models for hydrate-bearing sediments (HBS). In this study, we develop a high-fidelity, fully coupled thermo-hydro-mechanical-chemical numerical model that incorporates the effect of ice. The model, developed using COMSOL, takes into account water–ice phase change, thermally induced cryogenic suction and constitutive relation in HBS. It is verified well against the temperature, pressure and cumulative gas production of Masuda’s experiment. The model is then employed to investigate multiphysical responses and gas/water production when ice generation is induced by setting a low outlet pressure. The results reveal that ice forms near the outlet boundary of the specimen center, leading to a reduction in intrinsic permeability and fluid velocity and an increase in the bulk modulus of ice-HBS. This enhanced bulk modulus results in highe...

Research paper thumbnail of Numerical Analysis of Coupled Thermal-Hydro-Chemo-Mechanical(Thcm) Behavior to Joint Production of Marine Gas Hydrate and Shallow Gas

Research paper thumbnail of Compression-induced dynamic change in effective permeability of hydrate-bearing sediments during hydrate dissociation by depressurization

Research paper thumbnail of Progress and trends in hydrate based desalination (HBD) technology: A review

Chinese Journal of Chemical Engineering, Sep 1, 2019

The shortage of freshwater boosts the development of seawater desalination technology. As a novel... more The shortage of freshwater boosts the development of seawater desalination technology. As a novel method, the hydrate based desalination technology has been put forward for decades and achieved considerable development in the past years. This review focuses on the experimental progress at the aspects of the hydrate former choice, formation promotion and ion removal efficiency and conceptive innovation of hydrate separation and energy utilization. It should be noted that gaseous hydrate former with low formation pressure and insoluble liquid hydrate former are worthy for further study. Besides, the water migration caused by propane deserves to be investigated much more deeply for the potential value of wide application. Moreover, the utilization proposal of LNG cold energy brings more possibility of commercial application. In a word, the hydrate based desalination technology is hopefully an environment friendly, low-cost and widely used desalination technology in the near future.

Research paper thumbnail of Compression-induced dynamic change in effective permeability of hydrate-bearing sediments during hydrate dissociation by depressurization

Research paper thumbnail of A Fully Coupled Thermo-Hydro-Mechanical-Chemical Model for Methane Hydrate Bearing Sediments Considering the Effect of Ice

Journal of Marine Science and Engineering

The ice generation is one of the challenges facing the methane hydrate depressurization, which, h... more The ice generation is one of the challenges facing the methane hydrate depressurization, which, however, has not been fully addressed by existing numerical models for hydrate-bearing sediments (HBS). In this study, we develop a high-fidelity, fully coupled thermo-hydro-mechanical-chemical numerical model that incorporates the effect of ice. The model, developed using COMSOL, takes into account water–ice phase change, thermally induced cryogenic suction and constitutive relation in HBS. It is verified well against the temperature, pressure and cumulative gas production of Masuda’s experiment. The model is then employed to investigate multiphysical responses and gas/water production when ice generation is induced by setting a low outlet pressure. The results reveal that ice forms near the outlet boundary of the specimen center, leading to a reduction in intrinsic permeability and fluid velocity and an increase in the bulk modulus of ice-HBS. This enhanced bulk modulus results in highe...

Research paper thumbnail of Numerical Analysis of Coupled Thermal-Hydro-Chemo-Mechanical(Thcm) Behavior to Joint Production of Marine Gas Hydrate and Shallow Gas

Research paper thumbnail of Compression-induced dynamic change in effective permeability of hydrate-bearing sediments during hydrate dissociation by depressurization

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