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Papers by Florence Mongin
Synlett, Nov 12, 2008
Several unsymmetrical heterobiaryls have been synthesized through palladium-catalyzed cross-coupl... more Several unsymmetrical heterobiaryls have been synthesized through palladium-catalyzed cross-coupling reactions of lithium triorganozincates. The latter have been prepared by deprotonative lithiation followed by transmetalation using non hygroscopic ZnCl 2 •TMEDA (1/3 equiv).
Organic and Biomolecular Chemistry, 2011
ChemInform, Feb 5, 2008
ABSTRACT ChemInform is a weekly Abstracting Service, delivering concise information at a glance t... more ABSTRACT ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Related Article: Mehdi Tazi, William Erb, Yury S. Halauko, Oleg A. Ivashkevich, Vadim E. Matulis,... more Related Article: Mehdi Tazi, William Erb, Yury S. Halauko, Oleg A. Ivashkevich, Vadim E. Matulis, Thierry Roisnel, Vincent Dorcet, Florence Mongin|2017|Organometallics|||doi:10.1021/acs.organomet.7b00659
Les 8-hydroxy et 8-methoxyquinoleines etudiees peuvent subir une reaction de bromation ; ainsi so... more Les 8-hydroxy et 8-methoxyquinoleines etudiees peuvent subir une reaction de bromation ; ainsi sont obtenues des quinoleines diversement substituees par des atomes de brome en position 3, 5 et 7. A partir des 5,7-dibromoquinoleines substituees en position 8, un echange brome-lithium selectif a ete realise ; la nature du substituant en position 8 modifie l'orientation de cette reaction. La reaction de couplage croise, appliquee a diverses bromo-8-methoxyquinoleines, permet de greffer differents groupements. Dans le cas de dibromoquinoleines, une bonne regioselectivite a ete observee. Enfin, de nombreux pyridocarbazoles ont ete synthetises, la reaction de couplage croise etant utilisee pour creer la jonction entre les cycles quinoleinique et benzenique
Acta Crystallographica Section C: Structural Chemistry, Sep 20, 2017
Synthetic Communications, Aug 1, 2007
Related Article: Andrada Stefania Trita, Thierry Roisnel, Florence Mongin, Floris Chevallier|2013... more Related Article: Andrada Stefania Trita, Thierry Roisnel, Florence Mongin, Floris Chevallier|2013|Org.Lett.|15|3798|doi:10.1021/ol401803t
![Research paper thumbnail of A combined experimental and theoretical study of the thermal [3+2] cycloaddition of carbonyl ylides with activated alkenes](https://attachments.academia-assets.com/117973530/thumbnails/1.jpg)
](Journal of Molecular Structure, Apr 1, 2018
ChemInform, Feb 19, 2010
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was e... more ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Chemical Communications
A ferrocene catalyzed difunctionalization of aryl alkenes using cycloketone oxime esters as bifun... more A ferrocene catalyzed difunctionalization of aryl alkenes using cycloketone oxime esters as bifunctional reagents is reported.
HAL (Le Centre pour la Communication Scientifique Directe), 2007
National audienc
Supporting data for the publication "Extending motifs in lithiocuprate chemistry: unexpected... more Supporting data for the publication "Extending motifs in lithiocuprate chemistry: unexpected structural diversity in thiocyanate complexes". Single crystal X-ray diffraction structures and NMR spectroscopic data for complexes 8-11 in the paper. All four complexes were made at Cambridge in 2015 and were characterized in house in 2015. NMR spectra for compounds 15 and 16. These were made and characterized in Rennes in 2015.This work was supported by the EPSRC [grant number EP/J500380/1] and Ministère de l'Enseignement Supérieur et de la Recherche scientifique Algérien
Synthesis, 2022
Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range ... more Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferrocenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki–Miyaura cross-coupling reactions are also described to reach original derivatives.
Synthesis, 2020
The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the fe... more The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the ferrocene series. Here an original access based on the remote deprotometalation of N,N-diisopropyl-2-trimethylsilylferrocenecarboxamide is reported. The key intermediate, 1′-iodo-N,N-diisopropylferrocenecarboxamide, was prepared in multiple grams and was further functionalized toward fifteen 1′-substituted iodoferrocenes.
Synlett, Nov 12, 2008
Several unsymmetrical heterobiaryls have been synthesized through palladium-catalyzed cross-coupl... more Several unsymmetrical heterobiaryls have been synthesized through palladium-catalyzed cross-coupling reactions of lithium triorganozincates. The latter have been prepared by deprotonative lithiation followed by transmetalation using non hygroscopic ZnCl 2 •TMEDA (1/3 equiv).
Organic and Biomolecular Chemistry, 2011
ChemInform, Feb 5, 2008
ABSTRACT ChemInform is a weekly Abstracting Service, delivering concise information at a glance t... more ABSTRACT ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Related Article: Mehdi Tazi, William Erb, Yury S. Halauko, Oleg A. Ivashkevich, Vadim E. Matulis,... more Related Article: Mehdi Tazi, William Erb, Yury S. Halauko, Oleg A. Ivashkevich, Vadim E. Matulis, Thierry Roisnel, Vincent Dorcet, Florence Mongin|2017|Organometallics|||doi:10.1021/acs.organomet.7b00659
Les 8-hydroxy et 8-methoxyquinoleines etudiees peuvent subir une reaction de bromation ; ainsi so... more Les 8-hydroxy et 8-methoxyquinoleines etudiees peuvent subir une reaction de bromation ; ainsi sont obtenues des quinoleines diversement substituees par des atomes de brome en position 3, 5 et 7. A partir des 5,7-dibromoquinoleines substituees en position 8, un echange brome-lithium selectif a ete realise ; la nature du substituant en position 8 modifie l'orientation de cette reaction. La reaction de couplage croise, appliquee a diverses bromo-8-methoxyquinoleines, permet de greffer differents groupements. Dans le cas de dibromoquinoleines, une bonne regioselectivite a ete observee. Enfin, de nombreux pyridocarbazoles ont ete synthetises, la reaction de couplage croise etant utilisee pour creer la jonction entre les cycles quinoleinique et benzenique
Acta Crystallographica Section C: Structural Chemistry, Sep 20, 2017
Synthetic Communications, Aug 1, 2007
Related Article: Andrada Stefania Trita, Thierry Roisnel, Florence Mongin, Floris Chevallier|2013... more Related Article: Andrada Stefania Trita, Thierry Roisnel, Florence Mongin, Floris Chevallier|2013|Org.Lett.|15|3798|doi:10.1021/ol401803t
Journal of Molecular Structure, Apr 1, 2018
ChemInform, Feb 19, 2010
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was e... more ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Chemical Communications
A ferrocene catalyzed difunctionalization of aryl alkenes using cycloketone oxime esters as bifun... more A ferrocene catalyzed difunctionalization of aryl alkenes using cycloketone oxime esters as bifunctional reagents is reported.
HAL (Le Centre pour la Communication Scientifique Directe), 2007
National audienc
Supporting data for the publication "Extending motifs in lithiocuprate chemistry: unexpected... more Supporting data for the publication "Extending motifs in lithiocuprate chemistry: unexpected structural diversity in thiocyanate complexes". Single crystal X-ray diffraction structures and NMR spectroscopic data for complexes 8-11 in the paper. All four complexes were made at Cambridge in 2015 and were characterized in house in 2015. NMR spectra for compounds 15 and 16. These were made and characterized in Rennes in 2015.This work was supported by the EPSRC [grant number EP/J500380/1] and Ministère de l'Enseignement Supérieur et de la Recherche scientifique Algérien
Synthesis, 2022
Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range ... more Ferrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferrocenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki–Miyaura cross-coupling reactions are also described to reach original derivatives.
Synthesis, 2020
The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the fe... more The 1,1′-disubstitution is currently the most frequent substitution pattern encountered in the ferrocene series. Here an original access based on the remote deprotometalation of N,N-diisopropyl-2-trimethylsilylferrocenecarboxamide is reported. The key intermediate, 1′-iodo-N,N-diisopropylferrocenecarboxamide, was prepared in multiple grams and was further functionalized toward fifteen 1′-substituted iodoferrocenes.