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Papers by Giuseppe Placucci

Research paper thumbnail of Reactions of alkanethiyl and alkoxyl radicals with unsaturated cyclic ethers

Tetrahedron, 1983

addition and hydrogen abstraction from the allylic positions. The esr spectra of the correspondin... more addition and hydrogen abstraction from the allylic positions. The esr spectra of the corresponding radicals have been determined. In some cases radicals arising from a rearrangement (probably I.4 H-shift) were observed. &Butoxyl radicals also give abstraction and addition with the same substrates. In two cases the barriers to ring inversion for six-membered ring radicals have been determined.

Research paper thumbnail of Reactions of alkanethiyl and alkoxyl radicals with unsaturated cyclic ethers

Tetrahedron, 1983

addition and hydrogen abstraction from the allylic positions. The esr spectra of the correspondin... more addition and hydrogen abstraction from the allylic positions. The esr spectra of the corresponding radicals have been determined. In some cases radicals arising from a rearrangement (probably I.4 H-shift) were observed. &Butoxyl radicals also give abstraction and addition with the same substrates. In two cases the barriers to ring inversion for six-membered ring radicals have been determined.

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