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Research paper thumbnail of X-ray Dichroism Reveals Ferromagnetism in Metal Free Carbon

Research paper thumbnail of Ferromagnetism in Mn-implanted epitaxially grown Ge on Si(100)

Physical Review B, 2011

ABSTRACT We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge fil... more ABSTRACT We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge films were grown by ultrahigh vacuum chemical vapor deposition using a mixture of germane (GeH4) and methylgermane (CH3GeH3) gases with a carbon concentration of less than 1 at. %, and observed surface rms roughness of ∼0.5 nm, as measured by atomic force microscopy. Manganese ions were implanted in epitaxial Ge films grown on Si (100) wafers to an effective concentration of ∼16, 12, 6, and 2 at. %. Superconducting quantum interference device measurements showed that only the three highest Mn concentration samples are ferromagnetic, while the fourth sample, with [Mn] = 2 at. %, is paramagnetic. X-ray absorption spectroscopy and x-ray magnetic circular dichroism measurements indicate that localized Mn moments are ferromagnetically coupled below the Curie temperature. Isothermal annealing of Mn-implanted Ge films with [Mn] = 16 at. % at 300 °C for up to 1200 s decreases the magnetization but does not change the Curie temperature, suggesting that the amount of the magnetic phase slowly decreases with time at this anneal temperature. Furthermore, transmission electron microscopy and synchrotron grazing incidence x-ray diffraction experiments show that the Mn-implanted region is amorphous, and we believe that it is this phase that is responsible for the ferromagnetism. This is supported by our observation that high-temperature annealing leads to recrystallization and transformation of the material into a paramagnetic phase.

Research paper thumbnail of Microwave pump-probe transmission x-ray microscopy for magnetization dynamics imaging

Research paper thumbnail of X-ray photoemission electron microscopy, a tool for the investigation of complex magnetic structures

X-ray Photoemission Electron Microscopy unites the chemical specificity and magnetic sensitivity ... more X-ray Photoemission Electron Microscopy unites the chemical specificity and magnetic sensitivity of soft x-ray absorption techniques with the high spatial resolution of electron microscopy. The discussed instrument possesses a spatial resolution of better than 50 nm and is located at a bending magnet beamline at the Advanced Light Source, providing linearly and circularly polarized radiation between 250 and 1300 eV. We will present examples which demonstrate the power of this technique applied to problems in the field of thin film magnetism. The chemical and elemental specificity is of particular importance for the study of magnetic exchange coupling because it allows separating the signal of the different layers and interfaces in complex multi-layered structures.

Research paper thumbnail of Transmission Magnetization Imaging Using the STXM

Research paper thumbnail of X-ray Dichroism Reveals Ferromagnetism in Metal Free Carbon

Research paper thumbnail of Ferromagnetism in Mn-implanted epitaxially grown Ge on Si(100)

Physical Review B, 2011

ABSTRACT We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge fil... more ABSTRACT We have studied ferromagnetism of Mn-implanted epitaxial Ge films on silicon. The Ge films were grown by ultrahigh vacuum chemical vapor deposition using a mixture of germane (GeH4) and methylgermane (CH3GeH3) gases with a carbon concentration of less than 1 at. %, and observed surface rms roughness of ∼0.5 nm, as measured by atomic force microscopy. Manganese ions were implanted in epitaxial Ge films grown on Si (100) wafers to an effective concentration of ∼16, 12, 6, and 2 at. %. Superconducting quantum interference device measurements showed that only the three highest Mn concentration samples are ferromagnetic, while the fourth sample, with [Mn] = 2 at. %, is paramagnetic. X-ray absorption spectroscopy and x-ray magnetic circular dichroism measurements indicate that localized Mn moments are ferromagnetically coupled below the Curie temperature. Isothermal annealing of Mn-implanted Ge films with [Mn] = 16 at. % at 300 °C for up to 1200 s decreases the magnetization but does not change the Curie temperature, suggesting that the amount of the magnetic phase slowly decreases with time at this anneal temperature. Furthermore, transmission electron microscopy and synchrotron grazing incidence x-ray diffraction experiments show that the Mn-implanted region is amorphous, and we believe that it is this phase that is responsible for the ferromagnetism. This is supported by our observation that high-temperature annealing leads to recrystallization and transformation of the material into a paramagnetic phase.

Research paper thumbnail of Microwave pump-probe transmission x-ray microscopy for magnetization dynamics imaging

Research paper thumbnail of X-ray photoemission electron microscopy, a tool for the investigation of complex magnetic structures

X-ray Photoemission Electron Microscopy unites the chemical specificity and magnetic sensitivity ... more X-ray Photoemission Electron Microscopy unites the chemical specificity and magnetic sensitivity of soft x-ray absorption techniques with the high spatial resolution of electron microscopy. The discussed instrument possesses a spatial resolution of better than 50 nm and is located at a bending magnet beamline at the Advanced Light Source, providing linearly and circularly polarized radiation between 250 and 1300 eV. We will present examples which demonstrate the power of this technique applied to problems in the field of thin film magnetism. The chemical and elemental specificity is of particular importance for the study of magnetic exchange coupling because it allows separating the signal of the different layers and interfaces in complex multi-layered structures.

Research paper thumbnail of Transmission Magnetization Imaging Using the STXM

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