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Papers by Heinrich Schwoerer
Nature Physics, 2008
Ultrashort light pulses are powerful tools for time-resolved studies of molecular and atomic dyna... more Ultrashort light pulses are powerful tools for time-resolved studies of molecular and atomic dynamics. They arise in the visible and infrared range from femtosecond lasers, and at shorter wavelengths, in the ultraviolet and X-ray range, from synchrotron sources and free-electron lasers. Recent progress in laser wakefield accelerators has resulted in electron beams with energies from tens of mega-electron volts (refs
Physical Chemistry Chemical Physics
The ultrafast dynamics of unsubstituted spironaphthopyran (SNP) were investigated using femtoseco... more The ultrafast dynamics of unsubstituted spironaphthopyran (SNP) were investigated using femtosecond transient UV and visible absorption spectroscopy in three different solvents and semi-classical nuclear dynamics simulations. The primary ring-opening of...
physica status solidi (b)
Journal of Polymer Science Part B: Polymer Physics
Journal of Physics B: Atomic, Molecular and Optical Physics
Physical Review Letters, 2016
Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in... more Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in solids. The transition between such phases involves formation and rearrangement of domain walls and is generally slow. Using ultrafast electron diffraction, we directly record the photoinduced transformation between a nearly commensurate and an incommensurate charge-density-wave phase in 1T-TaS(2). The transformation takes place on the picosecond time scale, orders of magnitude faster than previously observed for commensurate-to-incommensurate transitions. The transition speed and mechanism can be linked to the peculiar nanoscale structure of the photoexcited nearly commensurate phase.
International Conference on Ultrafast Phenomena, 2016
Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in... more Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in solids. The transition between such phases involves formation and rearrangement of domain walls and is generally slow. Using ultrafast electron diffraction, we directly record the photoinduced transformation between a nearly commensurate and an incommensurate charge-density-wave phase in 1T-TaS(2). The transformation takes place on the picosecond time scale, orders of magnitude faster than previously observed for commensurate-to-incommensurate transitions. The transition speed and mechanism can be linked to the peculiar nanoscale structure of the photoexcited nearly commensurate phase.
South African Journal of Science, Aug 1, 2008
Summaries of Papers Presented at the Lasers and Electro Optics Cleo 02 Technical Diges, Feb 1, 2002
Europhysics Letters, 2002
We present systematic investigations on the generation of titanium Kalpha-radiation (E = 4.5 keV)... more We present systematic investigations on the generation of titanium Kalpha-radiation (E = 4.5 keV) from plasmas produced with ultrashort, high-intensity laser pulses. A maximum Kalpha-yield appears at a laser intensity of about 3·1017 W/cm2, corresponding to a plasma electron temperature of a few times the Kalpha photon energy. We observe a second increase in the Kalpha-emission yield at intensities higher
Physical chemistry chemical physics : PCCP, Jan 23, 2016
Charge transfer dynamics in fully operational dye sensitised solar cells consisting of an electro... more Charge transfer dynamics in fully operational dye sensitised solar cells consisting of an electrolyte or organic spiroOMeTAD in contact with a highly porous electrodeposited ZnO film sensitised with a monolayer of the indoline dye DN216 were observed using ultrafast transient absorption spectroscopy. From the temporal evolution of spectral signatures assigned with the help of spectroelectrochemical experiments to the population and depopulation of initial, transient and final states, a model was completed for the multistep injection of photoexcited electrons from the molecular absorber to the ZnO acceptor. Injection was found to occur via three different paths with three characteristic rates: directly from the dye's lowest unoccupied molecular orbital into the ZnO conduction band (200 fs) and via intermediate molecular dominated and surface dominated hybrid states (2 ps and 10 ps, respectively).
Journal of the Chinese Chemical Society, 2000
ChemPhysChem, 2015
Ultrafast transient absorption measurements open aw indow to photo-induced chargetransfer process... more Ultrafast transient absorption measurements open aw indow to photo-induced chargetransfer processes in fully functional indoline dye sensitized solar cells. On p. 943, H. Schwoerer et al. presentthe effect of systematically modified indoline dyes in the cells on electron injection from dye to semiconductor and detrimental recombination channels, and on the cells macroscopic stability.The cover picture displays one of these cells with an indoline dye attached in the African sunlight, accompanied by afemtosecond transient absorptionlandscape.
Topics in Applied Physics, 2004
Nature Physics, 2008
Ultrashort light pulses are powerful tools for time-resolved studies of molecular and atomic dyna... more Ultrashort light pulses are powerful tools for time-resolved studies of molecular and atomic dynamics. They arise in the visible and infrared range from femtosecond lasers, and at shorter wavelengths, in the ultraviolet and X-ray range, from synchrotron sources and free-electron lasers. Recent progress in laser wakefield accelerators has resulted in electron beams with energies from tens of mega-electron volts (refs
Physical Chemistry Chemical Physics
The ultrafast dynamics of unsubstituted spironaphthopyran (SNP) were investigated using femtoseco... more The ultrafast dynamics of unsubstituted spironaphthopyran (SNP) were investigated using femtosecond transient UV and visible absorption spectroscopy in three different solvents and semi-classical nuclear dynamics simulations. The primary ring-opening of...
physica status solidi (b)
Journal of Polymer Science Part B: Polymer Physics
Journal of Physics B: Atomic, Molecular and Optical Physics
Physical Review Letters, 2016
Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in... more Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in solids. The transition between such phases involves formation and rearrangement of domain walls and is generally slow. Using ultrafast electron diffraction, we directly record the photoinduced transformation between a nearly commensurate and an incommensurate charge-density-wave phase in 1T-TaS(2). The transformation takes place on the picosecond time scale, orders of magnitude faster than previously observed for commensurate-to-incommensurate transitions. The transition speed and mechanism can be linked to the peculiar nanoscale structure of the photoexcited nearly commensurate phase.
International Conference on Ultrafast Phenomena, 2016
Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in... more Modulated phases, commensurate or incommensurate with the host crystal lattice, are ubiquitous in solids. The transition between such phases involves formation and rearrangement of domain walls and is generally slow. Using ultrafast electron diffraction, we directly record the photoinduced transformation between a nearly commensurate and an incommensurate charge-density-wave phase in 1T-TaS(2). The transformation takes place on the picosecond time scale, orders of magnitude faster than previously observed for commensurate-to-incommensurate transitions. The transition speed and mechanism can be linked to the peculiar nanoscale structure of the photoexcited nearly commensurate phase.
South African Journal of Science, Aug 1, 2008
Summaries of Papers Presented at the Lasers and Electro Optics Cleo 02 Technical Diges, Feb 1, 2002
Europhysics Letters, 2002
We present systematic investigations on the generation of titanium Kalpha-radiation (E = 4.5 keV)... more We present systematic investigations on the generation of titanium Kalpha-radiation (E = 4.5 keV) from plasmas produced with ultrashort, high-intensity laser pulses. A maximum Kalpha-yield appears at a laser intensity of about 3·1017 W/cm2, corresponding to a plasma electron temperature of a few times the Kalpha photon energy. We observe a second increase in the Kalpha-emission yield at intensities higher
Physical chemistry chemical physics : PCCP, Jan 23, 2016
Charge transfer dynamics in fully operational dye sensitised solar cells consisting of an electro... more Charge transfer dynamics in fully operational dye sensitised solar cells consisting of an electrolyte or organic spiroOMeTAD in contact with a highly porous electrodeposited ZnO film sensitised with a monolayer of the indoline dye DN216 were observed using ultrafast transient absorption spectroscopy. From the temporal evolution of spectral signatures assigned with the help of spectroelectrochemical experiments to the population and depopulation of initial, transient and final states, a model was completed for the multistep injection of photoexcited electrons from the molecular absorber to the ZnO acceptor. Injection was found to occur via three different paths with three characteristic rates: directly from the dye's lowest unoccupied molecular orbital into the ZnO conduction band (200 fs) and via intermediate molecular dominated and surface dominated hybrid states (2 ps and 10 ps, respectively).
Journal of the Chinese Chemical Society, 2000
ChemPhysChem, 2015
Ultrafast transient absorption measurements open aw indow to photo-induced chargetransfer process... more Ultrafast transient absorption measurements open aw indow to photo-induced chargetransfer processes in fully functional indoline dye sensitized solar cells. On p. 943, H. Schwoerer et al. presentthe effect of systematically modified indoline dyes in the cells on electron injection from dye to semiconductor and detrimental recombination channels, and on the cells macroscopic stability.The cover picture displays one of these cells with an indoline dye attached in the African sunlight, accompanied by afemtosecond transient absorptionlandscape.
Topics in Applied Physics, 2004