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Research paper thumbnail of The role of active silica and alumina in geopolymerization

Vietnam Journal of Science, Technology and Engineering

In this study, the alkaline solutions (NaOH) with concentrations from 1M to 18M, red mud (RM) and... more In this study, the alkaline solutions (NaOH) with concentrations from 1M to 18M, red mud (RM) and silica fume (SF) were used as reactors in geopolymer reactions. RM contains 7.40% SiO 2 and 13.65% Al 2 o 3 and SF has 94.50% SiO 2 , but only the active oxides can participate in the geopolymer reactions. The activity of the oxides was investigated by determining the compressive strength of the samples under different curing conditions. The characteristics of the geopolymer samples were determined by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA)/differential thermal analysis (DTA) and nuclear magnetic resonance analysis (NMR). The experimental results indicate that active silica mainly exists in SF. In the structure of geopolymers, the silicon can bond directly with each other (Si-Si) or be linked through 'bridging' oxygen (Si-O-Si) to form independent polymer chains, while aluminium atoms can only replace the silicon atoms in Si-O-Si polymer chains to form Si-O-Al instead.

Research paper thumbnail of The Stress–Strain State of Three-Layer Precast Flexural Concrete Enclosure Structures with the Contact Interlayers

Buildings

The research object was three-layer reinforced precast concrete enclosure structures. The structu... more The research object was three-layer reinforced precast concrete enclosure structures. The structures consist of heavy concrete B25 in the external layers and polystyrene concrete B1 in the internal layer. The stress–strain state of precast concrete structures during crack formation was studied by considering the influence of contact interlayers between different types of concretes. Stereoscopic microscopy and scanning electron microscopy were used in the experimental study of multilayer concrete blocks. Samples were made with a varied break time from 30 min to two hours between the previous and the next concrete layer placings. The experimental results showed that the contact interlayer with mutual penetration of aggregates into the adjacent concrete layers is formed in the successive layer-by-layer placing of various concretes. The thickness of the contact interlayer was up to 1 cm. The contact interlayer affects the solidity of the concrete layers’ connection and the structure’s s...

Research paper thumbnail of The role of active silica and alumina in geopolymerization

Vietnam Journal of Science, Technology and Engineering

In this study, the alkaline solutions (NaOH) with concentrations from 1M to 18M, red mud (RM) and... more In this study, the alkaline solutions (NaOH) with concentrations from 1M to 18M, red mud (RM) and silica fume (SF) were used as reactors in geopolymer reactions. RM contains 7.40% SiO 2 and 13.65% Al 2 o 3 and SF has 94.50% SiO 2 , but only the active oxides can participate in the geopolymer reactions. The activity of the oxides was investigated by determining the compressive strength of the samples under different curing conditions. The characteristics of the geopolymer samples were determined by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA)/differential thermal analysis (DTA) and nuclear magnetic resonance analysis (NMR). The experimental results indicate that active silica mainly exists in SF. In the structure of geopolymers, the silicon can bond directly with each other (Si-Si) or be linked through 'bridging' oxygen (Si-O-Si) to form independent polymer chains, while aluminium atoms can only replace the silicon atoms in Si-O-Si polymer chains to form Si-O-Al instead.

Research paper thumbnail of The Stress–Strain State of Three-Layer Precast Flexural Concrete Enclosure Structures with the Contact Interlayers

Buildings

The research object was three-layer reinforced precast concrete enclosure structures. The structu... more The research object was three-layer reinforced precast concrete enclosure structures. The structures consist of heavy concrete B25 in the external layers and polystyrene concrete B1 in the internal layer. The stress–strain state of precast concrete structures during crack formation was studied by considering the influence of contact interlayers between different types of concretes. Stereoscopic microscopy and scanning electron microscopy were used in the experimental study of multilayer concrete blocks. Samples were made with a varied break time from 30 min to two hours between the previous and the next concrete layer placings. The experimental results showed that the contact interlayer with mutual penetration of aggregates into the adjacent concrete layers is formed in the successive layer-by-layer placing of various concretes. The thickness of the contact interlayer was up to 1 cm. The contact interlayer affects the solidity of the concrete layers’ connection and the structure’s s...

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