Marc Jacquin - Academia.edu (original) (raw)

Papers by Marc Jacquin

Research paper thumbnail of Controlling the Melting of Kinetically Frozen PBA-b-PAA Micelles via addition of surfactant

HAL (Le Centre pour la Communication Scientifique Directe), 2007

Research paper thumbnail of Copolymères diblocs amphiphiles chargés : d'un comportement colloÏdal à tensioactif

Research paper thumbnail of High throughput screening of amine thermodynamic properties applied to post-combustion CO2 capture process evaluation

Research paper thumbnail of Controlling the Melting of Kinetically Frozen Poly(butyl acrylate-<i>b</i>-acrylic acid) Micelles via Addition of Surfactant

Research paper thumbnail of Characterization of Amphiphilic Diblock Copolymers Synthesized by MADIX Polymerization Process

Macromolecules, Mar 15, 2007

Research paper thumbnail of Kinetics Modeling of the Heterogeneously Catalyzed Esterification of 2,3-Butanediol with Acetic Acid

Industrial & Engineering Chemistry Research, Apr 26, 2016

Research paper thumbnail of Novel graph machine based QSAR approach for the prediction of the adsorption enthalpies of alkanes on zeolites

Catalysis Today, 2011

This paper presents the application of a new machine learning approach called Graph Machines to t... more This paper presents the application of a new machine learning approach called Graph Machines to the prediction of the adsorption enthalpies of linear and branched alkanes on various zeolites. In this approach, the molecules are considered as structured data and are represented by graphs. For each individual of the data set, a mathematical function (graph machine) is built, which structure

Research paper thumbnail of Self-Assembly of Charged Amphiphilic Diblock Copolymers with Insoluble Blocks of Decreasing Hydrophobicity: From Kinetically Frozen Colloids to Macrosurfactants

Research paper thumbnail of Adsorption Kinetics of Amphiphilic Diblock Copolymers: From Kinetically Frozen Colloids to Macrosurfactants

Research paper thumbnail of Correlation between CO2 absorption capacity and amine molecular structures using a High throughput screening methodology

HAL (Le Centre pour la Communication Scientifique Directe), Mar 25, 2012

A major amount of greenhouse gas emissions comes from coal-fired power station generating large q... more A major amount of greenhouse gas emissions comes from coal-fired power station generating large quantities of CO2. Post-combustion carbon capture and storage (CCS) using amine solutions is one of the most mature solutions developed to reduce these emissions. However, the benchmark molecule (MEA) suffers from the high energy required to regenerate the solution. Thus, it is necessary to identify amine structures which minimize the energy consumption of the process. In our study, we focus on establishing a correlation between molecular structure and thermodynamics properties of amine solution. First, we use a High Throughput Screening (HTS) experimental device to determine the absorption isotherms of several amine solutions. Then, we build a statistical model using a quantitative structure activity relationship (QSAR) approach, in order to correlate amine structures to their absorption properties. Finally, this statistical model is applied to a set of new molecules to predict their thermodynamic properties

Research paper thumbnail of Procédé d’estérification d’un diol mettant en œuvre une distillation réactive

L'invention concerne un procédé de conversion alimenté par une charge diol comprenant au moin... more L'invention concerne un procédé de conversion alimenté par une charge diol comprenant au moins 90% poids de diol et une charge acide carboxylique comprenant au moins 80% poids d'acide carboxylique, ledit procédé comprenant au moins : - une étape d'estérification, alimentée par au moins ladite charge diol et au moins ladite charge acide carboxylique, les débits d'alimentation étant ajustés de telle sorte que le ratio molaire acide carboxylique/diol en entrée de ladite étape d'estérification est compris entre 2 et 6, ladite étape d'estérification comprenant au moins une colonne de distillation réactive opérée à une température comprise entre 40 et 280°C, à une pression comprise entre 0,01 et 0,5 MPa, avec un taux de reflux molaire compris entre 0,5 et 10 et un taux de rebouillage molaire compris entre 0,5 et 10, constituée d'une zone mixte de réaction/séparation située entre deux zones de séparation, chacune desdites zones de séparation ayant une efficacité...

Research paper thumbnail of Process for the production of 1,3-butadiene from a feed comprising ethanol

Research paper thumbnail of Method for the deacidification of a gas by an absorbing solution with release of a gaseous effluent from the absorbing solution and washing of this effluent by the regenerated absorbent solution

The invention relates to a method for deacidizing a gas feed comprising acid compounds. The gas f... more The invention relates to a method for deacidizing a gas feed comprising acid compounds. The gas feed is contacted in C1 with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two liquid phases when heated. A gaseous effluent is then released from the absorbent solution laden with acid compounds. At least part of the absorbent solution laden with acid compounds is thermally regenerated and at least a fraction of the regenerated absorbent solution is separated into a water-enriched liquid phase and a liquid phase enriched in reactive compounds. The water-enriched liquid phase is used to wash the gaseous effluent released from the absorbent solution enriched in acid compounds in order to obtain a gaseous effluent depleted in reactive compounds.

Research paper thumbnail of Solution absorbante a base de ν,ν,ν',ν'- tétraéthyldiéthylènetriamine et procédé d'elimination de composes acides d'un effluent gazeux

L'invention concerne l'elimination de composes acides dans un effluent gazeux dans un pro... more L'invention concerne l'elimination de composes acides dans un effluent gazeux dans un procede d'absorption mettant en oeuvre une solution aqueuse de Ν,Ν,Ν',Ν'-Tetraethyldiethylenetriamine. L'invention s'applique avantageusement au traitement du gaz naturel et de gaz d'origine industrielle.

Research paper thumbnail of Deacidification of gas e.g. natural gas comprising acid compounds, comprises contacting gas with regenerated adsorbent solution in aqueous solution, introducing mineral solution in regeneration column, and injecting heat in column

Research paper thumbnail of Correlation between CO2 absorption capacity and amine molecular structures using a High throughput screening methodology

A major amount of greenhouse gas emissions comes from coal-fired power station generating large q... more A major amount of greenhouse gas emissions comes from coal-fired power station generating large quantities of CO2. Post-combustion carbon capture and storage (CCS) using amine solutions is one of the most mature solutions developed to reduce these emissions. However, the benchmark molecule (MEA) suffers from the high energy required to regenerate the solution. Thus, it is necessary to identify amine structures which minimize the energy consumption of the process. In our study, we focus on establishing a correlation between molecular structure and thermodynamics properties of amine solution. First, we use a High Throughput Screening (HTS) experimental device to determine the absorption isotherms of several amine solutions. Then, we build a statistical model using a quantitative structure activity relationship (QSAR) approach, in order to correlate amine structures to their absorption properties. Finally, this statistical model is applied to a set of new molecules to predict their the...

Research paper thumbnail of Process for purifying an aqueous solution comprising diethylacetal

Research paper thumbnail of An integrated process for producing electricity and hydrogen with capture and storage of carbon dioxide

The process comprises producing electricity by combustion of hydrocarbon fuel (1) with an oxidant... more The process comprises producing electricity by combustion of hydrocarbon fuel (1) with an oxidant (2) comprising oxygen produced by an electrolysis unit, where the combustion produces a carbon dioxide (CO 2) rich stream, increasing a pressure of the CO 2rich stream by compression and cooling steps, treating the CO 2rich stream to remove a part of the dust, nitrogen oxides and sulfur oxides, injecting CO 2rich stream into a saline aquifer (6) and evacuating a saline water aquifer (SA), and introducing saline water in the electrolysis unit. The process comprises producing electricity by combustion of hydrocarbon fuel (1) with an oxidant (2) comprising oxygen produced by an electrolysis unit, where the combustion produces a carbon dioxide (CO 2) rich stream, increasing a pressure of the CO 2rich stream by compression and cooling steps, treating the CO 2rich stream to remove a part of the dust, nitrogen oxides and sulfur oxides, injecting CO 2rich stream into a saline aquifer (6) and ev...

Research paper thumbnail of Procedure deacidification of a gas by demixing absorbent solution during regeneration

Procedure deacidification of a gaseous effluent comprising at least one theGroup acid compound co... more Procedure deacidification of a gaseous effluent comprising at least one theGroup acid compound comprising hydrogen sulfide and carbon dioxide, in which it contacts the effluent gaseosocon an absorbent solution, the absorbent solution comprising at least one reactive compound in faseacuosa in a contact zone (C1) to obtain a gaseous effluent depleted in acidic compounds and absorbent unasolucion charged with acidic compounds, selected the absorbent solution for its property deforming two separable liquid phases when it has absorbed a quantity of acidic compounds and when heated a) distilling at least a portion of the absorbent solution charged with acidic compounds in a primerazona regeneration (Z1) to produce a partially regenerated absorbent solution, and wherein the absorbent solution charged with acidic compounds performing the following steps regenerates , b) is extracted at least a portion the partially regenerated first zone deregeneracion (Z1) absorbent solution is separated (...

Research paper thumbnail of A method of removing acidic compounds from a gaseous effluent with an absorbent solution based triamines iii / ii / iii

L'invention concerne l'elimination de composes acides d'un effluent gazeux dans un pr... more L'invention concerne l'elimination de composes acides d'un effluent gazeux dans un procede d'absorption mettant en oeuvre une solution aqueuse contenant une ou plusieurs triamines dans lesquelles les trois fonctions amines ne sont pas reliees entre elles par des cycles et dont les fonctions amines en positions α et ω sont toujours tertiaires et la fonction amine situee en position centrale est toujours secondaire plus ou moins encombree steriquement et qui repondent a la formule generale (I) suivante :

Research paper thumbnail of Controlling the Melting of Kinetically Frozen PBA-b-PAA Micelles via addition of surfactant

HAL (Le Centre pour la Communication Scientifique Directe), 2007

Research paper thumbnail of Copolymères diblocs amphiphiles chargés : d'un comportement colloÏdal à tensioactif

Research paper thumbnail of High throughput screening of amine thermodynamic properties applied to post-combustion CO2 capture process evaluation

Research paper thumbnail of Controlling the Melting of Kinetically Frozen Poly(butyl acrylate-<i>b</i>-acrylic acid) Micelles via Addition of Surfactant

Research paper thumbnail of Characterization of Amphiphilic Diblock Copolymers Synthesized by MADIX Polymerization Process

Macromolecules, Mar 15, 2007

Research paper thumbnail of Kinetics Modeling of the Heterogeneously Catalyzed Esterification of 2,3-Butanediol with Acetic Acid

Industrial & Engineering Chemistry Research, Apr 26, 2016

Research paper thumbnail of Novel graph machine based QSAR approach for the prediction of the adsorption enthalpies of alkanes on zeolites

Catalysis Today, 2011

This paper presents the application of a new machine learning approach called Graph Machines to t... more This paper presents the application of a new machine learning approach called Graph Machines to the prediction of the adsorption enthalpies of linear and branched alkanes on various zeolites. In this approach, the molecules are considered as structured data and are represented by graphs. For each individual of the data set, a mathematical function (graph machine) is built, which structure

Research paper thumbnail of Self-Assembly of Charged Amphiphilic Diblock Copolymers with Insoluble Blocks of Decreasing Hydrophobicity: From Kinetically Frozen Colloids to Macrosurfactants

Research paper thumbnail of Adsorption Kinetics of Amphiphilic Diblock Copolymers: From Kinetically Frozen Colloids to Macrosurfactants

Research paper thumbnail of Correlation between CO2 absorption capacity and amine molecular structures using a High throughput screening methodology

HAL (Le Centre pour la Communication Scientifique Directe), Mar 25, 2012

A major amount of greenhouse gas emissions comes from coal-fired power station generating large q... more A major amount of greenhouse gas emissions comes from coal-fired power station generating large quantities of CO2. Post-combustion carbon capture and storage (CCS) using amine solutions is one of the most mature solutions developed to reduce these emissions. However, the benchmark molecule (MEA) suffers from the high energy required to regenerate the solution. Thus, it is necessary to identify amine structures which minimize the energy consumption of the process. In our study, we focus on establishing a correlation between molecular structure and thermodynamics properties of amine solution. First, we use a High Throughput Screening (HTS) experimental device to determine the absorption isotherms of several amine solutions. Then, we build a statistical model using a quantitative structure activity relationship (QSAR) approach, in order to correlate amine structures to their absorption properties. Finally, this statistical model is applied to a set of new molecules to predict their thermodynamic properties

Research paper thumbnail of Procédé d’estérification d’un diol mettant en œuvre une distillation réactive

L'invention concerne un procédé de conversion alimenté par une charge diol comprenant au moin... more L'invention concerne un procédé de conversion alimenté par une charge diol comprenant au moins 90% poids de diol et une charge acide carboxylique comprenant au moins 80% poids d'acide carboxylique, ledit procédé comprenant au moins : - une étape d'estérification, alimentée par au moins ladite charge diol et au moins ladite charge acide carboxylique, les débits d'alimentation étant ajustés de telle sorte que le ratio molaire acide carboxylique/diol en entrée de ladite étape d'estérification est compris entre 2 et 6, ladite étape d'estérification comprenant au moins une colonne de distillation réactive opérée à une température comprise entre 40 et 280°C, à une pression comprise entre 0,01 et 0,5 MPa, avec un taux de reflux molaire compris entre 0,5 et 10 et un taux de rebouillage molaire compris entre 0,5 et 10, constituée d'une zone mixte de réaction/séparation située entre deux zones de séparation, chacune desdites zones de séparation ayant une efficacité...

Research paper thumbnail of Process for the production of 1,3-butadiene from a feed comprising ethanol

Research paper thumbnail of Method for the deacidification of a gas by an absorbing solution with release of a gaseous effluent from the absorbing solution and washing of this effluent by the regenerated absorbent solution

The invention relates to a method for deacidizing a gas feed comprising acid compounds. The gas f... more The invention relates to a method for deacidizing a gas feed comprising acid compounds. The gas feed is contacted in C1 with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two liquid phases when heated. A gaseous effluent is then released from the absorbent solution laden with acid compounds. At least part of the absorbent solution laden with acid compounds is thermally regenerated and at least a fraction of the regenerated absorbent solution is separated into a water-enriched liquid phase and a liquid phase enriched in reactive compounds. The water-enriched liquid phase is used to wash the gaseous effluent released from the absorbent solution enriched in acid compounds in order to obtain a gaseous effluent depleted in reactive compounds.

Research paper thumbnail of Solution absorbante a base de ν,ν,ν',ν'- tétraéthyldiéthylènetriamine et procédé d'elimination de composes acides d'un effluent gazeux

L'invention concerne l'elimination de composes acides dans un effluent gazeux dans un pro... more L'invention concerne l'elimination de composes acides dans un effluent gazeux dans un procede d'absorption mettant en oeuvre une solution aqueuse de Ν,Ν,Ν',Ν'-Tetraethyldiethylenetriamine. L'invention s'applique avantageusement au traitement du gaz naturel et de gaz d'origine industrielle.

Research paper thumbnail of Deacidification of gas e.g. natural gas comprising acid compounds, comprises contacting gas with regenerated adsorbent solution in aqueous solution, introducing mineral solution in regeneration column, and injecting heat in column

Research paper thumbnail of Correlation between CO2 absorption capacity and amine molecular structures using a High throughput screening methodology

A major amount of greenhouse gas emissions comes from coal-fired power station generating large q... more A major amount of greenhouse gas emissions comes from coal-fired power station generating large quantities of CO2. Post-combustion carbon capture and storage (CCS) using amine solutions is one of the most mature solutions developed to reduce these emissions. However, the benchmark molecule (MEA) suffers from the high energy required to regenerate the solution. Thus, it is necessary to identify amine structures which minimize the energy consumption of the process. In our study, we focus on establishing a correlation between molecular structure and thermodynamics properties of amine solution. First, we use a High Throughput Screening (HTS) experimental device to determine the absorption isotherms of several amine solutions. Then, we build a statistical model using a quantitative structure activity relationship (QSAR) approach, in order to correlate amine structures to their absorption properties. Finally, this statistical model is applied to a set of new molecules to predict their the...

Research paper thumbnail of Process for purifying an aqueous solution comprising diethylacetal

Research paper thumbnail of An integrated process for producing electricity and hydrogen with capture and storage of carbon dioxide

The process comprises producing electricity by combustion of hydrocarbon fuel (1) with an oxidant... more The process comprises producing electricity by combustion of hydrocarbon fuel (1) with an oxidant (2) comprising oxygen produced by an electrolysis unit, where the combustion produces a carbon dioxide (CO 2) rich stream, increasing a pressure of the CO 2rich stream by compression and cooling steps, treating the CO 2rich stream to remove a part of the dust, nitrogen oxides and sulfur oxides, injecting CO 2rich stream into a saline aquifer (6) and evacuating a saline water aquifer (SA), and introducing saline water in the electrolysis unit. The process comprises producing electricity by combustion of hydrocarbon fuel (1) with an oxidant (2) comprising oxygen produced by an electrolysis unit, where the combustion produces a carbon dioxide (CO 2) rich stream, increasing a pressure of the CO 2rich stream by compression and cooling steps, treating the CO 2rich stream to remove a part of the dust, nitrogen oxides and sulfur oxides, injecting CO 2rich stream into a saline aquifer (6) and ev...

Research paper thumbnail of Procedure deacidification of a gas by demixing absorbent solution during regeneration

Procedure deacidification of a gaseous effluent comprising at least one theGroup acid compound co... more Procedure deacidification of a gaseous effluent comprising at least one theGroup acid compound comprising hydrogen sulfide and carbon dioxide, in which it contacts the effluent gaseosocon an absorbent solution, the absorbent solution comprising at least one reactive compound in faseacuosa in a contact zone (C1) to obtain a gaseous effluent depleted in acidic compounds and absorbent unasolucion charged with acidic compounds, selected the absorbent solution for its property deforming two separable liquid phases when it has absorbed a quantity of acidic compounds and when heated a) distilling at least a portion of the absorbent solution charged with acidic compounds in a primerazona regeneration (Z1) to produce a partially regenerated absorbent solution, and wherein the absorbent solution charged with acidic compounds performing the following steps regenerates , b) is extracted at least a portion the partially regenerated first zone deregeneracion (Z1) absorbent solution is separated (...

Research paper thumbnail of A method of removing acidic compounds from a gaseous effluent with an absorbent solution based triamines iii / ii / iii

L'invention concerne l'elimination de composes acides d'un effluent gazeux dans un pr... more L'invention concerne l'elimination de composes acides d'un effluent gazeux dans un procede d'absorption mettant en oeuvre une solution aqueuse contenant une ou plusieurs triamines dans lesquelles les trois fonctions amines ne sont pas reliees entre elles par des cycles et dont les fonctions amines en positions α et ω sont toujours tertiaires et la fonction amine situee en position centrale est toujours secondaire plus ou moins encombree steriquement et qui repondent a la formule generale (I) suivante :