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Linh Dang

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Research paper thumbnail of Comparing the dynamic behaviour of several rubbers filled with silanized silica nanofiller

Polymer International, 2009

BACKGROUND: The effect of the same amount of precipitated silica nanofiller on the curing and dyn... more BACKGROUND: The effect of the same amount of precipitated silica nanofiller on the curing and dynamic properties of different rubbers, including natural rubber (NR) without and with the addition of elemental sulfur (NR with S), synthetic polyisoprene (IR), polybutadiene (BR) and poly(styrene-co-butadiene) copolymer (SBR), was investigated. The silica surfaces were pre-treated with bis(3-triethoxysilylpropyl)tetrasulfane (TESPT) to chemically bond the silica to the rubber. The rubbers were primarily cured by using sulfur in TESPT with the addition of optimum accelerator (TBBS) and activator (ZnO), which helped to form sulfur chemical bonds between the rubber and filler.RESULTS: Cure properties, Mooney viscosity, glass transition temperature, bound rubber and crosslink density along with dynamic properties of the filled rubbers, including tan δ, loss modulus (G″) and storage modulus (G′), were measured as a function of double oscillation amplitude (DSA) from 15 to 1000 µm, temperature...

Research paper thumbnail of Comparing the dynamic behaviour of several rubbers filled with silanized silica nanofiller

Polymer International, 2009

BACKGROUND: The effect of the same amount of precipitated silica nanofiller on the curing and dyn... more BACKGROUND: The effect of the same amount of precipitated silica nanofiller on the curing and dynamic properties of different rubbers, including natural rubber (NR) without and with the addition of elemental sulfur (NR with S), synthetic polyisoprene (IR), polybutadiene (BR) and poly(styrene-co-butadiene) copolymer (SBR), was investigated. The silica surfaces were pre-treated with bis(3-triethoxysilylpropyl)tetrasulfane (TESPT) to chemically bond the silica to the rubber. The rubbers were primarily cured by using sulfur in TESPT with the addition of optimum accelerator (TBBS) and activator (ZnO), which helped to form sulfur chemical bonds between the rubber and filler.RESULTS: Cure properties, Mooney viscosity, glass transition temperature, bound rubber and crosslink density along with dynamic properties of the filled rubbers, including tan δ, loss modulus (G″) and storage modulus (G′), were measured as a function of double oscillation amplitude (DSA) from 15 to 1000 µm, temperature...

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