Luca Palmeri - Academia.edu (original) (raw)

Papers by Luca Palmeri

Water Science and Technology Library, 1996

ABSTRACT In this chapter we present the result of two model exercises aiming at simulating the im... more ABSTRACT In this chapter we present the result of two model exercises aiming at simulating the impact of climate change onto two classes of surface aquifers: lakes and rivers. Subchapter 3.1 focuses on the impact of global warming on the thermal structure of two Italian South alpine lakes: Lake Como and Pusiano. Long term hydrodynamic simulations (1953-2050) were performed using the hydrodynamic model DYRESM (Dynamic Reservoir Simulation Model). DYRESM simulations were forced with downscaled regional climate scenarios undertaken within CIRCE. Our model simulations projected a yearly average temperature increase of 0.04°C y-1 for the period 1970-2000 and 0.03°C y-1 for the period 2001-2050 (A1b IPCC scenario). These results are in line with those detected in long term research studies carried out world-wide. This temperature increase is first responsible for a general increase of the water column stability and for a reduction of the mass transfer between deep and surface waters with direct implications on the oxygen and nutrient cycles. The magnitude of the temperature increase is also sufficient to impact on the growth of phytoplankton populations and it is likely one of the concurrent causes promoting the massive cyanobacteria blooms, recently detected in the two Italian case studies and in different lake environments in Europe. Subchapter 3.2 approaches the problem of establishing a methodology to estimate the average yearly nutrient (phosphorus and nitrogen) river loads under present climate conditions and under the forcing of climate change. The case study is the Po River the largest hydrological basin in Italy and the third tributary of the Mediterranean semi-enclosed basin. The methodology developed in this study is based on a hierarchy of different numerical models which allowed to feed the MONERIS model (MOdeling Nutrient Emissions into River System) with the necessary meteorological and hydrological forcing. MONERIS was previously calibrated (1990-1995) and validated (1996-2000) under past conditions and then run under current condi-tions to define a control experiment (CE). Current nutrient loads have been esti-mated in 170,000 and 8,000 t y-1 respectively for nitrogen and phosphorus. Ap-proximately 70% of the nitrogen load is from diffuse sources while 65% of the phosphorus load originates from point sources. Nutrient loads projections at 2100 (under different IPCC scenarios) allowed to estimate that both nitrogen and phos-phorus loads are strictly dependent on the resident population which is responsible of a 61% and 41% increase respectively for nitrogen and phosphorus. Projected nutrient load variations were found to be negligible when holding the resident population constant. Finally the phosphorus load is markedly influenced by the efficiency of the waste water treatment plants (WWTPs).

Ecological Processes Handbook, 2013

Transactions of the American Fisheries Society, 2016

To describe the life histories and demography of a fluvial population of Bull Trout Salvelinus co... more To describe the life histories and demography of a fluvial population of Bull Trout Salvelinus confluentus, we PIT-tagged and radio-tagged Bull Trout captured in Mill Creek, a tributary of the Walla Walla River (Washington-Oregon), during 1998-2009. Adult abundance declined 63% during 2006-2010, driven primarily by a 10-fold reduction in subadult-to-adult returns. Larger subadults and fall-winter emigrants survived at higher rates, but they were a small proportion of the subadult migrants. The survival rates of larger, generally older adults were also more than 40% greater than those of smaller adults. Changes in abundance influenced other characteristics of the population. For example, adult upstream movement into spawning areas during 1999-2005 peaked in late July, whereas the smaller runs observed during 2006-2010 peaked in early September, and the relationship between fish size and migration timing shifted. Unlike many adfluvial populations, more than 90% of the adults in Mill Creek spawned annually. Bull Trout that spawned in main-stem Mill Creek were primarily larger migratory adults; however, about 20% of the large adults were strictly or intermittently resident, remaining in the spawning area year-round. The downstream extent of individuals' migratory distributions varied greatly-from just downstream of the spawning area to the mouth of the Walla Walla River and potentially hundreds of kilometers into the Columbia River. Despite a large sample size of radio-tagged fish, radiotelemetry substantially underestimated the distribution and range that were evident from PIT tag detections. Life history terms such as "migratory," "resident," and "fluvial" and their associations with body size, movement, and distribution are useful for describing general patterns, but they fail to reflect the diversity and complexity within and among populations. For Bull Trout in Mill Creek, that life history diversity, including small, resident adult forms in the tributaries and a continuum of distribution for large adults, maximizes the use of available habitat and likely contributes to the population's persistence.

North American Journal of Fisheries Management, 1997

Page 1. North American Journal <>fFisheries Management 17:1065-1078. 1997 <*... more Page 1. North American Journal <>fFisheries Management 17:1065-1078. 1997 <*' Copyright by the American Fisheries Society 1997 Introgression and Susceptibility to Disease in a Wild Population of Rainbow Trout KENNETH ...

Ecological Processes Handbook, 2013

CICIMAR Oceánides, 2012

We tested the hypothesis that ecosystem metabolism follows a quarter power scaling relation, anal... more We tested the hypothesis that ecosystem metabolism follows a quarter power scaling relation, analogous to organisms. Logarithm of Biomass/Production (B/P) to Trophic Level (TL) relationship was estimated to 98 trophic models of aquatic ecosystems. A normal distribution of the slopes gives a modal value of 0.64, which was significantly different of the theoretical value of 0.75 (p0.05). We also tested for error in both variables, Log (B/P) and TL, through a Reduced Major Axis regression with similar results, with a modal value of 0.756 (p>0.05). We also explored a geographic distribution showing no significant relation (p>0.05) to latitude and between different regions of the world. We conclude that: a) ecosystem metabolism follows the quarter-power scaling rule; b) transfer efficiency between TL plays a relevant role characterizing local attributes to ecosystem metabolism; and c) there is neither latitudinal nor geographic differences. These findings confirm the existence of a...

Marine Pollution Bulletin, 2014

The northern Gulf of Aqaba is an oligotrophic water body hosting valuable coral reefs. In the Gul... more The northern Gulf of Aqaba is an oligotrophic water body hosting valuable coral reefs. In the Gulf, phytoplankton dynamics are driven by an annual cycle of stratification and mixing. Superimposed on that fairly regular pattern was the establishment of a shallow-water fish-farm initiative that increased gradually until its activity was terminated in June 2008. Nutrient, water temperature, irradiation, phytoplankton data gathered in the area during the years 2007-2009, covering the peak of the fish-farm activity and its cessation, were analyzed by means of statistical analyses and ecological models of phytoplankton dynamics. Two datasets, one from an open water station and one next to the fish farms, were used. Results show that nutrient concentrations and, consequently, phytoplankton abundance and seasonal succession were radically altered by the pollution originating from the fish-farm in the sampling station closer to it, and also that the fish-farm might even have influenced the open water station.

Regional Environmental Change, 2005

... The Driver-Pressure-State-Impact-Response (DPSIR) approach ... An ad-hoc DPSIR framework was ... more ... The Driver-Pressure-State-Impact-Response (DPSIR) approach ... An ad-hoc DPSIR framework was developed for the Po River Catchment and the North Adriatic coastal zone in order to elaborate pos-sible strategies for controlling and/or reducing eutro-phication. ...

Ecology and Society, 2014

The Mediterranean region is of fundamental importance to Europe given its strategic position. The... more The Mediterranean region is of fundamental importance to Europe given its strategic position. The responsibility for its overall ecosystem integrity is shared by European Union Member States (EU-MS) and other Mediterranean countries. A juxtaposition of overlapping governance instruments occurred recently in the region, with the implementation of both the Marine Strategy Framework Directive (MSFD) for EU-MS and the Ecosystem Approach Strategy (ECAP) for all Mediterranean countries, including EU-MS. Both MSFD and ECAP are structured around vision-driven processes to achieve Good Environmental Status and a Healthy Environment, respectively. These processes have clear ecosystem-based, integrated policy objectives to guarantee the preservation and integrity of Mediterranean marine ecosystem goods and services. However, adoption of these instruments, especially those related to the new EU-MS directives on marine policy, could result in a governance gap in addition to the well-known economic gap between the EU and the non-EU political blocs. We identify two complementary requirements for effective implementation of both MSFD and ECAP that could work together to reduce this gap, to ensure a better alignment between MSFD and ECAP and better planning for stakeholder engagement. These are key issues for the future success of these instruments in a Mediterranean region where discrepancies between societal and ecological objectives may pose a challenge to these processes.

Waste Management, 2013

The Biopotentiality Index is a landscape ecology indicator, which can be used to estimate the lat... more The Biopotentiality Index is a landscape ecology indicator, which can be used to estimate the latent energy of a given land and to assess the environmental impacts due to the loss of naturalness on a landscape scale. This indicator has been applied to estimate the effectiveness of the measures put in place to provide an environmental compensation for the revamping of a composting plant. These compensation measures are represented by a green belt with a minimum width of 25 m all around the plant, representing both a windbreak and a buffer zone, and by two wide wooded zones acting as core natural areas. This case-study shows that the compensation index could be used as a key tool in order to negotiate the acceptance of waste treatment plant with the population.

The loss of coastal habitats is a widespread problem in Europe. To protect the intertidal salt ma... more The loss of coastal habitats is a widespread problem in Europe. To protect the intertidal salt marshes of the lagoon of Venice from the erosion due to natural and human causes which is diffusely and intensely impacting them, the European Commission has funded the demonstrative project LIFE VIMINE. LIFE VIMINE aims to protect the most interior, hard-to-access salt marshes in the northern lagoon of Venice through an integrated approach, whose core is the prevention of erosion through numerous, small but spatially-diffuse soil-bioengineering protections works, mainly placed through semi-manual labour and with low impact on the environment and the landscape. The effectiveness of protection works in the long term is ensured through routine, temporally-continuous and spatially-diffuse actions of monitoring and maintenance. This method contrasts the common approach to managing hydraulic risk and erosion in Italy which is based on large, one-off and irreversible protection actions. The sust...

Science of The Total Environment

Perfluoroalkyl acids (PFAAs), particularly short-chained ones, have high potential for crop uptak... more Perfluoroalkyl acids (PFAAs), particularly short-chained ones, have high potential for crop uptake, posing a threat to human health in contaminated areas. There is a scarcity of studies using contaminated water as the medium for PFAAs delivery to crops, and a lack of data on the partitioning of PFAA mixtures in growing media. In this context, a controlled experimental study was carried out in a greenhouse to investigate the uptake of a PFAA mixture into red chicory, a typical crop from a major PFAA contamination hot-spot in northern Italy, under treatments with environmentally relevant concentrations in spiked irrigation water and soil, separately and simultaneously. To our knowledge, this is the first study involving multiple exposure media and laboratory adsorption/desorption batch tests as a way of assessing the decrease in the bioavailability of PFAAs from soil. Exposure concentrations for each of the 9 utilized PFAAs were 0, 1, 10 and 80 µg/L in irrigation water and 0, 100 and 200 ng/gdw in soil, combined into 12 treatments. The highest bioaccumulation was measured for PFBA in roots (maximum of 43 µg/gdw), followed by leaves and heads of the chicory plants in all treatments, with the concentrations exponentially decreasing with an increasing PFAA chain length in all plant compartments. The use of irrigation water as the delivery medium increased the transport of PFAAs to the aerial chicory parts, long-chain substances in particular. Additionally, the distribution of PFAAs in the soil was assessed by depth and compared with laboratory measured soil-water equilibrium partition coefficients, revealing only partial dependency of PFAAs bioavailability on the adsorption in soil.

Environment international, Jan 20, 2018

Over the past decades, per- and polyfluoroalkyl substances (PFASs) found in environmental matrice... more Over the past decades, per- and polyfluoroalkyl substances (PFASs) found in environmental matrices worldwide have raised concerns due to their toxicity, ubiquity and persistence. A widespread pollution of groundwater and surface waters caused by PFASs in Northern Italy has been recently discovered, becoming a major environmental issue, also because the exact risk for humans and nature posed by this contamination is unclear. Here, the Po River in Northern Italy was selected as a study area to assess the ecological risk posed by perfluoroalkyl acids (PFAAs), a class of PFASs, considering the noticeable concentration of various PFAAs detected in the Po waters over the past years. Moreover, the Po has a large environmental and socio-economic importance: it is the largest Italian river and drains a densely inhabited, intensely cultivated and heavily industrialized watershed. Predicted no-effect concentrations (PNECs) were derived using two regulated methodologies, assessment factors (AFs...

Ecological Modelling, 2016

Ecological modelling has the potential to increase the realism of chemical risk assessment for be... more Ecological modelling has the potential to increase the realism of chemical risk assessment for better informed risk management and decision making meeting the protection goals and requirements of the EU's chemicals- and water-related regulations. We developed a food web model of the final lowland section of the longest Italian river (Po) to assess the importance of ecological interactions in setting protective thresholds for river ecosystems exposed to chemicals discharged via wastewater. An integrated 14 compartment model was setup using AQUATOX 3.1, providing a dynamic, quantitative representation of the main functional groups in the food web. To our knowledge, this is the first time that the functioning of the Po ecosystem is quantitatively described. The model was calibrated against observations of biomass density of riverine biota, as typically available for a large lowland river in Europe. The role of ecological interactions on the response of the modelled organisms to chemical exposure was tested on realistic and hypothetical exposure scenarios for two compounds contained in home and personal care products: the anionic surfactant linear alkylbenzene sulphonate and the antimicrobial triclosan. At realistic exposure concentrations the model showed no significant effect compared to control simulations. At hypothetical higher exposure, effects resulting from complex ecosystem-scale interactions emerge. Depending on the organism's position in the food web, indirect effects due to ecological interactions can either amplify or mitigate the effect of direct toxicity. Model results indicate that organisms’ responses to chemicals in real ecosystems is poorly correlated to their direct toxicity (i.e. measured by L/ECX values) for a range of simulated exposure, including concentrations equal to the reported PNEC values. AQUATOX is a useful tool to investigate the relative importance of direct toxicity and ecological interactions, but at this stage it is difficult to use it for prospective chemical risk assessment, given the underlying model uncertainties and the practical limitations of field scale evaluations. An improvement of the quantitative monitoring of feeding preferences and abundance over time of the most representative species within each functional group would be of great help to refine the model parameterisation and calibration. Nonetheless, the development of river ecosystem model scenarios is a stepping stone towards the incorporation of ecological modelling in risk assessment. When extensively tested on different scenarios AQUATOX provides a useful platform, which can be linked to mechanistic effect models as long as this component can be evaluated in controlled settings (i.e. laboratory or mesocosm scale).

Science of The Total Environment, 2016

The risk of air quality degradation is of considerable concern particularly for those airports th... more The risk of air quality degradation is of considerable concern particularly for those airports that are located near urban areas. The ability to quantitatively predict the effects of air pollutants originated by airport operations is important for assessing air quality and the related impacts on human health. Current emission regulations have focused on local air quality in the proximity of airports. However, an integrated study should consider the effects of meteorological events, at both regional and local level, that can affect the dispersion and the deposition of exhausts. Rigorous scientific studies and extensive experimental data could contribute to the analysis of the impacts of airports expansion plans. This paper is focused on the analysis of the effects of meteorology on aircraft emission for the Marco Polo Airport in Venice. This is the most important international airport in the eastern part of the Po' Valley, one of the most polluted area in Europe. Air pollution is exacerbated by meteorology that is a combination of large and local scale effects that do not allow significant dispersion. Moreover, the airport is located near Venice, a city of noteworthy cultural and architectural relevance, and nearby the lagoon that hosts several areas of outstanding ecological importance at European level (Natura 2000 sites). Dispersion and deposit of the main aircraft exhausts (NOx, HC and CO) have been evaluated by using a Lagrangian particle model. Spatial and temporal aircraft exhaust dispersion has been analyzed for LTO cycle. Aircraft taxiing resulted to be the most impacting aircraft operation especially for the airport working area and its surroundings, however occasionally peaks may be observed even at high altitudes when cruise mode starts. Mixing height can affect concentrations more significantly than the concentrations in the exhausts themselves. An increase of HC and CO concentrations (15-50%) has been observed during specific meteorological events.

Water Science and Technology Library, 1996

ABSTRACT In this chapter we present the result of two model exercises aiming at simulating the im... more ABSTRACT In this chapter we present the result of two model exercises aiming at simulating the impact of climate change onto two classes of surface aquifers: lakes and rivers. Subchapter 3.1 focuses on the impact of global warming on the thermal structure of two Italian South alpine lakes: Lake Como and Pusiano. Long term hydrodynamic simulations (1953-2050) were performed using the hydrodynamic model DYRESM (Dynamic Reservoir Simulation Model). DYRESM simulations were forced with downscaled regional climate scenarios undertaken within CIRCE. Our model simulations projected a yearly average temperature increase of 0.04°C y-1 for the period 1970-2000 and 0.03°C y-1 for the period 2001-2050 (A1b IPCC scenario). These results are in line with those detected in long term research studies carried out world-wide. This temperature increase is first responsible for a general increase of the water column stability and for a reduction of the mass transfer between deep and surface waters with direct implications on the oxygen and nutrient cycles. The magnitude of the temperature increase is also sufficient to impact on the growth of phytoplankton populations and it is likely one of the concurrent causes promoting the massive cyanobacteria blooms, recently detected in the two Italian case studies and in different lake environments in Europe. Subchapter 3.2 approaches the problem of establishing a methodology to estimate the average yearly nutrient (phosphorus and nitrogen) river loads under present climate conditions and under the forcing of climate change. The case study is the Po River the largest hydrological basin in Italy and the third tributary of the Mediterranean semi-enclosed basin. The methodology developed in this study is based on a hierarchy of different numerical models which allowed to feed the MONERIS model (MOdeling Nutrient Emissions into River System) with the necessary meteorological and hydrological forcing. MONERIS was previously calibrated (1990-1995) and validated (1996-2000) under past conditions and then run under current condi-tions to define a control experiment (CE). Current nutrient loads have been esti-mated in 170,000 and 8,000 t y-1 respectively for nitrogen and phosphorus. Ap-proximately 70% of the nitrogen load is from diffuse sources while 65% of the phosphorus load originates from point sources. Nutrient loads projections at 2100 (under different IPCC scenarios) allowed to estimate that both nitrogen and phos-phorus loads are strictly dependent on the resident population which is responsible of a 61% and 41% increase respectively for nitrogen and phosphorus. Projected nutrient load variations were found to be negligible when holding the resident population constant. Finally the phosphorus load is markedly influenced by the efficiency of the waste water treatment plants (WWTPs).

Ecological Processes Handbook, 2013

Transactions of the American Fisheries Society, 2016

To describe the life histories and demography of a fluvial population of Bull Trout Salvelinus co... more To describe the life histories and demography of a fluvial population of Bull Trout Salvelinus confluentus, we PIT-tagged and radio-tagged Bull Trout captured in Mill Creek, a tributary of the Walla Walla River (Washington-Oregon), during 1998-2009. Adult abundance declined 63% during 2006-2010, driven primarily by a 10-fold reduction in subadult-to-adult returns. Larger subadults and fall-winter emigrants survived at higher rates, but they were a small proportion of the subadult migrants. The survival rates of larger, generally older adults were also more than 40% greater than those of smaller adults. Changes in abundance influenced other characteristics of the population. For example, adult upstream movement into spawning areas during 1999-2005 peaked in late July, whereas the smaller runs observed during 2006-2010 peaked in early September, and the relationship between fish size and migration timing shifted. Unlike many adfluvial populations, more than 90% of the adults in Mill Creek spawned annually. Bull Trout that spawned in main-stem Mill Creek were primarily larger migratory adults; however, about 20% of the large adults were strictly or intermittently resident, remaining in the spawning area year-round. The downstream extent of individuals' migratory distributions varied greatly-from just downstream of the spawning area to the mouth of the Walla Walla River and potentially hundreds of kilometers into the Columbia River. Despite a large sample size of radio-tagged fish, radiotelemetry substantially underestimated the distribution and range that were evident from PIT tag detections. Life history terms such as "migratory," "resident," and "fluvial" and their associations with body size, movement, and distribution are useful for describing general patterns, but they fail to reflect the diversity and complexity within and among populations. For Bull Trout in Mill Creek, that life history diversity, including small, resident adult forms in the tributaries and a continuum of distribution for large adults, maximizes the use of available habitat and likely contributes to the population's persistence.

North American Journal of Fisheries Management, 1997

Page 1. North American Journal <>fFisheries Management 17:1065-1078. 1997 <*... more Page 1. North American Journal <>fFisheries Management 17:1065-1078. 1997 <*' Copyright by the American Fisheries Society 1997 Introgression and Susceptibility to Disease in a Wild Population of Rainbow Trout KENNETH ...

Ecological Processes Handbook, 2013

CICIMAR Oceánides, 2012

We tested the hypothesis that ecosystem metabolism follows a quarter power scaling relation, anal... more We tested the hypothesis that ecosystem metabolism follows a quarter power scaling relation, analogous to organisms. Logarithm of Biomass/Production (B/P) to Trophic Level (TL) relationship was estimated to 98 trophic models of aquatic ecosystems. A normal distribution of the slopes gives a modal value of 0.64, which was significantly different of the theoretical value of 0.75 (p0.05). We also tested for error in both variables, Log (B/P) and TL, through a Reduced Major Axis regression with similar results, with a modal value of 0.756 (p>0.05). We also explored a geographic distribution showing no significant relation (p>0.05) to latitude and between different regions of the world. We conclude that: a) ecosystem metabolism follows the quarter-power scaling rule; b) transfer efficiency between TL plays a relevant role characterizing local attributes to ecosystem metabolism; and c) there is neither latitudinal nor geographic differences. These findings confirm the existence of a...

Marine Pollution Bulletin, 2014

The northern Gulf of Aqaba is an oligotrophic water body hosting valuable coral reefs. In the Gul... more The northern Gulf of Aqaba is an oligotrophic water body hosting valuable coral reefs. In the Gulf, phytoplankton dynamics are driven by an annual cycle of stratification and mixing. Superimposed on that fairly regular pattern was the establishment of a shallow-water fish-farm initiative that increased gradually until its activity was terminated in June 2008. Nutrient, water temperature, irradiation, phytoplankton data gathered in the area during the years 2007-2009, covering the peak of the fish-farm activity and its cessation, were analyzed by means of statistical analyses and ecological models of phytoplankton dynamics. Two datasets, one from an open water station and one next to the fish farms, were used. Results show that nutrient concentrations and, consequently, phytoplankton abundance and seasonal succession were radically altered by the pollution originating from the fish-farm in the sampling station closer to it, and also that the fish-farm might even have influenced the open water station.

Regional Environmental Change, 2005

... The Driver-Pressure-State-Impact-Response (DPSIR) approach ... An ad-hoc DPSIR framework was ... more ... The Driver-Pressure-State-Impact-Response (DPSIR) approach ... An ad-hoc DPSIR framework was developed for the Po River Catchment and the North Adriatic coastal zone in order to elaborate pos-sible strategies for controlling and/or reducing eutro-phication. ...

Ecology and Society, 2014

The Mediterranean region is of fundamental importance to Europe given its strategic position. The... more The Mediterranean region is of fundamental importance to Europe given its strategic position. The responsibility for its overall ecosystem integrity is shared by European Union Member States (EU-MS) and other Mediterranean countries. A juxtaposition of overlapping governance instruments occurred recently in the region, with the implementation of both the Marine Strategy Framework Directive (MSFD) for EU-MS and the Ecosystem Approach Strategy (ECAP) for all Mediterranean countries, including EU-MS. Both MSFD and ECAP are structured around vision-driven processes to achieve Good Environmental Status and a Healthy Environment, respectively. These processes have clear ecosystem-based, integrated policy objectives to guarantee the preservation and integrity of Mediterranean marine ecosystem goods and services. However, adoption of these instruments, especially those related to the new EU-MS directives on marine policy, could result in a governance gap in addition to the well-known economic gap between the EU and the non-EU political blocs. We identify two complementary requirements for effective implementation of both MSFD and ECAP that could work together to reduce this gap, to ensure a better alignment between MSFD and ECAP and better planning for stakeholder engagement. These are key issues for the future success of these instruments in a Mediterranean region where discrepancies between societal and ecological objectives may pose a challenge to these processes.

Waste Management, 2013

The Biopotentiality Index is a landscape ecology indicator, which can be used to estimate the lat... more The Biopotentiality Index is a landscape ecology indicator, which can be used to estimate the latent energy of a given land and to assess the environmental impacts due to the loss of naturalness on a landscape scale. This indicator has been applied to estimate the effectiveness of the measures put in place to provide an environmental compensation for the revamping of a composting plant. These compensation measures are represented by a green belt with a minimum width of 25 m all around the plant, representing both a windbreak and a buffer zone, and by two wide wooded zones acting as core natural areas. This case-study shows that the compensation index could be used as a key tool in order to negotiate the acceptance of waste treatment plant with the population.

The loss of coastal habitats is a widespread problem in Europe. To protect the intertidal salt ma... more The loss of coastal habitats is a widespread problem in Europe. To protect the intertidal salt marshes of the lagoon of Venice from the erosion due to natural and human causes which is diffusely and intensely impacting them, the European Commission has funded the demonstrative project LIFE VIMINE. LIFE VIMINE aims to protect the most interior, hard-to-access salt marshes in the northern lagoon of Venice through an integrated approach, whose core is the prevention of erosion through numerous, small but spatially-diffuse soil-bioengineering protections works, mainly placed through semi-manual labour and with low impact on the environment and the landscape. The effectiveness of protection works in the long term is ensured through routine, temporally-continuous and spatially-diffuse actions of monitoring and maintenance. This method contrasts the common approach to managing hydraulic risk and erosion in Italy which is based on large, one-off and irreversible protection actions. The sust...

Science of The Total Environment

Perfluoroalkyl acids (PFAAs), particularly short-chained ones, have high potential for crop uptak... more Perfluoroalkyl acids (PFAAs), particularly short-chained ones, have high potential for crop uptake, posing a threat to human health in contaminated areas. There is a scarcity of studies using contaminated water as the medium for PFAAs delivery to crops, and a lack of data on the partitioning of PFAA mixtures in growing media. In this context, a controlled experimental study was carried out in a greenhouse to investigate the uptake of a PFAA mixture into red chicory, a typical crop from a major PFAA contamination hot-spot in northern Italy, under treatments with environmentally relevant concentrations in spiked irrigation water and soil, separately and simultaneously. To our knowledge, this is the first study involving multiple exposure media and laboratory adsorption/desorption batch tests as a way of assessing the decrease in the bioavailability of PFAAs from soil. Exposure concentrations for each of the 9 utilized PFAAs were 0, 1, 10 and 80 µg/L in irrigation water and 0, 100 and 200 ng/gdw in soil, combined into 12 treatments. The highest bioaccumulation was measured for PFBA in roots (maximum of 43 µg/gdw), followed by leaves and heads of the chicory plants in all treatments, with the concentrations exponentially decreasing with an increasing PFAA chain length in all plant compartments. The use of irrigation water as the delivery medium increased the transport of PFAAs to the aerial chicory parts, long-chain substances in particular. Additionally, the distribution of PFAAs in the soil was assessed by depth and compared with laboratory measured soil-water equilibrium partition coefficients, revealing only partial dependency of PFAAs bioavailability on the adsorption in soil.

Environment international, Jan 20, 2018

Over the past decades, per- and polyfluoroalkyl substances (PFASs) found in environmental matrice... more Over the past decades, per- and polyfluoroalkyl substances (PFASs) found in environmental matrices worldwide have raised concerns due to their toxicity, ubiquity and persistence. A widespread pollution of groundwater and surface waters caused by PFASs in Northern Italy has been recently discovered, becoming a major environmental issue, also because the exact risk for humans and nature posed by this contamination is unclear. Here, the Po River in Northern Italy was selected as a study area to assess the ecological risk posed by perfluoroalkyl acids (PFAAs), a class of PFASs, considering the noticeable concentration of various PFAAs detected in the Po waters over the past years. Moreover, the Po has a large environmental and socio-economic importance: it is the largest Italian river and drains a densely inhabited, intensely cultivated and heavily industrialized watershed. Predicted no-effect concentrations (PNECs) were derived using two regulated methodologies, assessment factors (AFs...

Ecological Modelling, 2016

Ecological modelling has the potential to increase the realism of chemical risk assessment for be... more Ecological modelling has the potential to increase the realism of chemical risk assessment for better informed risk management and decision making meeting the protection goals and requirements of the EU's chemicals- and water-related regulations. We developed a food web model of the final lowland section of the longest Italian river (Po) to assess the importance of ecological interactions in setting protective thresholds for river ecosystems exposed to chemicals discharged via wastewater. An integrated 14 compartment model was setup using AQUATOX 3.1, providing a dynamic, quantitative representation of the main functional groups in the food web. To our knowledge, this is the first time that the functioning of the Po ecosystem is quantitatively described. The model was calibrated against observations of biomass density of riverine biota, as typically available for a large lowland river in Europe. The role of ecological interactions on the response of the modelled organisms to chemical exposure was tested on realistic and hypothetical exposure scenarios for two compounds contained in home and personal care products: the anionic surfactant linear alkylbenzene sulphonate and the antimicrobial triclosan. At realistic exposure concentrations the model showed no significant effect compared to control simulations. At hypothetical higher exposure, effects resulting from complex ecosystem-scale interactions emerge. Depending on the organism's position in the food web, indirect effects due to ecological interactions can either amplify or mitigate the effect of direct toxicity. Model results indicate that organisms’ responses to chemicals in real ecosystems is poorly correlated to their direct toxicity (i.e. measured by L/ECX values) for a range of simulated exposure, including concentrations equal to the reported PNEC values. AQUATOX is a useful tool to investigate the relative importance of direct toxicity and ecological interactions, but at this stage it is difficult to use it for prospective chemical risk assessment, given the underlying model uncertainties and the practical limitations of field scale evaluations. An improvement of the quantitative monitoring of feeding preferences and abundance over time of the most representative species within each functional group would be of great help to refine the model parameterisation and calibration. Nonetheless, the development of river ecosystem model scenarios is a stepping stone towards the incorporation of ecological modelling in risk assessment. When extensively tested on different scenarios AQUATOX provides a useful platform, which can be linked to mechanistic effect models as long as this component can be evaluated in controlled settings (i.e. laboratory or mesocosm scale).

Science of The Total Environment, 2016

The risk of air quality degradation is of considerable concern particularly for those airports th... more The risk of air quality degradation is of considerable concern particularly for those airports that are located near urban areas. The ability to quantitatively predict the effects of air pollutants originated by airport operations is important for assessing air quality and the related impacts on human health. Current emission regulations have focused on local air quality in the proximity of airports. However, an integrated study should consider the effects of meteorological events, at both regional and local level, that can affect the dispersion and the deposition of exhausts. Rigorous scientific studies and extensive experimental data could contribute to the analysis of the impacts of airports expansion plans. This paper is focused on the analysis of the effects of meteorology on aircraft emission for the Marco Polo Airport in Venice. This is the most important international airport in the eastern part of the Po' Valley, one of the most polluted area in Europe. Air pollution is exacerbated by meteorology that is a combination of large and local scale effects that do not allow significant dispersion. Moreover, the airport is located near Venice, a city of noteworthy cultural and architectural relevance, and nearby the lagoon that hosts several areas of outstanding ecological importance at European level (Natura 2000 sites). Dispersion and deposit of the main aircraft exhausts (NOx, HC and CO) have been evaluated by using a Lagrangian particle model. Spatial and temporal aircraft exhaust dispersion has been analyzed for LTO cycle. Aircraft taxiing resulted to be the most impacting aircraft operation especially for the airport working area and its surroundings, however occasionally peaks may be observed even at high altitudes when cruise mode starts. Mixing height can affect concentrations more significantly than the concentrations in the exhausts themselves. An increase of HC and CO concentrations (15-50%) has been observed during specific meteorological events.