Milena Di Deo - Academia.edu (original) (raw)

Papers by Milena Di Deo

Research paper thumbnail of ChemInform Abstract: A Simple, Efficient, and General Method for the Conversion of Alcohols into Alkyl Iodides by a CeCl3×7H2O/NaI System in Acetonitrile

Research paper thumbnail of Oxidation of dibenzothiophene by hydrogen peroxide in the presence of bis(acetylacetonato)oxovanadium(IV)

Fuel Processing Technology, 2011

In the presence of bis(acetylacetonato)oxovanadium(IV), dibenzothiophene was oxidized by hydrogen... more In the presence of bis(acetylacetonato)oxovanadium(IV), dibenzothiophene was oxidized by hydrogen peroxide to form sulfoxide and sulfone products. The percentage of dibenzothiophene remaining after the oxidation and the ratio of these oxidation products, as determined by 1H NMR spectroscopy, was largely dependent on the solvent used. Reactions in acetonitrile consumed more than 99% of the dibenzothiophene in the reaction and yielded

Research paper thumbnail of Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti‐Markovnikov Regioselectivity, Formation of α,β‐Unsaturated Products and Catalytic Decarbonylation to 1‐Alkenes

European Journal of Inorganic Chemistry, 2004

Ruthenium catalysts — water‐soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hyd... more Ruthenium catalysts — water‐soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes — proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1‐Phenyl‐2‐propyn‐1‐ol underwent an unprecedented catalytic hydration‐decarbonylation‐dehydration reaction, giving rise to styrene and carbon monoxide; 2‐propyn‐1‐ol and 3‐butyn‐2‐ol gave predominantly the products of anti‐Markovnikov addition, together with products of hydration‐dehydration (α,β‐rearrangement) and, to a minor extent, the decarbonylation products, ethene or propene, respectively. Hydrations were also conducted in D2O, giving indications of the mechanism of the reactions and apparently ruling out the allenylidene route for the α,β‐rearrangement. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

Research paper thumbnail of Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti‐Markovnikov Regioselectivity, Formation of α,β‐Unsaturated Products and Catalytic Decarbonylation to 1‐Alkenes

European Journal of Inorganic Chemistry, Feb 1, 2004

Ruthenium catalysts-water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydro... more Ruthenium catalysts-water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes-proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1-Phenyl-2-propyn-1-ol underwent an unprecedented catalytic hydration-decarbonylation-dehydration reaction, giving rise to styrene and carbon monoxide; 2-propyn-1-ol and 3-butyn-2ol gave predominantly the products of anti-Markovnikov ad-[a

Research paper thumbnail of A Simple, Efficient, and General Method for the Conversion of Alcohols into Alkyl Iodides by a CeCl 3 ·7H 2 O/NaI System in Acetonitrile

The Journal of Organic Chemistry, May 1, 2000

... Giuseppe Bartoli, Giustino Di Antonio, Riccardo Giovannini, Sandra Giuli, Silvia Lanari, Meli... more ... Giuseppe Bartoli, Giustino Di Antonio, Riccardo Giovannini, Sandra Giuli, Silvia Lanari, Melissa Paoletti, and Enrico Marcantoni. The ... Giuseppe Bartoli, Marcella Bosco, Arianna Giuliani, Enrico Marcantoni, Alessandro Palmieri, Marino Petrini, and Letizia Sambri. The Journal of ...

Research paper thumbnail of Oxidation of dibenzothiophene by hydrogen peroxide or monopersulfate and metal?sulfophthalocyanine catalysts: an easy access to biphenylsultone or 2-(2?-hydroxybiphenyl)sulfonate under mild conditions

New Journal of Chemistry, 2003

... Dibenzothiophene (DBT) and its alkylated analogues are among the most abundant polycyclic aro... more ... Dibenzothiophene (DBT) and its alkylated analogues are among the most abundant polycyclic aromatic sulfur hydrocarbons (PASH) in crude oils and are usually selected for model studies of desulfurization, both reductive and oxidative.1 In December 2000, the US EPA issued ...

Research paper thumbnail of Thermal stability and photostability of water solutions of sulfophthalocyanines of Ru(II), Cu(II), Ni(II), Fe(III) and Co(II)

Journal of Organometallic Chemistry, 2005

The thermal and photochemical stabilities were investigated for tetrasulfophthalocyanines of Cu, ... more The thermal and photochemical stabilities were investigated for tetrasulfophthalocyanines of Cu, Co, Ni, Fe and Ru (MPcS) and for two monosulfophthalocyanines of Ru, either without (RuPcS1) or with the coordination of two units of DMSO in apical positions ([RuPcS1(DMSO) 2 ]DMSO). The thermal degradation of all of the studied complexes never showed the formation of spectroscopically detectable intermediates. CuPcS was the most stable complex, while all of the Ru-sulfophthalocyanines were particularly prone to thermal degradation. Photodegradation showed a better selectivity, and as with thermal degradation, the order of reactivity goes from the most stable CuPcS, to the least stable Ru-sulfophthalocyanines (RuPcS, RuPcS1 and [RuPcS(DMSO) 2 ]DMSO). In particular, when the RuPcS complex was irradiated, a stable intermediate was detected that had an absorption band at 532 nm and a mass spectrum attributable to the tetrasulfophthalocyanine from oxidative ring cleavage by the action of the singlet oxygen formed via 1 *RuPcS photosensitization. The most probable molecular formula demonstrates a new complex, with a cleaved ring containing an-N@O group and two-OH groups that are all bonded at the two extremities of the open-chain molecule.

Research paper thumbnail of Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti-Markovnikov Regioselectivity, Formation ofα,β-Unsaturated Products and Catalytic Decarbonylation to 1-Alkenes

European Journal of Inorganic Chemistry, 2004

Ruthenium catalysts — water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hyd... more Ruthenium catalysts — water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes — proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1-Phenyl-2-propyn-1-ol underwent an unprecedented catalytic hydration-decarbonylation-dehydration reaction, giving rise to styrene and carbon monoxide; 2-propyn-1-ol and 3-butyn-2-ol gave predominantly the products of anti-Markovnikov addition, together with products of hydration-dehydration (α,β-rearrangement) and, to a minor extent, the decarbonylation products, ethene or propene, respectively. Hydrations were also conducted in D2O, giving indications of the mechanism of the reactions and apparently ruling out the allenylidene route for the α,β-rearrangement. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

Research paper thumbnail of ChemInform Abstract: A Simple, Efficient, and General Method for the Conversion of Alcohols into Alkyl Iodides by a CeCl3×7H2O/NaI System in Acetonitrile

Research paper thumbnail of Oxidation of dibenzothiophene by hydrogen peroxide in the presence of bis(acetylacetonato)oxovanadium(IV)

Fuel Processing Technology, 2011

In the presence of bis(acetylacetonato)oxovanadium(IV), dibenzothiophene was oxidized by hydrogen... more In the presence of bis(acetylacetonato)oxovanadium(IV), dibenzothiophene was oxidized by hydrogen peroxide to form sulfoxide and sulfone products. The percentage of dibenzothiophene remaining after the oxidation and the ratio of these oxidation products, as determined by 1H NMR spectroscopy, was largely dependent on the solvent used. Reactions in acetonitrile consumed more than 99% of the dibenzothiophene in the reaction and yielded

Research paper thumbnail of Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti‐Markovnikov Regioselectivity, Formation of α,β‐Unsaturated Products and Catalytic Decarbonylation to 1‐Alkenes

European Journal of Inorganic Chemistry, 2004

Ruthenium catalysts — water‐soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hyd... more Ruthenium catalysts — water‐soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes — proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1‐Phenyl‐2‐propyn‐1‐ol underwent an unprecedented catalytic hydration‐decarbonylation‐dehydration reaction, giving rise to styrene and carbon monoxide; 2‐propyn‐1‐ol and 3‐butyn‐2‐ol gave predominantly the products of anti‐Markovnikov addition, together with products of hydration‐dehydration (α,β‐rearrangement) and, to a minor extent, the decarbonylation products, ethene or propene, respectively. Hydrations were also conducted in D2O, giving indications of the mechanism of the reactions and apparently ruling out the allenylidene route for the α,β‐rearrangement. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

Research paper thumbnail of Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti‐Markovnikov Regioselectivity, Formation of α,β‐Unsaturated Products and Catalytic Decarbonylation to 1‐Alkenes

European Journal of Inorganic Chemistry, Feb 1, 2004

Ruthenium catalysts-water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydro... more Ruthenium catalysts-water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes-proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1-Phenyl-2-propyn-1-ol underwent an unprecedented catalytic hydration-decarbonylation-dehydration reaction, giving rise to styrene and carbon monoxide; 2-propyn-1-ol and 3-butyn-2ol gave predominantly the products of anti-Markovnikov ad-[a

Research paper thumbnail of A Simple, Efficient, and General Method for the Conversion of Alcohols into Alkyl Iodides by a CeCl 3 ·7H 2 O/NaI System in Acetonitrile

The Journal of Organic Chemistry, May 1, 2000

... Giuseppe Bartoli, Giustino Di Antonio, Riccardo Giovannini, Sandra Giuli, Silvia Lanari, Meli... more ... Giuseppe Bartoli, Giustino Di Antonio, Riccardo Giovannini, Sandra Giuli, Silvia Lanari, Melissa Paoletti, and Enrico Marcantoni. The ... Giuseppe Bartoli, Marcella Bosco, Arianna Giuliani, Enrico Marcantoni, Alessandro Palmieri, Marino Petrini, and Letizia Sambri. The Journal of ...

Research paper thumbnail of Oxidation of dibenzothiophene by hydrogen peroxide or monopersulfate and metal?sulfophthalocyanine catalysts: an easy access to biphenylsultone or 2-(2?-hydroxybiphenyl)sulfonate under mild conditions

New Journal of Chemistry, 2003

... Dibenzothiophene (DBT) and its alkylated analogues are among the most abundant polycyclic aro... more ... Dibenzothiophene (DBT) and its alkylated analogues are among the most abundant polycyclic aromatic sulfur hydrocarbons (PASH) in crude oils and are usually selected for model studies of desulfurization, both reductive and oxidative.1 In December 2000, the US EPA issued ...

Research paper thumbnail of Thermal stability and photostability of water solutions of sulfophthalocyanines of Ru(II), Cu(II), Ni(II), Fe(III) and Co(II)

Journal of Organometallic Chemistry, 2005

The thermal and photochemical stabilities were investigated for tetrasulfophthalocyanines of Cu, ... more The thermal and photochemical stabilities were investigated for tetrasulfophthalocyanines of Cu, Co, Ni, Fe and Ru (MPcS) and for two monosulfophthalocyanines of Ru, either without (RuPcS1) or with the coordination of two units of DMSO in apical positions ([RuPcS1(DMSO) 2 ]DMSO). The thermal degradation of all of the studied complexes never showed the formation of spectroscopically detectable intermediates. CuPcS was the most stable complex, while all of the Ru-sulfophthalocyanines were particularly prone to thermal degradation. Photodegradation showed a better selectivity, and as with thermal degradation, the order of reactivity goes from the most stable CuPcS, to the least stable Ru-sulfophthalocyanines (RuPcS, RuPcS1 and [RuPcS(DMSO) 2 ]DMSO). In particular, when the RuPcS complex was irradiated, a stable intermediate was detected that had an absorption band at 532 nm and a mass spectrum attributable to the tetrasulfophthalocyanine from oxidative ring cleavage by the action of the singlet oxygen formed via 1 *RuPcS photosensitization. The most probable molecular formula demonstrates a new complex, with a cleaved ring containing an-N@O group and two-OH groups that are all bonded at the two extremities of the open-chain molecule.

Research paper thumbnail of Hydration of Propargylic Alcohols by Ruthenium Catalysts, with Dominant Anti-Markovnikov Regioselectivity, Formation ofα,β-Unsaturated Products and Catalytic Decarbonylation to 1-Alkenes

European Journal of Inorganic Chemistry, 2004

Ruthenium catalysts — water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hyd... more Ruthenium catalysts — water-soluble ruthenium sulfophthalocyanine and heterogeneous ruthenium hydroxyapatite complexes — proved to be effective for the hydration of propargylic alcohols in entirely aqueous media. 1-Phenyl-2-propyn-1-ol underwent an unprecedented catalytic hydration-decarbonylation-dehydration reaction, giving rise to styrene and carbon monoxide; 2-propyn-1-ol and 3-butyn-2-ol gave predominantly the products of anti-Markovnikov addition, together with products of hydration-dehydration (α,β-rearrangement) and, to a minor extent, the decarbonylation products, ethene or propene, respectively. Hydrations were also conducted in D2O, giving indications of the mechanism of the reactions and apparently ruling out the allenylidene route for the α,β-rearrangement. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)