Marcelo Antunes - Academia.edu (original) (raw)
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Papers by Marcelo Antunes
Journal of Applied Polymer Science, 2006
Combined effects of clay treatment and compatibilizer polymers on the structure and properties of... more Combined effects of clay treatment and compatibilizer polymers on the structure and properties of polypropylene/clay nanocomposites were studied. Dynamic mechanical analysis was used to analyze comparatively the dynamic mechanical response of different nanocomposites prepared from polypropylene and montmorillonite‐rich bentonite, and to relate such response with the material microstructure. Two different bentonites were used: a purified Spanish natural bentonite was organophillized by means of 11‐undecyl‐ammonium ion and a commercial bentonite organophillized with dimethyl dehydrogenated tallow ammonium ion. Three different polar copolymers were employed as compatibilizer agents in some of the formulations: maleic anhydride‐grafted polypropylene, maleic anhydride‐grafted poly(styrene‐co‐ethylenebutylene‐co‐styrene), and poly(ethylene terephthalate‐co‐isophthalate) (PET). To ascertain the microstructure characteristics in the nanocomposites, wide angle X‐ray diffraction, transmission...
Journal of Applied Polymer Science, 2006
Combined effects of clay treatment and compatibilizer polymers on the structure and properties of... more Combined effects of clay treatment and compatibilizer polymers on the structure and properties of polypropylene/clay nanocomposites were studied. Dynamic mechanical analysis was used to analyze comparatively the dynamic mechanical response of different nanocomposites prepared from polypropylene and montmorillonite‐rich bentonite, and to relate such response with the material microstructure. Two different bentonites were used: a purified Spanish natural bentonite was organophillized by means of 11‐undecyl‐ammonium ion and a commercial bentonite organophillized with dimethyl dehydrogenated tallow ammonium ion. Three different polar copolymers were employed as compatibilizer agents in some of the formulations: maleic anhydride‐grafted polypropylene, maleic anhydride‐grafted poly(styrene‐co‐ethylenebutylene‐co‐styrene), and poly(ethylene terephthalate‐co‐isophthalate) (PET). To ascertain the microstructure characteristics in the nanocomposites, wide angle X‐ray diffraction, transmission...