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Papers by Marcelo Mansur
Mineral Processing and Extractive Metallurgy Review
Waste Electrical and Electronic Equipment (WEEE) Handbook, 2012
Brazilian Journal of Chemical Engineering
Mineral Processing and Extractive Metallurgy Review
Journal of Materials Research and Technology
Separation and Purification Technology
Brazilian Journal of Chemical Engineering
Brazilian Journal of Chemical Engineering
Brazilian Journal of Chemical Engineering
Journal of Power Sources, 2010
The separation of rare earth elements, cobalt and nickel from NiMH battery residues is evaluated ... more The separation of rare earth elements, cobalt and nickel from NiMH battery residues is evaluated in this paper. Analysis of the internal content of the NiMH batteries shows that nickel is the main metal present in the residue (around 50% in weight), as well as potassium (2.210.9%), ...
Journal of Power Sources, Jun 1, 2007
Journal of Hazardous Materials, May 1, 2008
The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking... more The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry is a hazardous waste due to the presence of chromium. While its coarse fraction is usually recycled into the own industrial process, the fine fraction is normally disposed in landfills. Techniques such as briquetting or magnetic separation were found to be inadequate to treat it for reuse purposes. So, in this work, the fine fraction of the AOD-L sludge was characterized aiming to find alternative methods to treat it. This sludge consists of a fine powder (mean diameter of 1 microm) containing 34 +/- 2% (w/w) of iron, 10.2 +/- 0.9% (w/w) of chromium and 1.4 +/- 0.1% (w/w) of nickel. The main crystalline phases identified in this study were chromite (FeCr(2)O(4)), magnetite (Fe(3)O(4)), hematite (Fe(2)O(3)) and calcite (CaCO(3)). In the digestion tests, the addition of HClO(4) has favored the dissolution of chromite which is a very stable oxide in aqueous media. Nickel was found in very fine particles, probably in the metallic form or associated with iron and oxygen. The sludge was classified as hazardous waste, so its disposal in landfills should be avoided.
Journal of Power Sources, Sep 1, 2006
Resources, Conservation and Recycling, 2015
Rem: Revista Escola de Minas, 2011
The use of solvent extraction to recover metals and water from industrial residues is highlighted... more The use of solvent extraction to recover metals and water from industrial residues is highlighted in this work. The method was applied (1) to selectively concentrate Zn from effluents generated by the zinc industry, (2) to separate Zn and Fe from spent pickling effluents produced by the hot-dip galvanizing industry, and (3) to recover Co and Ni from spent batteries. Batch and pilot scale data was used to point out solvent extraction as a feasible method to reuse both metals and water thus resulting in energy savings with reducing environmental impacts, minimizing costs required to transport hazardous materials to waste sites, to replace the discharged wastewater and to produce the raw material that would be previously discharged as wastes.
Mineral Processing and Extractive Metallurgy Review
Waste Electrical and Electronic Equipment (WEEE) Handbook, 2012
Brazilian Journal of Chemical Engineering
Mineral Processing and Extractive Metallurgy Review
Journal of Materials Research and Technology
Separation and Purification Technology
Brazilian Journal of Chemical Engineering
Brazilian Journal of Chemical Engineering
Brazilian Journal of Chemical Engineering
Journal of Power Sources, 2010
The separation of rare earth elements, cobalt and nickel from NiMH battery residues is evaluated ... more The separation of rare earth elements, cobalt and nickel from NiMH battery residues is evaluated in this paper. Analysis of the internal content of the NiMH batteries shows that nickel is the main metal present in the residue (around 50% in weight), as well as potassium (2.210.9%), ...
Journal of Power Sources, Jun 1, 2007
Journal of Hazardous Materials, May 1, 2008
The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking... more The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry is a hazardous waste due to the presence of chromium. While its coarse fraction is usually recycled into the own industrial process, the fine fraction is normally disposed in landfills. Techniques such as briquetting or magnetic separation were found to be inadequate to treat it for reuse purposes. So, in this work, the fine fraction of the AOD-L sludge was characterized aiming to find alternative methods to treat it. This sludge consists of a fine powder (mean diameter of 1 microm) containing 34 +/- 2% (w/w) of iron, 10.2 +/- 0.9% (w/w) of chromium and 1.4 +/- 0.1% (w/w) of nickel. The main crystalline phases identified in this study were chromite (FeCr(2)O(4)), magnetite (Fe(3)O(4)), hematite (Fe(2)O(3)) and calcite (CaCO(3)). In the digestion tests, the addition of HClO(4) has favored the dissolution of chromite which is a very stable oxide in aqueous media. Nickel was found in very fine particles, probably in the metallic form or associated with iron and oxygen. The sludge was classified as hazardous waste, so its disposal in landfills should be avoided.
Journal of Power Sources, Sep 1, 2006
Resources, Conservation and Recycling, 2015
Rem: Revista Escola de Minas, 2011
The use of solvent extraction to recover metals and water from industrial residues is highlighted... more The use of solvent extraction to recover metals and water from industrial residues is highlighted in this work. The method was applied (1) to selectively concentrate Zn from effluents generated by the zinc industry, (2) to separate Zn and Fe from spent pickling effluents produced by the hot-dip galvanizing industry, and (3) to recover Co and Ni from spent batteries. Batch and pilot scale data was used to point out solvent extraction as a feasible method to reuse both metals and water thus resulting in energy savings with reducing environmental impacts, minimizing costs required to transport hazardous materials to waste sites, to replace the discharged wastewater and to produce the raw material that would be previously discharged as wastes.