Muhamad Ramli - Academia.edu (original) (raw)

Papers by Muhamad Ramli

Research paper thumbnail of Spatial-based assessment of land use, soil erosion, and water protection in the Jeneberang valley, Indonesia

Biologia, 2009

Soil erosion by water is considered as one of the most significant forms of land degradation that... more Soil erosion by water is considered as one of the most significant forms of land degradation that affects sustained productivity of agricultural land use and water quality. It is influenced by a considerable number of factors (including climate, soil, topography, land use and types of land management), so that the information on the spatial distribution of soil erosion rate and its related effects can be effectively employed as a baseline data for land use development and water protection. The principal aim of this study is three-fold: (i) to map existing land use; (ii) to assess and map the spatial distribution of average annual rate of soil losses in the study area; (iii) to evaluate spatial matching between existing and proposed land use including a distance analysis from the water body (the Bili-Bili Dam). An analytical procedures used, respectively, include supervised classification of satellite imagery, application of RUSLE (Revised USLE), and overlay analysis in a raster GIS environment, utilising available information in the region covering some parts of Jeneberang catchment, South Sulawesi, Indonesia. The results suggest that the outputs of this study can be used for the identification of land units on a cell-basis with different land use types, rate of soil loss, inconsistency between proposed and planned land use, as well as the threat of land degradation to the main river and the dam. The analytical procedures developed in this research may be useful in other areas, particularly in the studies related to the assessment and mapping of land use and erosion for the importance of sustainable land use at a relatively large area.

Research paper thumbnail of Properties of High-Oleic Palm Oils Derived by Fractional Crystallization

Journal of Food Science, 2008

ABSTRACT: High-oleic palm oil (HOPO) with an oleic acid content of 59.0% and an iodine value (IV... more ABSTRACT: High-oleic palm oil (HOPO) with an oleic acid content of 59.0% and an iodine value (IV) of 78.2 was crystallized in a 200-kg De Smet crystallizer with a predetermined cooling program and appropriate agitation. The slurry was then fractionated by means of dry fractionation at 4, 8, 10, 12, and 15 °C. The oil and the fractionated products were subjected to physical and chemical analyses, including fatty acid composition, triacylglycerol and diacylglycerol composition, solid fat content, cloud point, slip melting point, and cold stability test. Fractionation at 15 °C resulted in the highest olein yield but with minimal oleic acid content. Due to the enhanced unsaturation of the oil, fractionation at relatively lower crystallization temperature showed a considerable effect on fatty acid composition as well as triacylglycerol and diacylglycerol composition of liquid fractions compared to higher crystallization temperature. The olein and stearin fractionated at 4 °C had the best cold stability at 0 °C and sharper melting profile, respectively.

Research paper thumbnail of Production of High Oleic Palm Oils on a Pilot Scale

Journal of The American Oil Chemists Society, 2010

Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemica... more Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemically interesterified with methyl oleate (MO) at a ratio of 50:50 (w/w). The reaction was carried out at 110°C in the presence of sodium methoxide as a catalyst using a 100-kg pilot scale reactor. Randomization between 15 and 30 min resulted in less free fatty acid (FFA) formation and higher oleic content in the interesterified product as compared to longer reaction time of 60-90 min. Sodium methoxidecatalyzed ester interchange increased the oleic content of the interesterified product to more than 57% from its initial content of 45%. The product obtained also has an IV of more than 75. The interesterified oil was then subjected to dry fractionation in a 200-kg De Smet jacketed crystallizer at 8°C to further enhance the oleic content of the liquid olein fraction. The resulted olein had an improved cloud point and higher IV of 81. The solid stearin had a slightly higher IV and oleic content as compared to normal palm stearin. The solid fat content was comparable to normal palm oil. The pilot scale study has proven a successful conversion of laboratory findings to a larger scale production and gave the most realistic information for possible commercialization.

Research paper thumbnail of Detection and Monitoring of 3-Monochloropropane-1,2Diol (3-MCPD) Esters in Cooking Oils

Food Control

A series of refined palm oil products were collected from different refineries in Malaysia and we... more A series of refined palm oil products were collected from different refineries in Malaysia and were analysed for 3-MCPD esters content. Samples were analysed using acidic transesterification and quantification by Gas ChromatographyeMass Selective Detector (GCeMSD). This method is based on the Federal German Institute for Risk Assessment (BfR) Method 008 for 3-MCPD esters. Limit of Detection (LOD) for this method was 0.25 mg kg À1 and Limit of Quantification (LOQ) was 0.50 mg kg À1 3-MCPD esters were generally not detected in crude oils, but were found at trace levels in bleached oils. Deodorized or fully refined oils contained higher 3-MCPD esters. The values ranged from <0.25e5.77 mg kg À1 for palm oil products, whilst other cooking oils in the retail ranged from <0.25e2.45 mg kg À1 .

Research paper thumbnail of Production of High Oleic Palm Oils on a Pilot Scale

Journal of The American Oil Chemists Society, 2009

Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemica... more Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemically interesterified with methyl oleate (MO) at a ratio of 50:50 (w/w). The reaction was carried out at 110 °C in the presence of sodium methoxide as a catalyst using a 100-kg pilot scale reactor. Randomization between 15 and 30 min resulted in less free fatty acid (FFA) formation and higher oleic content in the interesterified product as compared to longer reaction time of 60–90 min. Sodium methoxide-catalyzed ester interchange increased the oleic content of the interesterified product to more than 57% from its initial content of 45%. The product obtained also has an IV of more than 75. The interesterified oil was then subjected to dry fractionation in a 200-kg De Smet jacketed crystallizer at 8 °C to further enhance the oleic content of the liquid olein fraction. The resulted olein had an improved cloud point and higher IV of 81. The solid stearin had a slightly higher IV and oleic content as compared to normal palm stearin. The solid fat content was comparable to normal palm oil. The pilot scale study has proven a successful conversion of laboratory findings to a larger scale production and gave the most realistic information for possible commercialization.

Research paper thumbnail of Effects of Degumming and Bleaching on 3-MCPD Esters Formation During Physical Refining

Journal of The American Oil Chemists Society

Crude palm oil (CPO) was physically refined in a 200-kg batch pilot refining plant. A study of th... more Crude palm oil (CPO) was physically refined in a 200-kg batch pilot refining plant. A study of the possible role of degumming and bleaching steps in the refining process for a possible critical role in the formation of 3-chloropropane-1,2-diol (3-MCPD) esters was evaluated. For the degumming step, different percentages of phosphoric acid (0.02–0.1%) as well as water degumming (2.0%) were carried out. Six different types of bleaching clays, mainly natural and acid activated clays were used for bleaching process at a fixed dose of 1.0%. Deodorization of the bleached oils was performed at 260 °C for 90 min. Analyses showed that 3-MCPD esters were not detected in the CPO. Phosphoric acid degumming (0.1%) in combination with acid activated clays produced the highest levels (3.89 ppm) of 3-MCPD esters in the refined (RBD) oil. The esters were at the lowest levels (0.25 ppm) when the oil was water degummed and bleached with natural bleaching clays. However, the refined oil qualities were slightly compromised. Good correlation of 0.9759 and 0.9351 was obtained when concentration of the esters was plotted against acidity of the bleaching earths for the respective acid and water degumming processes. The findings revealed the contribution of acidic conditions on the higher formation of 3-MCPD esters. In order to lower the esters formation, it is important to reduce acid dosage based on the crude oil qualities or to find alternatives to acid degumming process. Neutralization of the acidity prior to deodorization was effective in reducing the formation of 3-MCPD esters.

Research paper thumbnail of Spatial-based assessment of land use, soil erosion, and water protection in the Jeneberang valley, Indonesia

Biologia, 2009

Soil erosion by water is considered as one of the most significant forms of land degradation that... more Soil erosion by water is considered as one of the most significant forms of land degradation that affects sustained productivity of agricultural land use and water quality. It is influenced by a considerable number of factors (including climate, soil, topography, land use and types of land management), so that the information on the spatial distribution of soil erosion rate and its related effects can be effectively employed as a baseline data for land use development and water protection. The principal aim of this study is three-fold: (i) to map existing land use; (ii) to assess and map the spatial distribution of average annual rate of soil losses in the study area; (iii) to evaluate spatial matching between existing and proposed land use including a distance analysis from the water body (the Bili-Bili Dam). An analytical procedures used, respectively, include supervised classification of satellite imagery, application of RUSLE (Revised USLE), and overlay analysis in a raster GIS environment, utilising available information in the region covering some parts of Jeneberang catchment, South Sulawesi, Indonesia. The results suggest that the outputs of this study can be used for the identification of land units on a cell-basis with different land use types, rate of soil loss, inconsistency between proposed and planned land use, as well as the threat of land degradation to the main river and the dam. The analytical procedures developed in this research may be useful in other areas, particularly in the studies related to the assessment and mapping of land use and erosion for the importance of sustainable land use at a relatively large area.

Research paper thumbnail of Properties of High-Oleic Palm Oils Derived by Fractional Crystallization

Journal of Food Science, 2008

ABSTRACT: High-oleic palm oil (HOPO) with an oleic acid content of 59.0% and an iodine value (IV... more ABSTRACT: High-oleic palm oil (HOPO) with an oleic acid content of 59.0% and an iodine value (IV) of 78.2 was crystallized in a 200-kg De Smet crystallizer with a predetermined cooling program and appropriate agitation. The slurry was then fractionated by means of dry fractionation at 4, 8, 10, 12, and 15 °C. The oil and the fractionated products were subjected to physical and chemical analyses, including fatty acid composition, triacylglycerol and diacylglycerol composition, solid fat content, cloud point, slip melting point, and cold stability test. Fractionation at 15 °C resulted in the highest olein yield but with minimal oleic acid content. Due to the enhanced unsaturation of the oil, fractionation at relatively lower crystallization temperature showed a considerable effect on fatty acid composition as well as triacylglycerol and diacylglycerol composition of liquid fractions compared to higher crystallization temperature. The olein and stearin fractionated at 4 °C had the best cold stability at 0 °C and sharper melting profile, respectively.

Research paper thumbnail of Production of High Oleic Palm Oils on a Pilot Scale

Journal of The American Oil Chemists Society, 2010

Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemica... more Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemically interesterified with methyl oleate (MO) at a ratio of 50:50 (w/w). The reaction was carried out at 110°C in the presence of sodium methoxide as a catalyst using a 100-kg pilot scale reactor. Randomization between 15 and 30 min resulted in less free fatty acid (FFA) formation and higher oleic content in the interesterified product as compared to longer reaction time of 60-90 min. Sodium methoxidecatalyzed ester interchange increased the oleic content of the interesterified product to more than 57% from its initial content of 45%. The product obtained also has an IV of more than 75. The interesterified oil was then subjected to dry fractionation in a 200-kg De Smet jacketed crystallizer at 8°C to further enhance the oleic content of the liquid olein fraction. The resulted olein had an improved cloud point and higher IV of 81. The solid stearin had a slightly higher IV and oleic content as compared to normal palm stearin. The solid fat content was comparable to normal palm oil. The pilot scale study has proven a successful conversion of laboratory findings to a larger scale production and gave the most realistic information for possible commercialization.

Research paper thumbnail of Detection and Monitoring of 3-Monochloropropane-1,2Diol (3-MCPD) Esters in Cooking Oils

Food Control

A series of refined palm oil products were collected from different refineries in Malaysia and we... more A series of refined palm oil products were collected from different refineries in Malaysia and were analysed for 3-MCPD esters content. Samples were analysed using acidic transesterification and quantification by Gas ChromatographyeMass Selective Detector (GCeMSD). This method is based on the Federal German Institute for Risk Assessment (BfR) Method 008 for 3-MCPD esters. Limit of Detection (LOD) for this method was 0.25 mg kg À1 and Limit of Quantification (LOQ) was 0.50 mg kg À1 3-MCPD esters were generally not detected in crude oils, but were found at trace levels in bleached oils. Deodorized or fully refined oils contained higher 3-MCPD esters. The values ranged from <0.25e5.77 mg kg À1 for palm oil products, whilst other cooking oils in the retail ranged from <0.25e2.45 mg kg À1 .

Research paper thumbnail of Production of High Oleic Palm Oils on a Pilot Scale

Journal of The American Oil Chemists Society, 2009

Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemica... more Refined, bleached and deodorized palm olein (RBD POo) with an iodine value (IV) of 62 was chemically interesterified with methyl oleate (MO) at a ratio of 50:50 (w/w). The reaction was carried out at 110 °C in the presence of sodium methoxide as a catalyst using a 100-kg pilot scale reactor. Randomization between 15 and 30 min resulted in less free fatty acid (FFA) formation and higher oleic content in the interesterified product as compared to longer reaction time of 60–90 min. Sodium methoxide-catalyzed ester interchange increased the oleic content of the interesterified product to more than 57% from its initial content of 45%. The product obtained also has an IV of more than 75. The interesterified oil was then subjected to dry fractionation in a 200-kg De Smet jacketed crystallizer at 8 °C to further enhance the oleic content of the liquid olein fraction. The resulted olein had an improved cloud point and higher IV of 81. The solid stearin had a slightly higher IV and oleic content as compared to normal palm stearin. The solid fat content was comparable to normal palm oil. The pilot scale study has proven a successful conversion of laboratory findings to a larger scale production and gave the most realistic information for possible commercialization.

Research paper thumbnail of Effects of Degumming and Bleaching on 3-MCPD Esters Formation During Physical Refining

Journal of The American Oil Chemists Society

Crude palm oil (CPO) was physically refined in a 200-kg batch pilot refining plant. A study of th... more Crude palm oil (CPO) was physically refined in a 200-kg batch pilot refining plant. A study of the possible role of degumming and bleaching steps in the refining process for a possible critical role in the formation of 3-chloropropane-1,2-diol (3-MCPD) esters was evaluated. For the degumming step, different percentages of phosphoric acid (0.02–0.1%) as well as water degumming (2.0%) were carried out. Six different types of bleaching clays, mainly natural and acid activated clays were used for bleaching process at a fixed dose of 1.0%. Deodorization of the bleached oils was performed at 260 °C for 90 min. Analyses showed that 3-MCPD esters were not detected in the CPO. Phosphoric acid degumming (0.1%) in combination with acid activated clays produced the highest levels (3.89 ppm) of 3-MCPD esters in the refined (RBD) oil. The esters were at the lowest levels (0.25 ppm) when the oil was water degummed and bleached with natural bleaching clays. However, the refined oil qualities were slightly compromised. Good correlation of 0.9759 and 0.9351 was obtained when concentration of the esters was plotted against acidity of the bleaching earths for the respective acid and water degumming processes. The findings revealed the contribution of acidic conditions on the higher formation of 3-MCPD esters. In order to lower the esters formation, it is important to reduce acid dosage based on the crude oil qualities or to find alternatives to acid degumming process. Neutralization of the acidity prior to deodorization was effective in reducing the formation of 3-MCPD esters.