R Manurung - Academia.edu (original) (raw)

Papers by R Manurung

Bioresource Technology, 2008

Food and Bioproducts Processing, 2009

Process Safety and Environmental Protection, 2007

Starch-starke, 2008

This paper describes the synthesis of long-chain fatty esters of corn starch (starch laurate and ... more This paper describes the synthesis of long-chain fatty esters of corn starch (starch laurate and starch stearate) with a broad range in degree of substitution (DS = 0.24−2.96). The fatty esters were prepared by reacting the starch with vinyl laurate or vinyl stearate in the presence of basic catalysts (Na2HPO4, K2CO3, and Na acetate) in DMSO at 110°C. The yellowish products were characterized by 1H-, 13C-NMR and FT-IR. The DS of the products is a function of the carbon number of the fatty acid chain, vinyl ester to starch ratio and the type of catalyst. When performing the reactions using Na2HPO4 as the catalyst, the DS for the starch laurate compounds is higher than for the corresponding starch stearates. For low vinyl ester to starch ratios, an increase in the vinyl ester concentration leads to higher product DS values. At higher ratios, the DS decreases, presumably due to a reduction of the polarity of the reaction medium. K2CO3 and Na acetate are superior catalysts with respect to activity compared to Na2HPO4 and products with DS values close to 3 were obtained.

Bioresource Technology, 2008

Food and Bioproducts Processing, 2009

Process Safety and Environmental Protection, 2007

Starch-starke, 2008

This paper describes the synthesis of long-chain fatty esters of corn starch (starch laurate and ... more This paper describes the synthesis of long-chain fatty esters of corn starch (starch laurate and starch stearate) with a broad range in degree of substitution (DS = 0.24−2.96). The fatty esters were prepared by reacting the starch with vinyl laurate or vinyl stearate in the presence of basic catalysts (Na2HPO4, K2CO3, and Na acetate) in DMSO at 110°C. The yellowish products were characterized by 1H-, 13C-NMR and FT-IR. The DS of the products is a function of the carbon number of the fatty acid chain, vinyl ester to starch ratio and the type of catalyst. When performing the reactions using Na2HPO4 as the catalyst, the DS for the starch laurate compounds is higher than for the corresponding starch stearates. For low vinyl ester to starch ratios, an increase in the vinyl ester concentration leads to higher product DS values. At higher ratios, the DS decreases, presumably due to a reduction of the polarity of the reaction medium. K2CO3 and Na acetate are superior catalysts with respect to activity compared to Na2HPO4 and products with DS values close to 3 were obtained.