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Papers by ROSANGELA BUZON PIROTA
Chemical Engineering Transactions, 2014
Enzymatic conversion of lignocellulosic biomass into fuels and chemicals will be a key technology... more Enzymatic conversion of lignocellulosic biomass into fuels and chemicals will be a key technology in the future. However, in order to make this process economically feasible, it is necessary to improve the efficiency of enzyme production, since the cost of the enzymatic cocktails significantly influences the viability of the overall process. In this sense, the use of solid-state fermentation (SSF) is particularly advantageous for enzyme production. Here, a comparative study on the enzymatic hydrolysis of steam- exploded sugarcane bagasse (SESB) using enzymatic extract (EE) and whole solid-state fermentation medium (WM) of two newly isolated strains of Aspergillus oryzae (P6B2 and P27C3A) from the Amazon Rainforest was carried out. The biomass conversion using WM from A. oryzae P6B2 was more efficient when compared with the EE, while for A. oryzae P27C3A the conversion yields were similar. The WM from P27C3A supplemented with a low dosage of commercial enzyme resulted in a final conv...
Brazilian Journal of Chemical Engineering, 2016
BioEnergy Research, 2014
ABSTRACT A novel simplified configuration is proposed for the conversion of biomass to ethanol us... more ABSTRACT A novel simplified configuration is proposed for the conversion of biomass to ethanol using whole medium enzymatic cocktails (WM) and enzymatic extracts (EE) from different filamentous fungi (Trichoderma reesei, Aspergillus niger, and Aspergillus oryzae) cultivated under solid-state fermentation (SSF) for the hydrolysis of steam-exploded sugarcane bagasse (SESB). The hydrolyzed material derived from the saccharification of SESB using the combinations A. niger WM + T. reesei EE, A. oryzae WM + A. niger EE, and A. niger EE + T. reesei WM resulted in the best biomass conversion yields (66, 65, and 64 % of the theoretical reducing sugar yields, respectively). The best ethanol production (84 % of the theoretical yield) was obtained using the material hydrolyzed by a combination of A. oryzae WM + A. niger EE. The enzymatic conversion of SESB using on-site produced enzymes from the whole SSF cultivation medium, followed by an ethanol production step, is a potential configuration for the biomass to ethanol conversion process. This novel simplified configuration would enable the use of a single reactor system, avoiding the need for additional separation steps.
Brazilian Journal of Chemical Engineering, 2013
Biocatalysis and Biotransformation, 2013
Industrial Crops and Products, 2013
... de laboratório pela ajuda na realizaçmo deste trabalho: Andréia, Ana Flávia, Ana Lúcia, Carol... more ... de laboratório pela ajuda na realizaçmo deste trabalho: Andréia, Ana Flávia, Ana Lúcia, Carol, Caroline, Denise, Ellen, Ellen Lago, Fabiana, Gisele, Hamilton, Heloiza, Lilian, Maira, Marcelo, Marcia Moretti ... Grande parte desses resíduos fica disponível no campo tornando-se, ...
Industrial Crops and Products, 2013
Bioprocess studies towards improving the production of xylanases are of great value due to the im... more Bioprocess studies towards improving the production of xylanases are of great value due to the importance of these enzymes on several industrial applications. This work evaluates the effects of operational conditions on xylanase production by a new strain of Aspergillus oryzae (P6B2) isolated from the Amazon Rain Forest. The fungus was cultivated under solid-state fermentation (SSF) using an instrumented lab-scale bioreactor equipped with an on-line automated monitoring and control system. The effects of initial substrate moisture content and temperature on xylanase production were evaluated and compared to static conditions. It was outstanding the positive effect on xylanase production by SSF cultivations under controlled conditions of forced over static aeration conditions. The conditions selected for further characterization resulted in the highest production of xylanase (2830.7 IU/g), which was achieved using an initial substrate moisture content of 80%, at 28 °C with an air flo...
Animal Feed Science and Technology, Jun 1, 2008
Biomass and Bioenergy, Feb 1, 2012
The successful strategy to produce cellulolytic enzymes includes both microorganism selection and... more The successful strategy to produce cellulolytic enzymes includes both microorganism selection and improved fermentation process conditions. This work describes the isolation, screening and selection of biomass-degrading fungi species from the Amazon forest and ...
Industrial Crops and Products, 2013
Biocatalysis and Biotransformation, 2014
The selection of enzyme-producing fungi is useful to obtain enzymes required to hydrolyze lignoce... more The selection of enzyme-producing fungi is useful to obtain enzymes required to hydrolyze lignocellulosic material and thereby contribute to biomass conversion into fuels and chemicals. Besides cellulases, the presence of accessory enzymes in enzyme cocktails is necessary to enhance hydrolysis efficiency. This study evaluates the production, purification, and biochemical-kinetic characterization of beta-galactosidase produced by a new strain of Aspergillus niger (P47C3) isolated from the Amazon Forest. The A. niger (P47C3) was cultured under SmF conditions and beta-galactosidase was purified in a three-step purification, using an ultrafiltration membrane, ion exchange (TSK-SP), and gel filtration (Sephacryl S-200). The calculated molecular weight of the purified enzyme was 125 kDa. Optimum pH (4.0) and temperature (55 degrees C) of beta-galactosidase activity were determined. The values of the kinetic parameters obtained from p-nitrophenyl-beta-D-galactopyranoside (PNPG) hydrolysis ...
Biocatalysis and Biotransformation, 2014
Abstract The biotransformation of lignocellulosic materials into biofuels and chemicals requires ... more Abstract The biotransformation of lignocellulosic materials into biofuels and chemicals requires the simultaneous action of multiple enzymes. Since the cost of producing an efficient enzyme system maybe high, mixed cultures of microorganisms maybe an alternative to increase enzymatic production and consequently reduce costs. This study investigated the effects of different inoculum ratios and inoculation delays on the biosynthesis of cellulases and xylanases during co-cultivation of Aspergillus niger and Trichoderma reesei under solid-state fermentation (SSF). While the monoculture of T. reesei was more efficient for CMCase production than the co-cultivation of A. niger and T. reesei, a significant increase in β-glucosidase and xylanase production was achieved by co-cultivation of both species. The maximum CMCase activity of 153.91 IU/g was obtained with T. reesei after 48 h of cultivation, while the highest β-glucosidase activity of 119.71 IU/g (after 120 h) was obtained by co-cultivation of A. niger and T. reesei with a 3:1 inoculum ratio (A. niger: T. reesei). The greatest xylanase activity observed was 589.39 IU/g after 72 h of mixed culturing of A. niger and T. Reesei with a 1:1 inoculum ratio. This is the first study where the effects of inoculum ratio and inoculation delay in mixed culture of T. reesei and A. niger under SSF have been systematically assessed, and it indicates co-cultivation as a feasible alternative to increase enzymatic production.
Chemical Engineering Transactions, 2014
Enzymatic conversion of lignocellulosic biomass into fuels and chemicals will be a key technology... more Enzymatic conversion of lignocellulosic biomass into fuels and chemicals will be a key technology in the future. However, in order to make this process economically feasible, it is necessary to improve the efficiency of enzyme production, since the cost of the enzymatic cocktails significantly influences the viability of the overall process. In this sense, the use of solid-state fermentation (SSF) is particularly advantageous for enzyme production. Here, a comparative study on the enzymatic hydrolysis of steam- exploded sugarcane bagasse (SESB) using enzymatic extract (EE) and whole solid-state fermentation medium (WM) of two newly isolated strains of Aspergillus oryzae (P6B2 and P27C3A) from the Amazon Rainforest was carried out. The biomass conversion using WM from A. oryzae P6B2 was more efficient when compared with the EE, while for A. oryzae P27C3A the conversion yields were similar. The WM from P27C3A supplemented with a low dosage of commercial enzyme resulted in a final conv...
Brazilian Journal of Chemical Engineering, 2016
BioEnergy Research, 2014
ABSTRACT A novel simplified configuration is proposed for the conversion of biomass to ethanol us... more ABSTRACT A novel simplified configuration is proposed for the conversion of biomass to ethanol using whole medium enzymatic cocktails (WM) and enzymatic extracts (EE) from different filamentous fungi (Trichoderma reesei, Aspergillus niger, and Aspergillus oryzae) cultivated under solid-state fermentation (SSF) for the hydrolysis of steam-exploded sugarcane bagasse (SESB). The hydrolyzed material derived from the saccharification of SESB using the combinations A. niger WM + T. reesei EE, A. oryzae WM + A. niger EE, and A. niger EE + T. reesei WM resulted in the best biomass conversion yields (66, 65, and 64 % of the theoretical reducing sugar yields, respectively). The best ethanol production (84 % of the theoretical yield) was obtained using the material hydrolyzed by a combination of A. oryzae WM + A. niger EE. The enzymatic conversion of SESB using on-site produced enzymes from the whole SSF cultivation medium, followed by an ethanol production step, is a potential configuration for the biomass to ethanol conversion process. This novel simplified configuration would enable the use of a single reactor system, avoiding the need for additional separation steps.
Brazilian Journal of Chemical Engineering, 2013
Biocatalysis and Biotransformation, 2013
Industrial Crops and Products, 2013
... de laboratório pela ajuda na realizaçmo deste trabalho: Andréia, Ana Flávia, Ana Lúcia, Carol... more ... de laboratório pela ajuda na realizaçmo deste trabalho: Andréia, Ana Flávia, Ana Lúcia, Carol, Caroline, Denise, Ellen, Ellen Lago, Fabiana, Gisele, Hamilton, Heloiza, Lilian, Maira, Marcelo, Marcia Moretti ... Grande parte desses resíduos fica disponível no campo tornando-se, ...
Industrial Crops and Products, 2013
Bioprocess studies towards improving the production of xylanases are of great value due to the im... more Bioprocess studies towards improving the production of xylanases are of great value due to the importance of these enzymes on several industrial applications. This work evaluates the effects of operational conditions on xylanase production by a new strain of Aspergillus oryzae (P6B2) isolated from the Amazon Rain Forest. The fungus was cultivated under solid-state fermentation (SSF) using an instrumented lab-scale bioreactor equipped with an on-line automated monitoring and control system. The effects of initial substrate moisture content and temperature on xylanase production were evaluated and compared to static conditions. It was outstanding the positive effect on xylanase production by SSF cultivations under controlled conditions of forced over static aeration conditions. The conditions selected for further characterization resulted in the highest production of xylanase (2830.7 IU/g), which was achieved using an initial substrate moisture content of 80%, at 28 °C with an air flo...
Animal Feed Science and Technology, Jun 1, 2008
Biomass and Bioenergy, Feb 1, 2012
The successful strategy to produce cellulolytic enzymes includes both microorganism selection and... more The successful strategy to produce cellulolytic enzymes includes both microorganism selection and improved fermentation process conditions. This work describes the isolation, screening and selection of biomass-degrading fungi species from the Amazon forest and ...
Industrial Crops and Products, 2013
Biocatalysis and Biotransformation, 2014
The selection of enzyme-producing fungi is useful to obtain enzymes required to hydrolyze lignoce... more The selection of enzyme-producing fungi is useful to obtain enzymes required to hydrolyze lignocellulosic material and thereby contribute to biomass conversion into fuels and chemicals. Besides cellulases, the presence of accessory enzymes in enzyme cocktails is necessary to enhance hydrolysis efficiency. This study evaluates the production, purification, and biochemical-kinetic characterization of beta-galactosidase produced by a new strain of Aspergillus niger (P47C3) isolated from the Amazon Forest. The A. niger (P47C3) was cultured under SmF conditions and beta-galactosidase was purified in a three-step purification, using an ultrafiltration membrane, ion exchange (TSK-SP), and gel filtration (Sephacryl S-200). The calculated molecular weight of the purified enzyme was 125 kDa. Optimum pH (4.0) and temperature (55 degrees C) of beta-galactosidase activity were determined. The values of the kinetic parameters obtained from p-nitrophenyl-beta-D-galactopyranoside (PNPG) hydrolysis ...
Biocatalysis and Biotransformation, 2014
Abstract The biotransformation of lignocellulosic materials into biofuels and chemicals requires ... more Abstract The biotransformation of lignocellulosic materials into biofuels and chemicals requires the simultaneous action of multiple enzymes. Since the cost of producing an efficient enzyme system maybe high, mixed cultures of microorganisms maybe an alternative to increase enzymatic production and consequently reduce costs. This study investigated the effects of different inoculum ratios and inoculation delays on the biosynthesis of cellulases and xylanases during co-cultivation of Aspergillus niger and Trichoderma reesei under solid-state fermentation (SSF). While the monoculture of T. reesei was more efficient for CMCase production than the co-cultivation of A. niger and T. reesei, a significant increase in β-glucosidase and xylanase production was achieved by co-cultivation of both species. The maximum CMCase activity of 153.91 IU/g was obtained with T. reesei after 48 h of cultivation, while the highest β-glucosidase activity of 119.71 IU/g (after 120 h) was obtained by co-cultivation of A. niger and T. reesei with a 3:1 inoculum ratio (A. niger: T. reesei). The greatest xylanase activity observed was 589.39 IU/g after 72 h of mixed culturing of A. niger and T. Reesei with a 1:1 inoculum ratio. This is the first study where the effects of inoculum ratio and inoculation delay in mixed culture of T. reesei and A. niger under SSF have been systematically assessed, and it indicates co-cultivation as a feasible alternative to increase enzymatic production.