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Andrea Resta

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Research paper thumbnail of Ammonia Oxidation over a Pt<sub>25</sub>Rh<sub>75</sub>(001) Model Catalyst Surface: An Operando Study

Journal of Physical Chemistry C, Sep 16, 2020

The reaction of ammonia oxidation over PtRh binary alloy has been studied with a surface science ... more The reaction of ammonia oxidation over PtRh binary alloy has been studied with a surface science approach by operando techniques such as Near Ambient Pressure X-Ray Photoemission Spectroscopy (NAP-...

Research paper thumbnail of Pseudo-2-Fold Surface of the Al<sub>13</sub>Co<sub>4</sub> Catalyst: Structure, Stability, and Hydrogen Adsorption

ACS Applied Materials & Interfaces, Jul 28, 2020

Research paper thumbnail of Combined surface x-ray diffraction and density functional theory study of the germanene/Al(111)- (7×7)R19.1∘ structure

Research paper thumbnail of Structure of Germanene/Al(111): A Two-Layer Surface Alloy

The Journal of Physical Chemistry C, 2021

Research paper thumbnail of Steps and catalytic reactions: CO oxidation with preadsorbed O on Rh(553)

Research paper thumbnail of Pseudo-2-Fold Surface of the Al13Co4 Catalyst: Structure, Stability, and Hydrogen Adsorption

ACS Applied Materials & Interfaces, 2020

Research paper thumbnail of From the Surface Structure to Catalytic Properties of Al5Co2(21̅0): A Study Combining Experimental and Theoretical Approaches

The Journal of Physical Chemistry C, 2020

Research paper thumbnail of Mn0.7Fe2.3O4 Nanoplatelets Embedded in BaTiO3 Perovskite Thin Films for Multifunctional Composite Barriers

ACS Applied Nano Materials, 2019

Research paper thumbnail of Low-temperature methane oxidation over single crystal Pd (100)

Research paper thumbnail of Reversible Formation of Palladium Carbide on Palladium Nanoparticles under CO Oxidation Conditions

Research paper thumbnail of Acetate formation during the ethanol oxidation on Rh(111)

Research paper thumbnail of Complex Interaction of Hydrogen with the RuO2(110) Surface

The Journal of Physical Chemistry C, 2007

Using a variety of dedicated surface sensitive techniques, we studied the interaction of hydrogen... more Using a variety of dedicated surface sensitive techniques, we studied the interaction of hydrogen with bare and adsorbate modified RuO2 (110) surfaces on the atomic scale. Hydrogen interacts strongly with the undercoordinated O atoms, thereby forming hydroxyl ...

Research paper thumbnail of Influence of Oxygen Vacancies on the Properties of Ceria-Supported Gold

The Journal of Physical Chemistry C, 2009

ABSTRACT The adsorption of CO on nanosized gold particles deposited on a cerium oxide substrate i... more ABSTRACT The adsorption of CO on nanosized gold particles deposited on a cerium oxide substrate is strongly influenced by the roughness and concentration of oxygen vacancies of the CeOx substrate surface. Literature showed that Au nucleates at step edges on oxidized samples. For oxidized samples we found that the Au dispersion is dependent on the surface roughness. A rough CeO2 surface has a higher step density, which results in a Au higher particle density with a smaller average diameter. Other studies showed that Au nucleates on oxygen vacancies on reduced CeOx substrates. We found that small Au particles adsorbed on oxygen vacancies exhibit a significantly higher Au 4f binding energy than Au particles on oxidized CeO2. Relatively less CO adsorbs on small Au particles on a reduced substrate, with a significantly lower adsorption energy than on Au on an oxidized substrate. For larger particles the influence of oxygen vacancies in the substrate is negligible.

Research paper thumbnail of Growth and Reactivity of Titanium Oxide Ultrathin Films on Ni(110)

The Journal of Physical Chemistry C, 2007

Soft X-ray photoelectron spectroscopy (SXPS) and X-ray absorption near-edge structure (XANES) hav... more Soft X-ray photoelectron spectroscopy (SXPS) and X-ray absorption near-edge structure (XANES) have been combined with low-energy electron diffraction (LEED) to examine the growth of titanium dioxide thin films on Ni (110). Depending on the initial titanium ...

Research paper thumbnail of Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic Conditions

The Journal of Physical Chemistry C, 2010

ABSTRACT Using a combination of surface X-ray diffraction and mass spectrometry at realistic pres... more ABSTRACT Using a combination of surface X-ray diffraction and mass spectrometry at realistic pressures, the CO oxidation reactivity of a Rh(111) model catalyst has been studied in conjunction with the surface structure. The measurements show that a specific thin surface oxide is always present in the high activity regime of Rh-based CO oxidation.

Research paper thumbnail of CO Adsorption on a Au/CeO2 (111) Model Catalyst

The Journal of Physical Chemistry C, 2008

Research paper thumbnail of Kinetics of the Reduction of the Rh(111) Surface Oxide:  Linking Spectroscopy and Atomic-Scale Information

The Journal of Physical Chemistry B, 2006

Research paper thumbnail of Unusual Process of Water Formation on RuO2(110) by Hydrogen Exposure at Room Temperature

The Journal of Physical Chemistry B, 2006

Research paper thumbnail of Step enhanced dehydrogenation of ethanol on Rh

Research paper thumbnail of Stressing Pd atoms: Initial oxidation of the Pd(110) surface

Research paper thumbnail of Ammonia Oxidation over a Pt<sub>25</sub>Rh<sub>75</sub>(001) Model Catalyst Surface: An Operando Study

Journal of Physical Chemistry C, Sep 16, 2020

The reaction of ammonia oxidation over PtRh binary alloy has been studied with a surface science ... more The reaction of ammonia oxidation over PtRh binary alloy has been studied with a surface science approach by operando techniques such as Near Ambient Pressure X-Ray Photoemission Spectroscopy (NAP-...

Research paper thumbnail of Pseudo-2-Fold Surface of the Al<sub>13</sub>Co<sub>4</sub> Catalyst: Structure, Stability, and Hydrogen Adsorption

ACS Applied Materials & Interfaces, Jul 28, 2020

Research paper thumbnail of Combined surface x-ray diffraction and density functional theory study of the germanene/Al(111)- (7×7)R19.1∘ structure

Research paper thumbnail of Structure of Germanene/Al(111): A Two-Layer Surface Alloy

The Journal of Physical Chemistry C, 2021

Research paper thumbnail of Steps and catalytic reactions: CO oxidation with preadsorbed O on Rh(553)

Research paper thumbnail of Pseudo-2-Fold Surface of the Al13Co4 Catalyst: Structure, Stability, and Hydrogen Adsorption

ACS Applied Materials & Interfaces, 2020

Research paper thumbnail of From the Surface Structure to Catalytic Properties of Al5Co2(21̅0): A Study Combining Experimental and Theoretical Approaches

The Journal of Physical Chemistry C, 2020

Research paper thumbnail of Mn0.7Fe2.3O4 Nanoplatelets Embedded in BaTiO3 Perovskite Thin Films for Multifunctional Composite Barriers

ACS Applied Nano Materials, 2019

Research paper thumbnail of Low-temperature methane oxidation over single crystal Pd (100)

Research paper thumbnail of Reversible Formation of Palladium Carbide on Palladium Nanoparticles under CO Oxidation Conditions

Research paper thumbnail of Acetate formation during the ethanol oxidation on Rh(111)

Research paper thumbnail of Complex Interaction of Hydrogen with the RuO2(110) Surface

The Journal of Physical Chemistry C, 2007

Using a variety of dedicated surface sensitive techniques, we studied the interaction of hydrogen... more Using a variety of dedicated surface sensitive techniques, we studied the interaction of hydrogen with bare and adsorbate modified RuO2 (110) surfaces on the atomic scale. Hydrogen interacts strongly with the undercoordinated O atoms, thereby forming hydroxyl ...

Research paper thumbnail of Influence of Oxygen Vacancies on the Properties of Ceria-Supported Gold

The Journal of Physical Chemistry C, 2009

ABSTRACT The adsorption of CO on nanosized gold particles deposited on a cerium oxide substrate i... more ABSTRACT The adsorption of CO on nanosized gold particles deposited on a cerium oxide substrate is strongly influenced by the roughness and concentration of oxygen vacancies of the CeOx substrate surface. Literature showed that Au nucleates at step edges on oxidized samples. For oxidized samples we found that the Au dispersion is dependent on the surface roughness. A rough CeO2 surface has a higher step density, which results in a Au higher particle density with a smaller average diameter. Other studies showed that Au nucleates on oxygen vacancies on reduced CeOx substrates. We found that small Au particles adsorbed on oxygen vacancies exhibit a significantly higher Au 4f binding energy than Au particles on oxidized CeO2. Relatively less CO adsorbs on small Au particles on a reduced substrate, with a significantly lower adsorption energy than on Au on an oxidized substrate. For larger particles the influence of oxygen vacancies in the substrate is negligible.

Research paper thumbnail of Growth and Reactivity of Titanium Oxide Ultrathin Films on Ni(110)

The Journal of Physical Chemistry C, 2007

Soft X-ray photoelectron spectroscopy (SXPS) and X-ray absorption near-edge structure (XANES) hav... more Soft X-ray photoelectron spectroscopy (SXPS) and X-ray absorption near-edge structure (XANES) have been combined with low-energy electron diffraction (LEED) to examine the growth of titanium dioxide thin films on Ni (110). Depending on the initial titanium ...

Research paper thumbnail of Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic Conditions

The Journal of Physical Chemistry C, 2010

ABSTRACT Using a combination of surface X-ray diffraction and mass spectrometry at realistic pres... more ABSTRACT Using a combination of surface X-ray diffraction and mass spectrometry at realistic pressures, the CO oxidation reactivity of a Rh(111) model catalyst has been studied in conjunction with the surface structure. The measurements show that a specific thin surface oxide is always present in the high activity regime of Rh-based CO oxidation.

Research paper thumbnail of CO Adsorption on a Au/CeO2 (111) Model Catalyst

The Journal of Physical Chemistry C, 2008

Research paper thumbnail of Kinetics of the Reduction of the Rh(111) Surface Oxide:  Linking Spectroscopy and Atomic-Scale Information

The Journal of Physical Chemistry B, 2006

Research paper thumbnail of Unusual Process of Water Formation on RuO2(110) by Hydrogen Exposure at Room Temperature

The Journal of Physical Chemistry B, 2006

Research paper thumbnail of Step enhanced dehydrogenation of ethanol on Rh

Research paper thumbnail of Stressing Pd atoms: Initial oxidation of the Pd(110) surface

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