Roland Solimando - Academia.edu (original) (raw)

Papers by Roland Solimando

Research paper thumbnail of Equations d'état susceptibles de représenter les fluides pétroliers

Http Www Theses Fr, 1991

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Research paper thumbnail of Phase equilibria modelling for binary systems that contain CO2

Fluid Phase Equilibria, 1997

... Article Outline. • References. HaUlS[ EOglUDRIA ELSEVIER Fluid Phase Equilibria 134 (1997) 63... more ... Article Outline. • References. HaUlS[ EOglUDRIA ELSEVIER Fluid Phase Equilibria 134 (1997) 6375 Phase equilibria modelling for binary systems that contain CO2 E. Cassel a, M. Matt a, M. Rogalski a.*, R ... Eng. Chem. 43 (1951) 25152520. [16] PK Behrens and SI Sandier ...

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Research paper thumbnail of Solutions aqueuses d'électrolytes. Détermination des paramètres du modèle de Pitzer à partir de mesures calorimétriques. Cas du système {H2O-Na2SO4}

Entropie, 1997

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Research paper thumbnail of Thermodynamic study of magnesium sulfate crystallization: application of Pitzer model and quinary diagrams

Desalination and Water Treatment, 2015

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Research paper thumbnail of Activity Coefficients at Infinite Dilution of Organic Compounds in 1-Butyl-3-methylimidazolium Tetrafluoroborate Using Inverse Gas Chromatography

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Research paper thumbnail of Determination of experimental excess molar properties for mixtures of carboxylic acids

MATEC Web of Conferences, 2013

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Research paper thumbnail of Dissolution enthalpy of NaCl in water at 25°C, 45°C and 60°C. Determination of the Pitzer's parameters of the {H2ONaCl} system and the molar dissolution enthalpy at infinite dilution of NaCl in water between 25°C and 100°C

Thermochimica Acta, 1997

... enthalpy at infinite dilution of NaC1 in water between 25C and 100C Nathalie Hubert*, Roland ... more ... enthalpy at infinite dilution of NaC1 in water between 25C and 100C Nathalie Hubert*, Roland Solimando, Alexandra Pere, Louis Schuffenecker Laboratoire de Thermodynamique des Sdparations, Ecole Nationale Sup ieure des Industries Chimiques, 1, Rue Grandville, BP 451 ...

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Research paper thumbnail of Thermodynamics of crystallization of sodium sulfate decahydrate in H2O–NaCl–Na2SO4: application to Na2SO4·10H2O-based latent heat storage materials

Thermochimica Acta, 2000

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Research paper thumbnail of Stacking phenomena in polyaromatic compounds

Thermochimica Acta, 1999

ABSTRACT Solid–liquid equilibria (SLE) and formation of films at the air/water interface were inv... more ABSTRACT Solid–liquid equilibria (SLE) and formation of films at the air/water interface were investigated for binaries formed with 1-pyrenecarboxaldehyde (PCA) or fluorenone, mixed with pyrene or phenanthrene. In all systems studied, the components are non-miscible in the solid phase. Two eutectic points and the formation of a solid compound is observed in the diagram. The aggregation phenomena occurring in presence of water can lead to the formation of organized structures, similar to those observed in the case of surfactant/water systems. The results obtained suggest that these polyaromatic molecules have a tendency to stacking and agglomerating.

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Research paper thumbnail of Heat capacity estimations using equations of state

Thermochimica Acta, 1992

ABSTRACT Five equations of state accurately expressing the vapor pressures of hydrocarbons were u... more ABSTRACT Five equations of state accurately expressing the vapor pressures of hydrocarbons were used to estimate ΔCp, the difference between liquid and ideal gas heat capacities. It was observed that two equations of state giving equally accurate vapor pressures can yield very different ΔCp estimates. The consequences are investigated and discussed.

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Research paper thumbnail of Dissolution enthalpy of anhydrous sodium sulfate in water. Experimental measurements and treatment with the electrolyte-NRTL model

The Journal of Chemical Thermodynamics, 2002

ABSTRACT Dissolution enthalpies of anhydrous sodium sulfate in water were measured up to saturati... more ABSTRACT Dissolution enthalpies of anhydrous sodium sulfate in water were measured up to saturation atT= (287.8, 317.5, and 352.1) K with a SETARAM C80 mixing calorimeter. Experimental isotherms, and previous ones at T= 297.6 K and T= 317.5 K (Hubert, N. et al., Thermochim. Acta1995, 259, 41–48), all intersect around a molality of 2 mol · kg−1. These five isotherms have been fitted with the electrolyte-NRTL model according to a methodology presented in this paper. This methodology uses enthalpy values along with values atT= 298.15 K from the literature and leads to the proposal of a unique set of parameters that allows a simultaneous representation of dissolution enthalpies, apparent relative molar enthalpies, and osmotic coefficients of sodium sulfate in water. Very good agreement was obtained between experimental and calculated values of dissolution enthalpies and osmotic coefficients in (water + sodium sulfate).

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Research paper thumbnail of Etude d'équations d'état en vue de représenter les propriétés PVT et les équilibres liquide-vapeur d'hydrocarbures

Oil & Gas Science and Technology, 1995

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Research paper thumbnail of Vapor Pressure and Dissolution Enthalpy Measurements in Ternary {H 2 O + NaCl + Na 2 SO 4 } System between 298 K and 363 K

Journal of Chemical & Engineering Data, 2003

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Research paper thumbnail of Evaluation of the Performance of Four Solvents for the Liquid–Liquid Extraction of Acrylic Acid from Water

Journal of Chemical & Engineering Data, 2012

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Research paper thumbnail of Solid−Liquid Equilibrium and Excess Enthalpy Measurements in Binary {Dibenzofuran or Xanthene + Normal Long-Chain Alkane} Systems

Journal of Chemical & Engineering Data, 2000

ABSTRACT This paper is a continuation of our previous studies on thermodynamic properties of bina... more ABSTRACT This paper is a continuation of our previous studies on thermodynamic properties of binary systems formed by a long-chain n-alkane and a polyaromatic. Solid-liquid equilibrium and enthalpies of mixing data of the following systems were measured: {dibenzofuran (DBF) (CASRN 132-64-9), C12H8O + eicosane (CASRN 112-95-8), C20H42}, {DBF + pentacosane (CASRN 629-99-2), C25H52}, {DBF + octacosane (CASRN 630-02-4), C28H58}, {DBF + hexatriacontane (CASRN 630-08-6), C36H74}, {xanthene (CASRN 92-83-1), C13H10O + eicosane}, {xanthene + octacosane}, {xanthene + hexatriacontane}. All data were correlated using the group contribution model based on the lattice theory of Kehiahian et al. (J. Chim. Phys. 1978, 75, 1032-1048).

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Research paper thumbnail of Thermodynamic Modeling of Mixtures Containing Carboxylic Acids Using the PC-SAFT Equation of State

Industrial & Engineering Chemistry Research, 2012

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Research paper thumbnail of Use of Distribution Functions:  A Useful Tool To Calculate the Properties of Condensate Gases

Industrial & Engineering Chemistry Research, 2000

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Research paper thumbnail of Correlation and predication of physical properties of hydrocarbons with the modified Peng-Robinson equation of state. 2. Representation of the vapor pressures and of the molar volumes

Industrial & Engineering Chemistry Research, 1990

... Marek Rogalski, Bruno Carrier, Roland Solimando, and Andre Pikeloux* Laboratoire de Chimie-Ph... more ... Marek Rogalski, Bruno Carrier, Roland Solimando, and Andre Pikeloux* Laboratoire de Chimie-Physique, Facults des Sciences de Luminy, 13228 Marseille ... Plots of the octane vapor preessure deviations between the data given by the TRC Tables (1987) and those ob-tained ...

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Research paper thumbnail of UNIFAC prediction of infinite dilution activity coefficients and enthalpies of mixing of chlorophenols in aqueous and 1-octane-ol solutions

Fluid Phase Equilibria, 1997

ABSTRACT Modelling of thermodynamic properties of chlorinated phenols in water and in 1-octane-ol... more ABSTRACT Modelling of thermodynamic properties of chlorinated phenols in water and in 1-octane-ol is presented. Activity coefficients at infinite dilution and enthalpies of mixing were considered. The UNIFAC method as presented by Gmehling et al. [J. Gmehling, J. Li, M. Schiller, A modified UNIFAC model: 2. Present parameter matrix and results for different thermodynamic properties, Ind. Eng. Chem. Res. 32 (1993) 178–193] and Larsen et al. [B.L. Larsen, P. Rasmussen, A. Fredenslund, A modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing, Ind. Eng. Chem. Res. 26 (1987) 2274–2286] was used. A method combining the group contribution approach with correlation based on physical descriptors yields results within experimental error.

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Research paper thumbnail of Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium methanesulfonate

Fluid Phase Equilibria, 2010

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Research paper thumbnail of Equations d'état susceptibles de représenter les fluides pétroliers

Http Www Theses Fr, 1991

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Research paper thumbnail of Phase equilibria modelling for binary systems that contain CO2

Fluid Phase Equilibria, 1997

... Article Outline. • References. HaUlS[ EOglUDRIA ELSEVIER Fluid Phase Equilibria 134 (1997) 63... more ... Article Outline. • References. HaUlS[ EOglUDRIA ELSEVIER Fluid Phase Equilibria 134 (1997) 6375 Phase equilibria modelling for binary systems that contain CO2 E. Cassel a, M. Matt a, M. Rogalski a.*, R ... Eng. Chem. 43 (1951) 25152520. [16] PK Behrens and SI Sandier ...

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Research paper thumbnail of Solutions aqueuses d'électrolytes. Détermination des paramètres du modèle de Pitzer à partir de mesures calorimétriques. Cas du système {H2O-Na2SO4}

Entropie, 1997

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Research paper thumbnail of Thermodynamic study of magnesium sulfate crystallization: application of Pitzer model and quinary diagrams

Desalination and Water Treatment, 2015

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Research paper thumbnail of Activity Coefficients at Infinite Dilution of Organic Compounds in 1-Butyl-3-methylimidazolium Tetrafluoroborate Using Inverse Gas Chromatography

Bookmarks Related papers MentionsView impact

Research paper thumbnail of Determination of experimental excess molar properties for mixtures of carboxylic acids

MATEC Web of Conferences, 2013

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Research paper thumbnail of Dissolution enthalpy of NaCl in water at 25°C, 45°C and 60°C. Determination of the Pitzer's parameters of the {H2ONaCl} system and the molar dissolution enthalpy at infinite dilution of NaCl in water between 25°C and 100°C

Thermochimica Acta, 1997

... enthalpy at infinite dilution of NaC1 in water between 25C and 100C Nathalie Hubert*, Roland ... more ... enthalpy at infinite dilution of NaC1 in water between 25C and 100C Nathalie Hubert*, Roland Solimando, Alexandra Pere, Louis Schuffenecker Laboratoire de Thermodynamique des Sdparations, Ecole Nationale Sup ieure des Industries Chimiques, 1, Rue Grandville, BP 451 ...

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Research paper thumbnail of Thermodynamics of crystallization of sodium sulfate decahydrate in H2O–NaCl–Na2SO4: application to Na2SO4·10H2O-based latent heat storage materials

Thermochimica Acta, 2000

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Research paper thumbnail of Stacking phenomena in polyaromatic compounds

Thermochimica Acta, 1999

ABSTRACT Solid–liquid equilibria (SLE) and formation of films at the air/water interface were inv... more ABSTRACT Solid–liquid equilibria (SLE) and formation of films at the air/water interface were investigated for binaries formed with 1-pyrenecarboxaldehyde (PCA) or fluorenone, mixed with pyrene or phenanthrene. In all systems studied, the components are non-miscible in the solid phase. Two eutectic points and the formation of a solid compound is observed in the diagram. The aggregation phenomena occurring in presence of water can lead to the formation of organized structures, similar to those observed in the case of surfactant/water systems. The results obtained suggest that these polyaromatic molecules have a tendency to stacking and agglomerating.

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Research paper thumbnail of Heat capacity estimations using equations of state

Thermochimica Acta, 1992

ABSTRACT Five equations of state accurately expressing the vapor pressures of hydrocarbons were u... more ABSTRACT Five equations of state accurately expressing the vapor pressures of hydrocarbons were used to estimate ΔCp, the difference between liquid and ideal gas heat capacities. It was observed that two equations of state giving equally accurate vapor pressures can yield very different ΔCp estimates. The consequences are investigated and discussed.

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Research paper thumbnail of Dissolution enthalpy of anhydrous sodium sulfate in water. Experimental measurements and treatment with the electrolyte-NRTL model

The Journal of Chemical Thermodynamics, 2002

ABSTRACT Dissolution enthalpies of anhydrous sodium sulfate in water were measured up to saturati... more ABSTRACT Dissolution enthalpies of anhydrous sodium sulfate in water were measured up to saturation atT= (287.8, 317.5, and 352.1) K with a SETARAM C80 mixing calorimeter. Experimental isotherms, and previous ones at T= 297.6 K and T= 317.5 K (Hubert, N. et al., Thermochim. Acta1995, 259, 41–48), all intersect around a molality of 2 mol · kg−1. These five isotherms have been fitted with the electrolyte-NRTL model according to a methodology presented in this paper. This methodology uses enthalpy values along with values atT= 298.15 K from the literature and leads to the proposal of a unique set of parameters that allows a simultaneous representation of dissolution enthalpies, apparent relative molar enthalpies, and osmotic coefficients of sodium sulfate in water. Very good agreement was obtained between experimental and calculated values of dissolution enthalpies and osmotic coefficients in (water + sodium sulfate).

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Research paper thumbnail of Etude d'équations d'état en vue de représenter les propriétés PVT et les équilibres liquide-vapeur d'hydrocarbures

Oil & Gas Science and Technology, 1995

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Research paper thumbnail of Vapor Pressure and Dissolution Enthalpy Measurements in Ternary {H 2 O + NaCl + Na 2 SO 4 } System between 298 K and 363 K

Journal of Chemical & Engineering Data, 2003

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Research paper thumbnail of Evaluation of the Performance of Four Solvents for the Liquid–Liquid Extraction of Acrylic Acid from Water

Journal of Chemical & Engineering Data, 2012

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Research paper thumbnail of Solid−Liquid Equilibrium and Excess Enthalpy Measurements in Binary {Dibenzofuran or Xanthene + Normal Long-Chain Alkane} Systems

Journal of Chemical & Engineering Data, 2000

ABSTRACT This paper is a continuation of our previous studies on thermodynamic properties of bina... more ABSTRACT This paper is a continuation of our previous studies on thermodynamic properties of binary systems formed by a long-chain n-alkane and a polyaromatic. Solid-liquid equilibrium and enthalpies of mixing data of the following systems were measured: {dibenzofuran (DBF) (CASRN 132-64-9), C12H8O + eicosane (CASRN 112-95-8), C20H42}, {DBF + pentacosane (CASRN 629-99-2), C25H52}, {DBF + octacosane (CASRN 630-02-4), C28H58}, {DBF + hexatriacontane (CASRN 630-08-6), C36H74}, {xanthene (CASRN 92-83-1), C13H10O + eicosane}, {xanthene + octacosane}, {xanthene + hexatriacontane}. All data were correlated using the group contribution model based on the lattice theory of Kehiahian et al. (J. Chim. Phys. 1978, 75, 1032-1048).

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Research paper thumbnail of Thermodynamic Modeling of Mixtures Containing Carboxylic Acids Using the PC-SAFT Equation of State

Industrial & Engineering Chemistry Research, 2012

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Research paper thumbnail of Use of Distribution Functions:  A Useful Tool To Calculate the Properties of Condensate Gases

Industrial & Engineering Chemistry Research, 2000

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Research paper thumbnail of Correlation and predication of physical properties of hydrocarbons with the modified Peng-Robinson equation of state. 2. Representation of the vapor pressures and of the molar volumes

Industrial & Engineering Chemistry Research, 1990

... Marek Rogalski, Bruno Carrier, Roland Solimando, and Andre Pikeloux* Laboratoire de Chimie-Ph... more ... Marek Rogalski, Bruno Carrier, Roland Solimando, and Andre Pikeloux* Laboratoire de Chimie-Physique, Facults des Sciences de Luminy, 13228 Marseille ... Plots of the octane vapor preessure deviations between the data given by the TRC Tables (1987) and those ob-tained ...

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Research paper thumbnail of UNIFAC prediction of infinite dilution activity coefficients and enthalpies of mixing of chlorophenols in aqueous and 1-octane-ol solutions

Fluid Phase Equilibria, 1997

ABSTRACT Modelling of thermodynamic properties of chlorinated phenols in water and in 1-octane-ol... more ABSTRACT Modelling of thermodynamic properties of chlorinated phenols in water and in 1-octane-ol is presented. Activity coefficients at infinite dilution and enthalpies of mixing were considered. The UNIFAC method as presented by Gmehling et al. [J. Gmehling, J. Li, M. Schiller, A modified UNIFAC model: 2. Present parameter matrix and results for different thermodynamic properties, Ind. Eng. Chem. Res. 32 (1993) 178–193] and Larsen et al. [B.L. Larsen, P. Rasmussen, A. Fredenslund, A modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing, Ind. Eng. Chem. Res. 26 (1987) 2274–2286] was used. A method combining the group contribution approach with correlation based on physical descriptors yields results within experimental error.

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Research paper thumbnail of Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium methanesulfonate

Fluid Phase Equilibria, 2010

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