Semaghiul Birghila - Academia.edu (original) (raw)
Papers by Semaghiul Birghila
Environmental Engineering and Management Journal, 2008
The aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain ... more The aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between other components, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers-blue hyacinth and chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrant springtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered forms. Flame atomic absorption spectrometry (FAAS) was used for the quantitative determination of metals in this matrix. Also, the refraction indexes and conductivity were measured using Abbe refractometer and LF 340-A conductometer, for the characterization of the obtained mixtures, respectively for correlation with the mineral content. It was observed that that iron concentrations are higher in blue hyacinth extract and macerates than chrysanthemum.
Environmental Engineering and Management Journal, 2005
Mud treatment is one of the oldest treatment procedures. The therapeutic value of water and mud f... more Mud treatment is one of the oldest treatment procedures. The therapeutic value of water and mud from the Salt Lake (Lacu Sarat) is known for a long time by the inhabitants of this region, but yearly a lot of tourists come here and most of them for a cure. This paper presents the results of studies for the duration of two years, with the students of the Department of Chemistry research group. These were analyzed the total contents of Fe, Cu and Cr in the sapropelic mud, for analytical characterization of the therapeutic and used mud. The methods applied were the titrimetric and molecular absorption spectrometry ones. The obtained results led us to evidence an ionic exchange between the therapeutic mud and the human organism at the epithelial level. In the field of natural cure, Romania has a special position thanks to its natural cure factors: mineral and thermal waters, therapeutic mud and lakes. Variety of natural resources and quality ranks Romania on the first place in Europe.
Journal of Elementology, 2005
Journal of Elementology, 2005
Environmental Engineering and Management Journal, 2004
Analyses of plants render important information in toxicological and environmental investigations... more Analyses of plants render important information in toxicological and environmental investigations since plants are a very significant link in the trophic chain. The aim of this study was to analyze quantitatively the distribution of heavy metals and ascorbic acid in Allium plants: Allium sativum L. (garlic) and Allium cepa L. (onion). Heavy metals accumulation in garlic and onion was quantified by flame atomic absorption spectrometry (FAAS) after the chemical mineralization of the samples with nitric acid and hydrogen peroxide in a Digesthal device. To determinate of vitamin C we used a titrimetric method with potassium brommat-bromide solution in acid medium, when vitamin C is oxidized to dehidroascorbic acid by bromine. Our results indicate a high concentration of vitamin C in leaves of the studied Allium plants.
Heavy metals are natural components of the Earth's crust that cannot be degraded or destroyed. As... more Heavy metals are natural components of the Earth's crust that cannot be degraded or destroyed. As trace elements some of them (e.g. copper, selenium, zinc) are essential to maintain the metabolism of human body, although at higher concentrations they can lead to poisoning. This work is going to present the results obtained from the determinations of grapes and melons extracts. For obtaining the extracts, Soxhlet extraction, maceration and ultrasonic method were used. A Shimadzu atomic absorption spectrometer (Model AA 6200) equipped with air-acetylene flame, was used to determine the Cu, Mn and Zn concentrations. Also, the refraction indices and relative density were measured, using an Abbé refractometer and a picnometer. The obtained results show that the highest Cu and Zn content is in the melons skin, the highest Mn content is in the grapes skin. The refraction indices and the density's values are very close to that from the Romanian standards. In the last part of this study we are
Springer eBooks, Jan 16, 2007
Journal of Elementology, 2005
Environmental Engineering and Management Journal, 2008
Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels... more Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector (GC-MS) and by gas chromatography with electron capture detector (GC-ECD).
Environmental Engineering and Management Journal, 2006
Vegetables constitute an important part of the human diet since they contain carbohydrates, prote... more Vegetables constitute an important part of the human diet since they contain carbohydrates, proteins, vitamins, minerals and trace elements. Vegetables grown at contaminated sites could take up and accumulate metals at concentrations that are toxic. Heavy metals are known to pose a variety of health risks such as cancer or mutations. The objective of this study was to analyze quantitatively the distribution of heavy metal and the organochlorine pesticides in Capsicum annuum L (pepper) grown in two different places, one indoors with no pollutants using soil from Babadag forest far from the city and second place is an urban garden from Constantza city expose to the city pollution. Metals were detected at mg/Kg levels and OCPs at ng/kg levels.
Environmental Engineering and Management Journal, 2010
The aim of present study was to determine the physical and chemical characteristics of different ... more The aim of present study was to determine the physical and chemical characteristics of different types of butter produced from pasteurized cream during the storage time. Therefore, the effect of storage time on the stability of low and high fat butters was evaluated. Samples were stored at +4° C at dark, and the reaction was observed by measuring peroxide value (PV), free fatty acids (FFA), refraction index, saponification value and water content. The peroxide values increased in the time, but this was not significant. PV values in both types of butter remained under permitted limits during the first three weeks of storage, followed by an unacceptable increase by the end of the shelf period. The storage time did not significantly influence the profile of free fat acids, even that little variations were observed.
Processes, Dec 1, 2022
This article is an open access article distributed under the terms and conditions of the Creative... more This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY
Environmental Engineering and Management Journal, 2007
Some industry activities in the area of Constanta (Romania) contribute to the polluting of the en... more Some industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the sample with a Digesdahl device. These levels were compared with those from literature.
Environmental Engineering and Management Journal, 2008
A study was conducted to investigate the organic compounds residues in different types of coffee ... more A study was conducted to investigate the organic compounds residues in different types of coffee from market in Romania. High pressure liquid chromatography with fluorescence detector (HPLC), respectively gas chromatography with electron capture detection (GC-ECD) was used for the determination of 7 polycyclic aromatic hydrocarbons (PAHs) and 9 organochlorine pesticides (OCPs) in coffee samples. It was found that concentrations of PAHs in coffee samples varied from 0.001 µg/Kg to 90.732 µg/Kg. B[a]P was absent in the green coffee samples. The detection limits ranged from 0.02 ng/kg to 0.04 ng/kg and quantification limits were 0.2 ng/kg. Calibration and recovery studies gave satisfactory results. Concentrations of OCPs in coffee samples varied from 0.001 mg/Kg to 0.007 mg/Kg. The methods provide a rapid and accurate determination of these organic compounds in coffee samples.
Environmental Engineering and Management Journal, 2008
Milk products are a very important human nutrient since their consumption has increased in recent... more Milk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarket chains in Romania. Inductively coupled plasma atomic emission spectrometry (ICP-AES) was used for the quantitative determination of elements in this matrix. Analyses were performed after the chemical mineralization of the samples with nitrogen acid. Detection limits ranged from 0.4 to7.03 ng/g.
Environmental Engineering and Management Journal, 2013
Fluoride content in some available teas, dry leaves and tea infusions were determined, in order t... more Fluoride content in some available teas, dry leaves and tea infusions were determined, in order to check the influence of brewing time on fluoride content in tea and to compare the percent extraction of fluoride releasing during tea infusion time. A fluoride ion selective electrode was used to determinate the fluoride content in tea samples (Hypericum perforatum, Tilia cordata and Camellia sinensis). Total fluoride contents of tea leaves were determined to be 91.1-162 mg/kg d.w., and 0.095-1.450 mg/L in tea infusions and the percentage of fluoride infused for analysed tea leaves ranged from 7.2% to 89.5%. The study shows that there are differences between the fluoride percentage in the tea infusions and about 85% of fluoride in tea leaves was released into Hypericum perforatum and Camellia sinensis, after 30 min of brewing. Tilia cordata shows a slow growth during the infusion process, having the lowest percentage of fluoride.
Polycyclic Aromatic Compounds, Nov 21, 2021
SEMAGHIUL BIRGHILA1, MIHAELA MIRELA BRATU2*, CORINA PRAJITURA2, FLORENTINA NICOLETA RONCEA2, TICU... more SEMAGHIUL BIRGHILA1, MIHAELA MIRELA BRATU2*, CORINA PRAJITURA2, FLORENTINA NICOLETA RONCEA2, TICUTA NEGREANU-PIRJOL2 1”Ovidius” University of Constanþa, Faculty of Physics, Chemistry, Electronics and Petroleum Technology, Department of Chemistry and Chemical Engineering, 124 Mamaia Bvd., 900527, Constanþa, Romania 2”Ovidius” University of Constanþa, Faculty of Pharmacy, 1, University Alley, Campus, Corp B, 900470, Constanþa, Romania
DOAJ (DOAJ: Directory of Open Access Journals), Mar 1, 2018
We studied four edible vegetable oils and nine oil blends based on refined sunflower oil, in orde... more We studied four edible vegetable oils and nine oil blends based on refined sunflower oil, in order to improve the quality characteristics of sunflower oil. The oils used for blends were linseed oil, grapeseed oil, and coconut oil. The physico-chemical properties demonstrated the superior features for oil blends, like lower acidity (measured by acid value) and higher stability to autoxidation (measured by peroxide value and refractive index). The best combination for sunflower oil was with coconut oil (lower acidity, higher stability to autoxidation). For a supplementary improvement of properties, especially for the preservation of oils and oil blends, we tested the lovage (Levisticum officinale) extract as additive. The obtained additivated mixtures demonstrated better quality characteristics, which recommend them for the human consumption.
Environmental Engineering and Management Journal, 2008
The aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain ... more The aim of this work was to study the content of Fe, Mn, Zn and Pb in the mixtures which contain volatile oil between other components, obtained after the Soxhlet extraction or maceration of the samples (different organs of garden flowers-blue hyacinth and chrysanthemum). The blue hyacinth is a bulbous perennial herb in the Lilliaceae family, grown for its showy and fragrant springtime flower display. Garden chrysanthemums are tender perennials in the Asteraceae family in double-flowered forms. Flame atomic absorption spectrometry (FAAS) was used for the quantitative determination of metals in this matrix. Also, the refraction indexes and conductivity were measured using Abbe refractometer and LF 340-A conductometer, for the characterization of the obtained mixtures, respectively for correlation with the mineral content. It was observed that that iron concentrations are higher in blue hyacinth extract and macerates than chrysanthemum.
Environmental Engineering and Management Journal, 2005
Mud treatment is one of the oldest treatment procedures. The therapeutic value of water and mud f... more Mud treatment is one of the oldest treatment procedures. The therapeutic value of water and mud from the Salt Lake (Lacu Sarat) is known for a long time by the inhabitants of this region, but yearly a lot of tourists come here and most of them for a cure. This paper presents the results of studies for the duration of two years, with the students of the Department of Chemistry research group. These were analyzed the total contents of Fe, Cu and Cr in the sapropelic mud, for analytical characterization of the therapeutic and used mud. The methods applied were the titrimetric and molecular absorption spectrometry ones. The obtained results led us to evidence an ionic exchange between the therapeutic mud and the human organism at the epithelial level. In the field of natural cure, Romania has a special position thanks to its natural cure factors: mineral and thermal waters, therapeutic mud and lakes. Variety of natural resources and quality ranks Romania on the first place in Europe.
Journal of Elementology, 2005
Journal of Elementology, 2005
Environmental Engineering and Management Journal, 2004
Analyses of plants render important information in toxicological and environmental investigations... more Analyses of plants render important information in toxicological and environmental investigations since plants are a very significant link in the trophic chain. The aim of this study was to analyze quantitatively the distribution of heavy metals and ascorbic acid in Allium plants: Allium sativum L. (garlic) and Allium cepa L. (onion). Heavy metals accumulation in garlic and onion was quantified by flame atomic absorption spectrometry (FAAS) after the chemical mineralization of the samples with nitric acid and hydrogen peroxide in a Digesthal device. To determinate of vitamin C we used a titrimetric method with potassium brommat-bromide solution in acid medium, when vitamin C is oxidized to dehidroascorbic acid by bromine. Our results indicate a high concentration of vitamin C in leaves of the studied Allium plants.
Heavy metals are natural components of the Earth's crust that cannot be degraded or destroyed. As... more Heavy metals are natural components of the Earth's crust that cannot be degraded or destroyed. As trace elements some of them (e.g. copper, selenium, zinc) are essential to maintain the metabolism of human body, although at higher concentrations they can lead to poisoning. This work is going to present the results obtained from the determinations of grapes and melons extracts. For obtaining the extracts, Soxhlet extraction, maceration and ultrasonic method were used. A Shimadzu atomic absorption spectrometer (Model AA 6200) equipped with air-acetylene flame, was used to determine the Cu, Mn and Zn concentrations. Also, the refraction indices and relative density were measured, using an Abbé refractometer and a picnometer. The obtained results show that the highest Cu and Zn content is in the melons skin, the highest Mn content is in the grapes skin. The refraction indices and the density's values are very close to that from the Romanian standards. In the last part of this study we are
Springer eBooks, Jan 16, 2007
Journal of Elementology, 2005
Environmental Engineering and Management Journal, 2008
Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels... more Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) contamination levels were determined in the water samples of Danube river (two sites in Romanian area), of one Romanian spring water (Pelisor), in tap water (from Constantza and from Borovetz) and sea water (the Black Sea and the Mediteranean Sea). These levels were compared to those available for other surface waters. The studied water samples were analyzed by gas chromatography with mass spectrometer detector (GC-MS) and by gas chromatography with electron capture detector (GC-ECD).
Environmental Engineering and Management Journal, 2006
Vegetables constitute an important part of the human diet since they contain carbohydrates, prote... more Vegetables constitute an important part of the human diet since they contain carbohydrates, proteins, vitamins, minerals and trace elements. Vegetables grown at contaminated sites could take up and accumulate metals at concentrations that are toxic. Heavy metals are known to pose a variety of health risks such as cancer or mutations. The objective of this study was to analyze quantitatively the distribution of heavy metal and the organochlorine pesticides in Capsicum annuum L (pepper) grown in two different places, one indoors with no pollutants using soil from Babadag forest far from the city and second place is an urban garden from Constantza city expose to the city pollution. Metals were detected at mg/Kg levels and OCPs at ng/kg levels.
Environmental Engineering and Management Journal, 2010
The aim of present study was to determine the physical and chemical characteristics of different ... more The aim of present study was to determine the physical and chemical characteristics of different types of butter produced from pasteurized cream during the storage time. Therefore, the effect of storage time on the stability of low and high fat butters was evaluated. Samples were stored at +4° C at dark, and the reaction was observed by measuring peroxide value (PV), free fatty acids (FFA), refraction index, saponification value and water content. The peroxide values increased in the time, but this was not significant. PV values in both types of butter remained under permitted limits during the first three weeks of storage, followed by an unacceptable increase by the end of the shelf period. The storage time did not significantly influence the profile of free fat acids, even that little variations were observed.
Processes, Dec 1, 2022
This article is an open access article distributed under the terms and conditions of the Creative... more This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY
Environmental Engineering and Management Journal, 2007
Some industry activities in the area of Constanta (Romania) contribute to the polluting of the en... more Some industry activities in the area of Constanta (Romania) contribute to the polluting of the environment with heavy metals. In order to estimate the pollution level and the danger created by this phenomenon, some analyses are required with regard to determining the concentration of the pollutant metals in plants samples. The investigated metals were determined by flame atomic absorbtion spectrometry in different types of vegetables and fruits, after the chemical mineralization of the sample with a Digesdahl device. These levels were compared with those from literature.
Environmental Engineering and Management Journal, 2008
A study was conducted to investigate the organic compounds residues in different types of coffee ... more A study was conducted to investigate the organic compounds residues in different types of coffee from market in Romania. High pressure liquid chromatography with fluorescence detector (HPLC), respectively gas chromatography with electron capture detection (GC-ECD) was used for the determination of 7 polycyclic aromatic hydrocarbons (PAHs) and 9 organochlorine pesticides (OCPs) in coffee samples. It was found that concentrations of PAHs in coffee samples varied from 0.001 µg/Kg to 90.732 µg/Kg. B[a]P was absent in the green coffee samples. The detection limits ranged from 0.02 ng/kg to 0.04 ng/kg and quantification limits were 0.2 ng/kg. Calibration and recovery studies gave satisfactory results. Concentrations of OCPs in coffee samples varied from 0.001 mg/Kg to 0.007 mg/Kg. The methods provide a rapid and accurate determination of these organic compounds in coffee samples.
Environmental Engineering and Management Journal, 2008
Milk products are a very important human nutrient since their consumption has increased in recent... more Milk products are a very important human nutrient since their consumption has increased in recent years. Good quality measurements are essential to control and maintain milk products and processes quality, both in manufacturing, trade and in research. The presence of toxic elements in powdered and liquid milk may create significant health problems for people. The aim of this paper was to determine the content of major and minor elements in different milk samples, sold in major supermarket chains in Romania. Inductively coupled plasma atomic emission spectrometry (ICP-AES) was used for the quantitative determination of elements in this matrix. Analyses were performed after the chemical mineralization of the samples with nitrogen acid. Detection limits ranged from 0.4 to7.03 ng/g.
Environmental Engineering and Management Journal, 2013
Fluoride content in some available teas, dry leaves and tea infusions were determined, in order t... more Fluoride content in some available teas, dry leaves and tea infusions were determined, in order to check the influence of brewing time on fluoride content in tea and to compare the percent extraction of fluoride releasing during tea infusion time. A fluoride ion selective electrode was used to determinate the fluoride content in tea samples (Hypericum perforatum, Tilia cordata and Camellia sinensis). Total fluoride contents of tea leaves were determined to be 91.1-162 mg/kg d.w., and 0.095-1.450 mg/L in tea infusions and the percentage of fluoride infused for analysed tea leaves ranged from 7.2% to 89.5%. The study shows that there are differences between the fluoride percentage in the tea infusions and about 85% of fluoride in tea leaves was released into Hypericum perforatum and Camellia sinensis, after 30 min of brewing. Tilia cordata shows a slow growth during the infusion process, having the lowest percentage of fluoride.
Polycyclic Aromatic Compounds, Nov 21, 2021
SEMAGHIUL BIRGHILA1, MIHAELA MIRELA BRATU2*, CORINA PRAJITURA2, FLORENTINA NICOLETA RONCEA2, TICU... more SEMAGHIUL BIRGHILA1, MIHAELA MIRELA BRATU2*, CORINA PRAJITURA2, FLORENTINA NICOLETA RONCEA2, TICUTA NEGREANU-PIRJOL2 1”Ovidius” University of Constanþa, Faculty of Physics, Chemistry, Electronics and Petroleum Technology, Department of Chemistry and Chemical Engineering, 124 Mamaia Bvd., 900527, Constanþa, Romania 2”Ovidius” University of Constanþa, Faculty of Pharmacy, 1, University Alley, Campus, Corp B, 900470, Constanþa, Romania
DOAJ (DOAJ: Directory of Open Access Journals), Mar 1, 2018
We studied four edible vegetable oils and nine oil blends based on refined sunflower oil, in orde... more We studied four edible vegetable oils and nine oil blends based on refined sunflower oil, in order to improve the quality characteristics of sunflower oil. The oils used for blends were linseed oil, grapeseed oil, and coconut oil. The physico-chemical properties demonstrated the superior features for oil blends, like lower acidity (measured by acid value) and higher stability to autoxidation (measured by peroxide value and refractive index). The best combination for sunflower oil was with coconut oil (lower acidity, higher stability to autoxidation). For a supplementary improvement of properties, especially for the preservation of oils and oil blends, we tested the lovage (Levisticum officinale) extract as additive. The obtained additivated mixtures demonstrated better quality characteristics, which recommend them for the human consumption.