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電気学会研究会資料 Mbe 医用 生体工学研究会, Mar 31, 2010
電気学会研究会資料 Mbe 医用 生体工学研究会, Mar 31, 2010
Journal of Adhesion Science and Technology
ABSTRACT
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2007
The degree of chlorination in chlorinated, vulcanized natural rubber was determined by X-ray abso... more The degree of chlorination in chlorinated, vulcanized natural rubber was determined by X-ray absorption near-edge spectroscopy (XANES). The vulcanized natural rubber samples were prepared in film with thickness of 180μm, approximately. They were treated with chlorination solution with different immersion times ranging from 0.5 to 30min. Experimental results implied that incorporated chlorine atoms were covalently bonded to carbon atoms in
Polymer Testing, 2014
ABSTRACT
Polymer Testing, 2014
ABSTRACT
Khon Kaen University Journal (Graduate Studies), 2009
Advanced Materials Research, 2013
ABSTRACT
Advanced Materials Research, 2013
ABSTRACT Non-rubber components (mainly proteins and lipids) in natural rubber (NR) play important... more ABSTRACT Non-rubber components (mainly proteins and lipids) in natural rubber (NR) play important roles for controlling the properties of NR. Crosslinking process creates intermolecular chemical bonds in order to obtain a three-dimensional network, resulting in more elastic rubber. Sulphur crosslinking is the most popular method and is applied in the present study. Two types of NR were prepared, namely, whole natural rubber (WNR) and purified natural rubber (PNR). PNR was deproteinized by centrifugation method and then acetone extraction. These rubbers were crosslinked by an efficient vulcanization (EV) system. They were cured for three curing times (1xt90, 2xt90, 3xt90) at 150°C. WNR presents shorter curing time than PNR because there are some phospholipids and proteins which are natural accelerators for curing reaction. The presence of non-rubber components seems to play a major role on crosslinking density and adhesion phenomenon for rubber/glass system. AFM images of WNR show more heterogeneity and roughness compared to PNR.
Journal of Applied Polymer Science, 2008
Journal of Applied Polymer Science, 2012
International Journal of Polymeric Materials, 2014
European Polymer Journal, 2009
Polymer Testing, May 1, 2007
電気学会研究会資料 Mbe 医用 生体工学研究会, Mar 31, 2010
電気学会研究会資料 Mbe 医用 生体工学研究会, Mar 31, 2010
Journal of Adhesion Science and Technology
ABSTRACT
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2007
The degree of chlorination in chlorinated, vulcanized natural rubber was determined by X-ray abso... more The degree of chlorination in chlorinated, vulcanized natural rubber was determined by X-ray absorption near-edge spectroscopy (XANES). The vulcanized natural rubber samples were prepared in film with thickness of 180μm, approximately. They were treated with chlorination solution with different immersion times ranging from 0.5 to 30min. Experimental results implied that incorporated chlorine atoms were covalently bonded to carbon atoms in
Polymer Testing, 2014
ABSTRACT
Polymer Testing, 2014
ABSTRACT
Khon Kaen University Journal (Graduate Studies), 2009
Advanced Materials Research, 2013
ABSTRACT
Advanced Materials Research, 2013
ABSTRACT Non-rubber components (mainly proteins and lipids) in natural rubber (NR) play important... more ABSTRACT Non-rubber components (mainly proteins and lipids) in natural rubber (NR) play important roles for controlling the properties of NR. Crosslinking process creates intermolecular chemical bonds in order to obtain a three-dimensional network, resulting in more elastic rubber. Sulphur crosslinking is the most popular method and is applied in the present study. Two types of NR were prepared, namely, whole natural rubber (WNR) and purified natural rubber (PNR). PNR was deproteinized by centrifugation method and then acetone extraction. These rubbers were crosslinked by an efficient vulcanization (EV) system. They were cured for three curing times (1xt90, 2xt90, 3xt90) at 150°C. WNR presents shorter curing time than PNR because there are some phospholipids and proteins which are natural accelerators for curing reaction. The presence of non-rubber components seems to play a major role on crosslinking density and adhesion phenomenon for rubber/glass system. AFM images of WNR show more heterogeneity and roughness compared to PNR.
Journal of Applied Polymer Science, 2008
Journal of Applied Polymer Science, 2012
International Journal of Polymeric Materials, 2014
European Polymer Journal, 2009
Polymer Testing, May 1, 2007