Terence Lomax - Academia.edu (original) (raw)
Papers by Terence Lomax
Journal of the American Chemical Society, Aug 1, 1978
Tetrahedron Letters, 1983
Abstract Application of the sequential self-association model to aminolysis reactions in alkyldia... more Abstract Application of the sequential self-association model to aminolysis reactions in alkyldiamine bis(dodecanoate)-benzene systems is investigated.
Journal of Adhesion Science and Technology, 2002
ABSTRACT A rapid-setting, starch-based lignocellulosic adhesive is described which could be cured... more ABSTRACT A rapid-setting, starch-based lignocellulosic adhesive is described which could be cured at ambient temperature to form a lmhaving a clear appearance and signi cant moisture resistance when tested under ambient conditions. Maltodextrins with a dextrose equivalent (DE) range of 5–25 were reacted as an intimate mixture in the dry state with N-methylolacrylamide (N-MAM) to give products containing the corresponding carbohydrate methyleneacrylamido ethers, which were characterized by NMR spectroscopy and electrospray mass spectrometry. The reaction products, comprising mixtures of maltodextrins and methyleneacrylamido ethers, were formulated in water for paper adhesive use and tested for performance. Paper strip peel tests showed a time to bre tear of 2 min, an initial time to paper tear of 5 min, and 10 min to full paper adhesion. The failure load was 2.4 kN, diminishing to 1 kN after a 24 h cold water soak.
Journal of Colloid and Interface Science, Sep 1, 1983
The rate of decomposition of p-nitrophenyl acetate, pnpa, has been measured in benzene solutions ... more The rate of decomposition of p-nitrophenyl acetate, pnpa, has been measured in benzene solutions of a series of alkylammonium propionates, CH3(CH2),NH3+-02CCH2CH3 (where n = 3, 5, 7, 9 or 1 I), and a series of dodecylammonium carboxylates, CH3(CH2)11NH3 +-O2C(CH2),,,CH3 where m = 1, 2, 6 or 7). The micellar rate constant is affected by the alkyl chain length. The bimolecular rate constant is affected by both the chain length and the acidity of the head-groups. The reactivity of longer chain esters with dodecylammonium propionate is markedly less than that of pnpa.
Chemischer Informationsdienst, Dec 5, 1978
Chemischer Informationsdienst, Aug 21, 1984
Springer eBooks, 1982
Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aq... more Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aqueous detergent systems, and much of the early work on surfactant aggregates in nonpolar solvents arose from the concept of modelling the active site of proteolytic enzymes. Moreover, the readiness with which quite large concentrations of water and substrate were solubilized in the polar interior of reversed micelles led to the attractive possibility of determining reaction order with respect to water.
Die Makromolekulare Chemie, Rapid Communications, Jul 1, 1991
Solution Behavior of Surfactants, 1982
Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aq... more Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aqueous detergent systems, and much of the early work on surfactant aggregates in nonpolar solvents arose from the concept of modelling the active site of proteolytic enzymes. Moreover, the readiness with which quite large concentrations of water and substrate were solubilized in the polar interior of reversed micelles led to the attractive possibility of determining reaction order with respect to water.
Tetrahedron Letters, 1983
Abstract Application of the sequential self-association model to aminolysis reactions in alkyldia... more Abstract Application of the sequential self-association model to aminolysis reactions in alkyldiamine bis(dodecanoate)-benzene systems is investigated.
Journal of the American Chemical Society, 1978
Advances in Colloid and Interface Science, 1984
... 20 (1984) 21 97 21 Elsevier Science Publishers BV, Amsterdam Printed in The Netherlands EXPLO... more ... 20 (1984) 21 97 21 Elsevier Science Publishers BV, Amsterdam Printed in The Netherlands EXPLOITATION OF REVERSED MICELLES AS MEMBRANE MIMETIC REAGENTS CHARHIAN J. 0"CONNOR, TERENCE D. LOMAX and ROBYN E. RAHAGE. ...
Journal of the American Chemical Society, Aug 1, 1978
Tetrahedron Letters, 1983
Abstract Application of the sequential self-association model to aminolysis reactions in alkyldia... more Abstract Application of the sequential self-association model to aminolysis reactions in alkyldiamine bis(dodecanoate)-benzene systems is investigated.
Journal of Adhesion Science and Technology, 2002
ABSTRACT A rapid-setting, starch-based lignocellulosic adhesive is described which could be cured... more ABSTRACT A rapid-setting, starch-based lignocellulosic adhesive is described which could be cured at ambient temperature to form a lmhaving a clear appearance and signi cant moisture resistance when tested under ambient conditions. Maltodextrins with a dextrose equivalent (DE) range of 5–25 were reacted as an intimate mixture in the dry state with N-methylolacrylamide (N-MAM) to give products containing the corresponding carbohydrate methyleneacrylamido ethers, which were characterized by NMR spectroscopy and electrospray mass spectrometry. The reaction products, comprising mixtures of maltodextrins and methyleneacrylamido ethers, were formulated in water for paper adhesive use and tested for performance. Paper strip peel tests showed a time to bre tear of 2 min, an initial time to paper tear of 5 min, and 10 min to full paper adhesion. The failure load was 2.4 kN, diminishing to 1 kN after a 24 h cold water soak.
Journal of Colloid and Interface Science, Sep 1, 1983
The rate of decomposition of p-nitrophenyl acetate, pnpa, has been measured in benzene solutions ... more The rate of decomposition of p-nitrophenyl acetate, pnpa, has been measured in benzene solutions of a series of alkylammonium propionates, CH3(CH2),NH3+-02CCH2CH3 (where n = 3, 5, 7, 9 or 1 I), and a series of dodecylammonium carboxylates, CH3(CH2)11NH3 +-O2C(CH2),,,CH3 where m = 1, 2, 6 or 7). The micellar rate constant is affected by the alkyl chain length. The bimolecular rate constant is affected by both the chain length and the acidity of the head-groups. The reactivity of longer chain esters with dodecylammonium propionate is markedly less than that of pnpa.
Chemischer Informationsdienst, Dec 5, 1978
Chemischer Informationsdienst, Aug 21, 1984
Springer eBooks, 1982
Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aq... more Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aqueous detergent systems, and much of the early work on surfactant aggregates in nonpolar solvents arose from the concept of modelling the active site of proteolytic enzymes. Moreover, the readiness with which quite large concentrations of water and substrate were solubilized in the polar interior of reversed micelles led to the attractive possibility of determining reaction order with respect to water.
Die Makromolekulare Chemie, Rapid Communications, Jul 1, 1991
Solution Behavior of Surfactants, 1982
Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aq... more Reversed micellar systems have borrowed extensively from the nomenclature and concepts used in aqueous detergent systems, and much of the early work on surfactant aggregates in nonpolar solvents arose from the concept of modelling the active site of proteolytic enzymes. Moreover, the readiness with which quite large concentrations of water and substrate were solubilized in the polar interior of reversed micelles led to the attractive possibility of determining reaction order with respect to water.
Tetrahedron Letters, 1983
Abstract Application of the sequential self-association model to aminolysis reactions in alkyldia... more Abstract Application of the sequential self-association model to aminolysis reactions in alkyldiamine bis(dodecanoate)-benzene systems is investigated.
Journal of the American Chemical Society, 1978
Advances in Colloid and Interface Science, 1984
... 20 (1984) 21 97 21 Elsevier Science Publishers BV, Amsterdam Printed in The Netherlands EXPLO... more ... 20 (1984) 21 97 21 Elsevier Science Publishers BV, Amsterdam Printed in The Netherlands EXPLOITATION OF REVERSED MICELLES AS MEMBRANE MIMETIC REAGENTS CHARHIAN J. 0"CONNOR, TERENCE D. LOMAX and ROBYN E. RAHAGE. ...