Thomas Joffre - Academia.edu (original) (raw)
Papers by Thomas Joffre
2015 IEEE Electrical Insulation Conference (EIC), 2015
Mechanics of Materials
Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstr... more Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstructural heterogeneities or defects controls the tensile strength. Short-fibre composites are an example of heterogeneous materials, where unwanted fibre agglomerates are likely to initiate tensile failure. In this study, the dimensions and orientation of fibre agglomerates have been analysed from three-dimensional images obtained by X-ray microtomography. The geometry of the specific agglomerate responsible for failure initiation has been identified and correlated with the strength. At the plane of fracture, a defect in the form of a large fibre agglomerate was almost inevitably found. These new experimental findings highlight a problem of some existing strength criteria, which are principally based on a rule of mixture of the strengths of constituent phases, and not on the weakest link. Only a weak correlation was found between stress concentration induced by the critical agglomerate an...
Cellulose, 2014
Polyelectrolytes have been used extensively in the papermaking industry for various purposes. Alt... more Polyelectrolytes have been used extensively in the papermaking industry for various purposes. Although recent studies have shown that polyamines can be efficient dry-strength additives, the mechanism governing the strength enhancement of paper materials following the adsorption of polyamines onto pulp fibres is still not well understood. In this study, the effect of the adsorption of polyallylamine hydrochloride (PAH) onto the surface of unbleached kraft pulp fibres was investigated on both the fibre and the network scale. Isolated fibre crosses were mechanically tested to evaluate the impact of the chemical additive on the interfibre joint strength on the microscopic scale and the effect was compared with that previously observed on the paper sheet scale. X-ray microtomography was used to understand structural changes in the fibrous network following the adsorption of a polyamine such as PAH. Using image analysis methods, it was possible to determine the number of interfibre contacts (or joints) per unit length of fibre as well as the average interfibre joint contact area. The results showed that the median interfibre joint strength increased by 18 % upon adsorption of PAH. This can be achieved both by a larger molecular contact area in the contact zones and by a stronger molecular adhesion. The addition of the polymer also increased the number of efficient interfibre contacts per sheet volume. This combination of effects is the reason why polyamines such as PAH can increase the dry tensile strength of paper materials.
Mechanics of Materials, 2014
Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstr... more Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstructural heterogeneities or defects controls the tensile strength. Short-fibre composites are an example of heterogeneous materials, where unwanted fibre agglomerates are likely to initiate tensile failure. In this study, the dimensions and orientation of fibre agglomerates have been analysed from three-dimensional images obtained by X-ray microtomography. The geometry of the specific agglomerate responsible for failure initiation has been identified and correlated with the strength. At the plane of fracture, a defect in the form of a large fibre agglomerate was almost inevitably found. These new experimental findings highlight a problem of some existing strength criteria, which are principally based on a rule of mixture of the strengths of constituent phases, and not on the weakest link. Only a weak correlation was found between stress concentration induced by the critical agglomerate and the strength. A strong correlation was however found between the stress intensity and the strength, which underlines the importance of the size of largest defects in formulation of improved failure criteria for short-fibre composites. The increased use of three-dimensional imaging will facilitate the quantification of dimensions of the critical flaws.
Journal of Structural Biology, 2014
Compression wood conifer tracheids show different swelling and stiffness properties than those of... more Compression wood conifer tracheids show different swelling and stiffness properties than those of usual normal wood, which has a practical function in the living plant: when a conifer shoot is moved from its vertical position, compression wood is formed in the under part of the shoot. The growth rate of the compression wood is faster than in the upper part resulting in a renewed horizontal growth. The actuating and load-carrying function of the compression wood is addressed, on the basis of its special ultrastructure and shape of the tracheids. As a first step, a quantitative model is developed to predict the difference of moisture-induced expansion and axial stiffness between normal wood and compression wood. The model is based on a state space approach using concentric cylinders with anisotropic helical structure for each cell-wall layer, whose hygroelastic properties are in turn determined by a self-consistent concentric cylinder assemblage of the constituent wood polymers. The predicted properties compare well with experimental results found in the literature. Significant differences in both stiffness and hygroexpansion are found for normal and compression wood, primarily due to the large difference in microfibril angle and lignin content. On the basis of these numerical results, some functional arguments for the reason of high microfibril angle, high lignin content and cylindrical structure of compression wood tracheids are supported.
Composites Science and Technology, 2013
Wood fibres have several highly desirable properties as reinforcement in composite materials for ... more Wood fibres have several highly desirable properties as reinforcement in composite materials for structural applications, e.g. high specific stiffness and strength, renewability and low cost. However, one of the main drawbacks is the swelling of these hydrophilic fibres due to moisture uptake. Since the fibres in the composite are generally embedded in a relatively hydrophobic matrix, the surrounding matrix should restrain the swelling of the fibres. The present study investigates this constraint effect and establishes a micromechanical model to predict the swelling of embedded fibres based on experimentally characterised microstructural parameters and hygroelastic properties of the constituents. The predicted swelling is in concert with direct measurement of various wood-pulp fibre composites by means of three-dimensional X-ray microtomographic images.
Composites Part A: Applied Science and Manufacturing, 2009
The heat resistance and the structural integrity of syntactic foam materials are vital for their ... more The heat resistance and the structural integrity of syntactic foam materials are vital for their high performance. Syntactic foam made of hollow glass microspheres and Diglycidyl Ether of Bisphenol A (DGEBA) based epoxy resin cured with Isophorone Diamine (IPD) hardener was subjected to oxidative thermal stress cycles. The degraded syntactic foam sample was examined using an X-ray Micro Computed Tomography (XlCT) to evaluate its internal damage between each state in a combined effect of cycling and increased temperature. Glass microsphere fracture, void enlargement and resin microcracks were observed as a result of the thermal stress using 3D XlCT images. The reconstructed slice representation showed the microcracks and microsphere damage distribution inside the sample. The damaged glass spheres percentage is shown to increase sharply with the progress of the thermal cycle. There was no change in the local density of the syntactic foam as a result of the thermal cycle. An XlCT system proves to be a successful non-destructive technique for examining syntactic foam for defects and structural damages in the micron scale.
2015 IEEE Electrical Insulation Conference (EIC), 2015
Mechanics of Materials
Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstr... more Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstructural heterogeneities or defects controls the tensile strength. Short-fibre composites are an example of heterogeneous materials, where unwanted fibre agglomerates are likely to initiate tensile failure. In this study, the dimensions and orientation of fibre agglomerates have been analysed from three-dimensional images obtained by X-ray microtomography. The geometry of the specific agglomerate responsible for failure initiation has been identified and correlated with the strength. At the plane of fracture, a defect in the form of a large fibre agglomerate was almost inevitably found. These new experimental findings highlight a problem of some existing strength criteria, which are principally based on a rule of mixture of the strengths of constituent phases, and not on the weakest link. Only a weak correlation was found between stress concentration induced by the critical agglomerate an...
Cellulose, 2014
Polyelectrolytes have been used extensively in the papermaking industry for various purposes. Alt... more Polyelectrolytes have been used extensively in the papermaking industry for various purposes. Although recent studies have shown that polyamines can be efficient dry-strength additives, the mechanism governing the strength enhancement of paper materials following the adsorption of polyamines onto pulp fibres is still not well understood. In this study, the effect of the adsorption of polyallylamine hydrochloride (PAH) onto the surface of unbleached kraft pulp fibres was investigated on both the fibre and the network scale. Isolated fibre crosses were mechanically tested to evaluate the impact of the chemical additive on the interfibre joint strength on the microscopic scale and the effect was compared with that previously observed on the paper sheet scale. X-ray microtomography was used to understand structural changes in the fibrous network following the adsorption of a polyamine such as PAH. Using image analysis methods, it was possible to determine the number of interfibre contacts (or joints) per unit length of fibre as well as the average interfibre joint contact area. The results showed that the median interfibre joint strength increased by 18 % upon adsorption of PAH. This can be achieved both by a larger molecular contact area in the contact zones and by a stronger molecular adhesion. The addition of the polymer also increased the number of efficient interfibre contacts per sheet volume. This combination of effects is the reason why polyamines such as PAH can increase the dry tensile strength of paper materials.
Mechanics of Materials, 2014
Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstr... more Heterogeneous materials tend to fail at the weakest cross-section, where the presence of microstructural heterogeneities or defects controls the tensile strength. Short-fibre composites are an example of heterogeneous materials, where unwanted fibre agglomerates are likely to initiate tensile failure. In this study, the dimensions and orientation of fibre agglomerates have been analysed from three-dimensional images obtained by X-ray microtomography. The geometry of the specific agglomerate responsible for failure initiation has been identified and correlated with the strength. At the plane of fracture, a defect in the form of a large fibre agglomerate was almost inevitably found. These new experimental findings highlight a problem of some existing strength criteria, which are principally based on a rule of mixture of the strengths of constituent phases, and not on the weakest link. Only a weak correlation was found between stress concentration induced by the critical agglomerate and the strength. A strong correlation was however found between the stress intensity and the strength, which underlines the importance of the size of largest defects in formulation of improved failure criteria for short-fibre composites. The increased use of three-dimensional imaging will facilitate the quantification of dimensions of the critical flaws.
Journal of Structural Biology, 2014
Compression wood conifer tracheids show different swelling and stiffness properties than those of... more Compression wood conifer tracheids show different swelling and stiffness properties than those of usual normal wood, which has a practical function in the living plant: when a conifer shoot is moved from its vertical position, compression wood is formed in the under part of the shoot. The growth rate of the compression wood is faster than in the upper part resulting in a renewed horizontal growth. The actuating and load-carrying function of the compression wood is addressed, on the basis of its special ultrastructure and shape of the tracheids. As a first step, a quantitative model is developed to predict the difference of moisture-induced expansion and axial stiffness between normal wood and compression wood. The model is based on a state space approach using concentric cylinders with anisotropic helical structure for each cell-wall layer, whose hygroelastic properties are in turn determined by a self-consistent concentric cylinder assemblage of the constituent wood polymers. The predicted properties compare well with experimental results found in the literature. Significant differences in both stiffness and hygroexpansion are found for normal and compression wood, primarily due to the large difference in microfibril angle and lignin content. On the basis of these numerical results, some functional arguments for the reason of high microfibril angle, high lignin content and cylindrical structure of compression wood tracheids are supported.
Composites Science and Technology, 2013
Wood fibres have several highly desirable properties as reinforcement in composite materials for ... more Wood fibres have several highly desirable properties as reinforcement in composite materials for structural applications, e.g. high specific stiffness and strength, renewability and low cost. However, one of the main drawbacks is the swelling of these hydrophilic fibres due to moisture uptake. Since the fibres in the composite are generally embedded in a relatively hydrophobic matrix, the surrounding matrix should restrain the swelling of the fibres. The present study investigates this constraint effect and establishes a micromechanical model to predict the swelling of embedded fibres based on experimentally characterised microstructural parameters and hygroelastic properties of the constituents. The predicted swelling is in concert with direct measurement of various wood-pulp fibre composites by means of three-dimensional X-ray microtomographic images.
Composites Part A: Applied Science and Manufacturing, 2009
The heat resistance and the structural integrity of syntactic foam materials are vital for their ... more The heat resistance and the structural integrity of syntactic foam materials are vital for their high performance. Syntactic foam made of hollow glass microspheres and Diglycidyl Ether of Bisphenol A (DGEBA) based epoxy resin cured with Isophorone Diamine (IPD) hardener was subjected to oxidative thermal stress cycles. The degraded syntactic foam sample was examined using an X-ray Micro Computed Tomography (XlCT) to evaluate its internal damage between each state in a combined effect of cycling and increased temperature. Glass microsphere fracture, void enlargement and resin microcracks were observed as a result of the thermal stress using 3D XlCT images. The reconstructed slice representation showed the microcracks and microsphere damage distribution inside the sample. The damaged glass spheres percentage is shown to increase sharply with the progress of the thermal cycle. There was no change in the local density of the syntactic foam as a result of the thermal cycle. An XlCT system proves to be a successful non-destructive technique for examining syntactic foam for defects and structural damages in the micron scale.