Thulani Dlamini - Academia.edu (original) (raw)

Thulani Dlamini

Uploads

Papers by Thulani Dlamini

Research paper thumbnail of Changes in PhysicoChemical Properties of Iron-Based Fischer–Tropsch Catalyst Induced by SiO2 Addition

Catalysis Letters, 2002

The effect of adding SiO2 to a precipitated Fe-based Fischer–Tropsch catalyst was investigated. S... more The effect of adding SiO2 to a precipitated Fe-based Fischer–Tropsch catalyst was investigated. Silica was added to the catalyst either during or after precipitation. The iron-based Fischer–Tropsch catalysts were studied using Mössbauer spectroscopy, BET surface area, XRD and SEM characterization methods. Adding SiO2 to the catalyst during precipitation or immediately after precipitation (i.e., precipitated SiO2) results in the formation of

Research paper thumbnail of Fast- and ultra-fast laser pulse induced reactions between carbon dioxide and methane

Journal of Natural Gas Chemistry, 2010

Research paper thumbnail of Synthesis of Fe carbides species by reactive milling

Hyperfine Interactions, 2009

Research paper thumbnail of Application of in situ Mössbauer spectroscopy to investigate the effect of precipitating agents on precipitated iron Fischer–Tropsch catalysts

Research paper thumbnail of Femtosecond laser control of chemical reactions

CSIR 3rd biennial conference: 2010 science real and, relevant, CSIR International Convention Cent... more CSIR 3rd biennial conference: 2010 science real and, relevant, CSIR International Convention Center, Pretoria, South Africa, 30 August-1 September 2010. Femtosecond laser control of chemical reactions is made possible through the use of pulse-shaping techniques coupled to a learning algorithm feedback loop – teaching the laser pulse to control the chemical reaction. This can result in controllable relative fragmentation ratios for unimolecular dissociation reactions – therefore selectively breaking bonds in a molecule. More interestingly, the same techniques can be used to provide control over chemical reactions involving two or more reactant molecules, where these come together, react and produce new reaction products. The reaction product ratios can be controlled in this way, providing a new form of selectivity in addition to the usual variation of temperature, pressure and catalysts in chemical reactions. In this work, low-pressure gas-phase laser-induced chemical reactions were ...

Research paper thumbnail of In-situ Moessbauer Spectroscopy of Supported Iron Fischer-Tropsch Catalysts During Activation

Aip Conference Proceedings, Apr 25, 2005

Research paper thumbnail of Photonics in South Africa

Nature Photonics, 2007

A growing research and development sector is a sign of a healthy economy. South Africa hopes that... more A growing research and development sector is a sign of a healthy economy. South Africa hopes that a focus on photonics technologies will help drive the country's socioeconomic development. Figure 1 philemon mjwara (left), the director general of the dst, during a visit to the research labs of the nlC. thulani dlamini (right), the director of the nlC, is showing him a high-power nd:YlF laser developed at the centre. the dst strongly supports photonics research in south Africa.

Research paper thumbnail of Changes in PhysicoChemical Properties of Iron-Based Fischer–Tropsch Catalyst Induced by SiO2 Addition

Catalysis Letters, 2002

The effect of adding SiO2 to a precipitated Fe-based Fischer–Tropsch catalyst was investigated. S... more The effect of adding SiO2 to a precipitated Fe-based Fischer–Tropsch catalyst was investigated. Silica was added to the catalyst either during or after precipitation. The iron-based Fischer–Tropsch catalysts were studied using Mössbauer spectroscopy, BET surface area, XRD and SEM characterization methods. Adding SiO2 to the catalyst during precipitation or immediately after precipitation (i.e., precipitated SiO2) results in the formation of

Research paper thumbnail of Fast- and ultra-fast laser pulse induced reactions between carbon dioxide and methane

Journal of Natural Gas Chemistry, 2010

Research paper thumbnail of Synthesis of Fe carbides species by reactive milling

Hyperfine Interactions, 2009

Research paper thumbnail of Application of in situ Mössbauer spectroscopy to investigate the effect of precipitating agents on precipitated iron Fischer–Tropsch catalysts

Research paper thumbnail of Femtosecond laser control of chemical reactions

CSIR 3rd biennial conference: 2010 science real and, relevant, CSIR International Convention Cent... more CSIR 3rd biennial conference: 2010 science real and, relevant, CSIR International Convention Center, Pretoria, South Africa, 30 August-1 September 2010. Femtosecond laser control of chemical reactions is made possible through the use of pulse-shaping techniques coupled to a learning algorithm feedback loop – teaching the laser pulse to control the chemical reaction. This can result in controllable relative fragmentation ratios for unimolecular dissociation reactions – therefore selectively breaking bonds in a molecule. More interestingly, the same techniques can be used to provide control over chemical reactions involving two or more reactant molecules, where these come together, react and produce new reaction products. The reaction product ratios can be controlled in this way, providing a new form of selectivity in addition to the usual variation of temperature, pressure and catalysts in chemical reactions. In this work, low-pressure gas-phase laser-induced chemical reactions were ...

Research paper thumbnail of In-situ Moessbauer Spectroscopy of Supported Iron Fischer-Tropsch Catalysts During Activation

Aip Conference Proceedings, Apr 25, 2005

Research paper thumbnail of Photonics in South Africa

Nature Photonics, 2007

A growing research and development sector is a sign of a healthy economy. South Africa hopes that... more A growing research and development sector is a sign of a healthy economy. South Africa hopes that a focus on photonics technologies will help drive the country's socioeconomic development. Figure 1 philemon mjwara (left), the director general of the dst, during a visit to the research labs of the nlC. thulani dlamini (right), the director of the nlC, is showing him a high-power nd:YlF laser developed at the centre. the dst strongly supports photonics research in south Africa.

Log In