Edoardo Torti - Academia.edu (original) (raw)
Papers by Edoardo Torti
Chemical Communications
An N-arylsulfonimide was successfully employed as a new reagent for the photoinduced trifluoromet... more An N-arylsulfonimide was successfully employed as a new reagent for the photoinduced trifluoromethylation of (hetero)aromatics. The reactions took place by UV irradiation, sunlight exposure and under continuous-flow conditions.
Chemistry (Weinheim an der Bergstrasse, Germany), Jan 27, 2017
The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavit... more The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavity is inhibited. This dianionic agent can be released on demand from its stable 1:1 complex in water (log K =6.9 m ) by addition of a more strongly bound anion, such as iodide (log K =7.1 m ), which can also be delivered in situ upon irradiation from a 4-hydroxyphenacyl iodide derivative with spatial and temporal precision. The oxidizing properties of peroxodisulfate ions liberated from the complex recover and can take part in subsequent chemical transformations.
Chemistry - A European Journal, 2016
Chemical Communications
An N-arylsulfonimide was successfully employed as a new reagent for the photoinduced trifluoromet... more An N-arylsulfonimide was successfully employed as a new reagent for the photoinduced trifluoromethylation of (hetero)aromatics. The reactions took place by UV irradiation, sunlight exposure and under continuous-flow conditions.
Chemistry (Weinheim an der Bergstrasse, Germany), Jan 27, 2017
The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavit... more The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavity is inhibited. This dianionic agent can be released on demand from its stable 1:1 complex in water (log K =6.9 m ) by addition of a more strongly bound anion, such as iodide (log K =7.1 m ), which can also be delivered in situ upon irradiation from a 4-hydroxyphenacyl iodide derivative with spatial and temporal precision. The oxidizing properties of peroxodisulfate ions liberated from the complex recover and can take part in subsequent chemical transformations.
Chemistry - A European Journal, 2016