Thanh Thanh Truong - Academia.edu (original) (raw)
Papers by Thanh Thanh Truong
Environment and Pollution, 2014
Electrodeposition of aluminum on metal at low temperatures, with the participation of the ionic l... more Electrodeposition of aluminum on metal at low temperatures, with the participation of the ionic liquid electrolyte will contribute to solving many technical issues in critical industries such as automobiles, aircraft, electronics ... the industry uses aluminum and aluminum coated materials most.Using ionic liquids based on choline chloride and urea to electrodeposition of aluminum is more published in scientific journals in the world. In this article, we present the preliminary results of electrodeposition of aluminum on cathodes as copper, iron and especially glassy carbon. The nature of electrolytes based on choline chloride and urea were analyzed and identified. The solubility of aluminum chloride in this mixture also surveyed. The results showed that only choline chloride mixture / urea with a mole ratio of 1:1 solution is to create transparent and recrystallized at room temperature. The nature of electrolytes based on choline chloride and urea were analyzed and identified. The solubility of aluminum chloride in this mixture also surveyed. The results showed that only choline chloride mixture / urea with a mole ratio of 1:1 solution is to create transparent and recrystallized at room temperature. Solubility of aluminum chloride in this system is 5% by weight. So in the study of aluminum deposited on the cathode, we use only liquid choline chloride / urea / AlCl 3 at the rate of 1 mol / 1 mol + 5% by weight of AlCl 3 . The electroplating are made with temperatures from 90-120 ° C, the time is 2 hours. Distance between two poles is 2 cm, the maximum of surface area 3 cm 2 voltage between the two poles from 1-3 V and amperage stable at 100 -150 mA. Nitrogen environment are set to limit the influence of oxygen and hydrogen. The results of the analysis on the cathode structure of aluminum films by XRD, SEM, XRF, EDS ... showed similarities with the aluminum anode. The purity of the aluminum film obtained depending on the materials used as the cathode. The purity of aluminum on the GC-cathode is 92.42 % atom, on iron is 70.33 % atom and on copper is 82.63 % atom.
Journal of Multinational Financial Management, 2007
If corporate governance works effectively, size and stability of the firm's officer/director grou... more If corporate governance works effectively, size and stability of the firm's officer/director group will be sensitive to firm performance. This should be most evident during periods of unusual firm performance and so we focus on a sample of 9817 firms drawn from 52 countries with 2001 performance measures and officer/director effects in the following 12-month period. Cross-sectional analysis indicates a positive relationship between prior period performance and changes in size and stability of the officer/director group. While the change in size relationship appears to be explained by the USA firms in the sample, the stability relationship is more broadly based. We also find that these results are sensitive to legal system with a firm's officer/director group showing greater sensitivity to past performance in common law countries.
The Quarterly Review of Economics and Finance, 2007
This paper examines the interaction between the largest shareholder and dividend policy in a samp... more This paper examines the interaction between the largest shareholder and dividend policy in a sample of 8,279 listed firms drawn from 37 countries. We find that firms are more likely to pay dividends when profitability is high, debt is low, investment opportunities are limited or when the largest shareholder is not an insider. Further, the magnitude of dividend payout tends to be smaller when the largest shareholder is either an insider or a financial institution. It is also apparent that largest shareholding and dividend payout are related and that, consistent with the extant literature, legal system does matter in dividend policy decisions.
Catalysis Science & Technology, 2014
A highly porous metal-organic framework (IRMOF-8) was synthesized by a solvothermal method, and u... more A highly porous metal-organic framework (IRMOF-8) was synthesized by a solvothermal method, and used as an efficient heterogeneous catalyst for the Friedel-Crafts acylation reaction. The solid catalyst was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), atomic absorption spectrophotometry (AAS), and nitrogen physisorption measurements. High conversions were achieved in the presence of a catalytic amount of the IRMOF-8 (1-5 mol%) without the need for an inert atmosphere. The solid catalyst could be facilely separated from the reaction mixture by simple centrifugation, and could be reused without a significant degradation in catalytic activity. No contribution from homogeneous catalysis of active acid species leaching into the reaction solution was detected.
SSRN Electronic Journal, 2000
Catal. Sci. Technol., 2015
ABSTRACT We have described an efficient method for oxidative cross coupling reactions between act... more ABSTRACT We have described an efficient method for oxidative cross coupling reactions between activated N-H amines and terminal alkynes using heterogeneous Cu2(BDC)2(BPY) as recyclable catalyst (BDC = benzene-1,4-dicarboxylate; BPY = 4,4’-bipyridine). The optimal conditions involved the use of inexpensive NaHCO3 base and oxygen as terminal oxidant in toluene solvent at 80 oC. Reactions proceeds efficiently and high selectivity with only trace amount of diynes as well as good yields were achieved in short reaction time. The Cu2(BDC)2(BPY) exhibited excellent catalytic activity and selectivity as compared to other Cu-MOFs on broad reaction scope. Interestingly, the presence of bipyridine ligand was showed to enhance the catalyst stability. Thus, the Cu2(BDC)2(BPY) could be facilely separated from the reaction mixture by simple centrifugation and could be reused several times with only a slight decrease in catalytic activity.
ChemPlusChem, 2014
ABSTRACT A crystalline porous metal-organic framework [Cu2(EDB)2(BPY)] was synthesized and used a... more ABSTRACT A crystalline porous metal-organic framework [Cu2(EDB)2(BPY)] was synthesized and used as a heterogeneous catalyst for the direct oxidative amidation between N,N-dimethylanilines and anhydrides to form tertiary amides as the principal products. The [Cu2(EDB)2(BPY)] exhibited similar activity as compared to that of [Cu2(BDC)2(BPY)], [Cu2(BDC)2(DABCO)], MOF-143, and other common homogeneous salt catalysts. The optimal reaction conditions employed were [Cu2(EDB)2(BPY)] (10 % mol), TBHP (2 equiv), pyridine (1 equiv) in CH3CN at 80 °C over 2 h. The Cu2(EDB)2(BPY) could be separated from the reaction mixture by filtration, and could be recovered and reused several times without a significant degradation in catalytic activity and selectivity. Furthermore, generality of the optimal conditions was confirmed by employing various N,N-dimethylaniline and anhydride derivatives.
ChemInform, 2011
Base-Mediated Intermolecular sp 2 C-H Bond Arylation via Benzyne Intermediates. -A transition-met... more Base-Mediated Intermolecular sp 2 C-H Bond Arylation via Benzyne Intermediates. -A transition-metal-free method for arylation of heterocycles and arenes by aryl chlorides and fluorides is developed. The reactions proceed via aryne intermediates and are highly regioselective. -(TRUONG, T.; DAUGULIS*, O.; J. Am. Chem. Soc. 133 (2011) 12, 4243-4245, http://dx.doi.org/10.1021/ja200184b ; Dep. Chem. Eng., Univ. Houston, Houston, TX 77204, USA; Eng.) -Bartels
ChemInform, 2015
A method for base-promoted arylation of arenes and heterocycles by aryl halides and aryl triflate... more A method for base-promoted arylation of arenes and heterocycles by aryl halides and aryl triflates is described. Additionally, in situ electrophilic trapping of ArLi intermediates generated in the reaction of benzyne with deprotonated arenes or heterocycles has been developed, providing rapid and easy access to a wide range of highly functionalized polyaryls. Base-promoted arylation methodology complements transition-metal-catalyzed direct arylation and allows access to structures that are not easily accessible via other direct arylation methods. The reactions are highly functional-group tolerant, with alkene, ether, dimethylamino, trifluoromethyl, ester, cyano, halide, hydroxyl, and silyl functionalities compatible with reaction conditions.
The Journal of Physical Chemistry A, 2001
A systematic theoretical study using the density functional theory is performed to provide molecu... more A systematic theoretical study using the density functional theory is performed to provide molecular-level understanding on the desorption of carbon monoxide from surface oxygen complexes that are formed in the gasification and combustion of coal. Particularly, a CO molecule release from carbonyl oxygen complexes in the presence of different oxygen environments was analyzed. Molecular carbonyl models of different sizes in the zigzag, armchair, and tip shapes of the active sites were selected. It was found that the shape of the local active site has a strong effect on the CO desorption energy, and they are correlated with the broaden feature of the CO molecule desorption in the temperature-programmed desorption (TPD) experiments of oxidized carbonaceous material. The calculated desorption activation energy range is in good agreement with experimental data. Molecular size convergence analyses on the carbonyl models suggest that the smallest graphene molecular system for accurate desorption structure on char is a three-ring molecule. The activation energy and normal-mode analyses for selected carbonyl complexes suggest that carbonyl surface oxygen complexes are stable structures and that they can be considered as labile surface oxygen complexes. The CO molecule desorption energy is affected by the influence of different neighboring surface oxygen groups on the carbon surface as well as the aromatic character of the molecular models. The desorption energy analysis suggests that the CO molecule can be adsorbed on clean carbonized surface to form stable structures. The preadsorbed oxygen group decreases the CO adsorption sticking probability on oxidized materials, but it remains an energetically favorable process.
Cheminform, 2010
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was e... more ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Organic Letters, 2012
A method for direct, transition-metal-free ortho-arylation of anilines by aryl chlorides, bromide... more A method for direct, transition-metal-free ortho-arylation of anilines by aryl chlorides, bromides, fluorides, and triflates has been developed. This methodology provides the most direct approach to 2-arylanilines since no protecting or directing groups on nitrogen are required. The arylation is functional-group tolerant, with alkene, ether, trifluoromethyl, dimethylamino, carbonyl, chloro, and cyano functionalities tolerated. Phenylation of enantiopure binaphthyldiamine affords a product with >99% ee.
Organic Letters, 2011
Two sets of conditions have been developed for a base-mediated, transition-metal-free alkynylatio... more Two sets of conditions have been developed for a base-mediated, transition-metal-free alkynylation of aryl chlorides that proceeds via benzyne intermediates. The first set of conditions involves the use of TMPLi base in a pentane/THF mixture at 25 °C. The second set involves use of a metal alkoxide base in dioxane at elevated temperature. Reasonable functional group tolerance has been observed. Fluoro, trifluoromethyl, silyl, cyano, and alcohol functionalities are compatible with the reaction conditions.
Journal of the American Chemical Society, 2013
We have developed a method for direct, copper-catalyzed, auxiliary-assisted fluorination of β-sp(... more We have developed a method for direct, copper-catalyzed, auxiliary-assisted fluorination of β-sp(2) C-H bonds of benzoic acid derivatives and γ-sp(2) C-H bonds of α,α-disubstituted benzylamine derivatives. The reaction employs a CuI catalyst, a AgF fluoride source, and DMF, pyridine, or DMPU solvent at moderately elevated temperatures. Selective mono- or difluorination can be achieved by simply changing reaction conditions. The method shows excellent functional group tolerance and provides a straightforward way for the preparation of ortho-fluorinated benzoic acids.
The Journal of Chemical Physics, 1997
We present a general methodology for calculating free-energy profile of reaction in solution usin... more We present a general methodology for calculating free-energy profile of reaction in solution using quantum mechanical methods coupled with the dielectric continuum solvation approach. Particularly, the generalized conductorlike screening model ͑GCOSMO͒ was employed in this study, though any continuum model with existing free-energy derivatives could also be used. Free-energy profile is defined as the steepest descent path from the transition state to the reactant and product channels on the liquid-phase free-energy surface. Application of this methodology to calculate the free-energy profile of the Menshutkin NH 3 ϩCH 3 Cl reaction in water is discussed. The efficiency of the GCOSMO method allows characterization of stationary points and determination of reaction paths to be carried out at less than 20% additional computational cost compared to gas-phase calculations. Excellent agreement between the present results and previous Monte Carlo simulations using a combined quantum mechanical/molecular mechanics ͑QM/MM͒ potential confirms the accuracy and usefulness of the GCOSMO model.
Environment and Pollution, 2014
Electrodeposition of aluminum on metal at low temperatures, with the participation of the ionic l... more Electrodeposition of aluminum on metal at low temperatures, with the participation of the ionic liquid electrolyte will contribute to solving many technical issues in critical industries such as automobiles, aircraft, electronics ... the industry uses aluminum and aluminum coated materials most.Using ionic liquids based on choline chloride and urea to electrodeposition of aluminum is more published in scientific journals in the world. In this article, we present the preliminary results of electrodeposition of aluminum on cathodes as copper, iron and especially glassy carbon. The nature of electrolytes based on choline chloride and urea were analyzed and identified. The solubility of aluminum chloride in this mixture also surveyed. The results showed that only choline chloride mixture / urea with a mole ratio of 1:1 solution is to create transparent and recrystallized at room temperature. The nature of electrolytes based on choline chloride and urea were analyzed and identified. The solubility of aluminum chloride in this mixture also surveyed. The results showed that only choline chloride mixture / urea with a mole ratio of 1:1 solution is to create transparent and recrystallized at room temperature. Solubility of aluminum chloride in this system is 5% by weight. So in the study of aluminum deposited on the cathode, we use only liquid choline chloride / urea / AlCl 3 at the rate of 1 mol / 1 mol + 5% by weight of AlCl 3 . The electroplating are made with temperatures from 90-120 ° C, the time is 2 hours. Distance between two poles is 2 cm, the maximum of surface area 3 cm 2 voltage between the two poles from 1-3 V and amperage stable at 100 -150 mA. Nitrogen environment are set to limit the influence of oxygen and hydrogen. The results of the analysis on the cathode structure of aluminum films by XRD, SEM, XRF, EDS ... showed similarities with the aluminum anode. The purity of the aluminum film obtained depending on the materials used as the cathode. The purity of aluminum on the GC-cathode is 92.42 % atom, on iron is 70.33 % atom and on copper is 82.63 % atom.
Journal of Multinational Financial Management, 2007
If corporate governance works effectively, size and stability of the firm's officer/director grou... more If corporate governance works effectively, size and stability of the firm's officer/director group will be sensitive to firm performance. This should be most evident during periods of unusual firm performance and so we focus on a sample of 9817 firms drawn from 52 countries with 2001 performance measures and officer/director effects in the following 12-month period. Cross-sectional analysis indicates a positive relationship between prior period performance and changes in size and stability of the officer/director group. While the change in size relationship appears to be explained by the USA firms in the sample, the stability relationship is more broadly based. We also find that these results are sensitive to legal system with a firm's officer/director group showing greater sensitivity to past performance in common law countries.
The Quarterly Review of Economics and Finance, 2007
This paper examines the interaction between the largest shareholder and dividend policy in a samp... more This paper examines the interaction between the largest shareholder and dividend policy in a sample of 8,279 listed firms drawn from 37 countries. We find that firms are more likely to pay dividends when profitability is high, debt is low, investment opportunities are limited or when the largest shareholder is not an insider. Further, the magnitude of dividend payout tends to be smaller when the largest shareholder is either an insider or a financial institution. It is also apparent that largest shareholding and dividend payout are related and that, consistent with the extant literature, legal system does matter in dividend policy decisions.
Catalysis Science & Technology, 2014
A highly porous metal-organic framework (IRMOF-8) was synthesized by a solvothermal method, and u... more A highly porous metal-organic framework (IRMOF-8) was synthesized by a solvothermal method, and used as an efficient heterogeneous catalyst for the Friedel-Crafts acylation reaction. The solid catalyst was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), atomic absorption spectrophotometry (AAS), and nitrogen physisorption measurements. High conversions were achieved in the presence of a catalytic amount of the IRMOF-8 (1-5 mol%) without the need for an inert atmosphere. The solid catalyst could be facilely separated from the reaction mixture by simple centrifugation, and could be reused without a significant degradation in catalytic activity. No contribution from homogeneous catalysis of active acid species leaching into the reaction solution was detected.
SSRN Electronic Journal, 2000
Catal. Sci. Technol., 2015
ABSTRACT We have described an efficient method for oxidative cross coupling reactions between act... more ABSTRACT We have described an efficient method for oxidative cross coupling reactions between activated N-H amines and terminal alkynes using heterogeneous Cu2(BDC)2(BPY) as recyclable catalyst (BDC = benzene-1,4-dicarboxylate; BPY = 4,4’-bipyridine). The optimal conditions involved the use of inexpensive NaHCO3 base and oxygen as terminal oxidant in toluene solvent at 80 oC. Reactions proceeds efficiently and high selectivity with only trace amount of diynes as well as good yields were achieved in short reaction time. The Cu2(BDC)2(BPY) exhibited excellent catalytic activity and selectivity as compared to other Cu-MOFs on broad reaction scope. Interestingly, the presence of bipyridine ligand was showed to enhance the catalyst stability. Thus, the Cu2(BDC)2(BPY) could be facilely separated from the reaction mixture by simple centrifugation and could be reused several times with only a slight decrease in catalytic activity.
ChemPlusChem, 2014
ABSTRACT A crystalline porous metal-organic framework [Cu2(EDB)2(BPY)] was synthesized and used a... more ABSTRACT A crystalline porous metal-organic framework [Cu2(EDB)2(BPY)] was synthesized and used as a heterogeneous catalyst for the direct oxidative amidation between N,N-dimethylanilines and anhydrides to form tertiary amides as the principal products. The [Cu2(EDB)2(BPY)] exhibited similar activity as compared to that of [Cu2(BDC)2(BPY)], [Cu2(BDC)2(DABCO)], MOF-143, and other common homogeneous salt catalysts. The optimal reaction conditions employed were [Cu2(EDB)2(BPY)] (10 % mol), TBHP (2 equiv), pyridine (1 equiv) in CH3CN at 80 °C over 2 h. The Cu2(EDB)2(BPY) could be separated from the reaction mixture by filtration, and could be recovered and reused several times without a significant degradation in catalytic activity and selectivity. Furthermore, generality of the optimal conditions was confirmed by employing various N,N-dimethylaniline and anhydride derivatives.
ChemInform, 2011
Base-Mediated Intermolecular sp 2 C-H Bond Arylation via Benzyne Intermediates. -A transition-met... more Base-Mediated Intermolecular sp 2 C-H Bond Arylation via Benzyne Intermediates. -A transition-metal-free method for arylation of heterocycles and arenes by aryl chlorides and fluorides is developed. The reactions proceed via aryne intermediates and are highly regioselective. -(TRUONG, T.; DAUGULIS*, O.; J. Am. Chem. Soc. 133 (2011) 12, 4243-4245, http://dx.doi.org/10.1021/ja200184b ; Dep. Chem. Eng., Univ. Houston, Houston, TX 77204, USA; Eng.) -Bartels
ChemInform, 2015
A method for base-promoted arylation of arenes and heterocycles by aryl halides and aryl triflate... more A method for base-promoted arylation of arenes and heterocycles by aryl halides and aryl triflates is described. Additionally, in situ electrophilic trapping of ArLi intermediates generated in the reaction of benzyne with deprotonated arenes or heterocycles has been developed, providing rapid and easy access to a wide range of highly functionalized polyaryls. Base-promoted arylation methodology complements transition-metal-catalyzed direct arylation and allows access to structures that are not easily accessible via other direct arylation methods. The reactions are highly functional-group tolerant, with alkene, ether, dimethylamino, trifluoromethyl, ester, cyano, halide, hydroxyl, and silyl functionalities compatible with reaction conditions.
The Journal of Physical Chemistry A, 2001
A systematic theoretical study using the density functional theory is performed to provide molecu... more A systematic theoretical study using the density functional theory is performed to provide molecular-level understanding on the desorption of carbon monoxide from surface oxygen complexes that are formed in the gasification and combustion of coal. Particularly, a CO molecule release from carbonyl oxygen complexes in the presence of different oxygen environments was analyzed. Molecular carbonyl models of different sizes in the zigzag, armchair, and tip shapes of the active sites were selected. It was found that the shape of the local active site has a strong effect on the CO desorption energy, and they are correlated with the broaden feature of the CO molecule desorption in the temperature-programmed desorption (TPD) experiments of oxidized carbonaceous material. The calculated desorption activation energy range is in good agreement with experimental data. Molecular size convergence analyses on the carbonyl models suggest that the smallest graphene molecular system for accurate desorption structure on char is a three-ring molecule. The activation energy and normal-mode analyses for selected carbonyl complexes suggest that carbonyl surface oxygen complexes are stable structures and that they can be considered as labile surface oxygen complexes. The CO molecule desorption energy is affected by the influence of different neighboring surface oxygen groups on the carbon surface as well as the aromatic character of the molecular models. The desorption energy analysis suggests that the CO molecule can be adsorbed on clean carbonized surface to form stable structures. The preadsorbed oxygen group decreases the CO adsorption sticking probability on oxidized materials, but it remains an energetically favorable process.
Cheminform, 2010
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was e... more ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Organic Letters, 2012
A method for direct, transition-metal-free ortho-arylation of anilines by aryl chlorides, bromide... more A method for direct, transition-metal-free ortho-arylation of anilines by aryl chlorides, bromides, fluorides, and triflates has been developed. This methodology provides the most direct approach to 2-arylanilines since no protecting or directing groups on nitrogen are required. The arylation is functional-group tolerant, with alkene, ether, trifluoromethyl, dimethylamino, carbonyl, chloro, and cyano functionalities tolerated. Phenylation of enantiopure binaphthyldiamine affords a product with >99% ee.
Organic Letters, 2011
Two sets of conditions have been developed for a base-mediated, transition-metal-free alkynylatio... more Two sets of conditions have been developed for a base-mediated, transition-metal-free alkynylation of aryl chlorides that proceeds via benzyne intermediates. The first set of conditions involves the use of TMPLi base in a pentane/THF mixture at 25 °C. The second set involves use of a metal alkoxide base in dioxane at elevated temperature. Reasonable functional group tolerance has been observed. Fluoro, trifluoromethyl, silyl, cyano, and alcohol functionalities are compatible with the reaction conditions.
Journal of the American Chemical Society, 2013
We have developed a method for direct, copper-catalyzed, auxiliary-assisted fluorination of β-sp(... more We have developed a method for direct, copper-catalyzed, auxiliary-assisted fluorination of β-sp(2) C-H bonds of benzoic acid derivatives and γ-sp(2) C-H bonds of α,α-disubstituted benzylamine derivatives. The reaction employs a CuI catalyst, a AgF fluoride source, and DMF, pyridine, or DMPU solvent at moderately elevated temperatures. Selective mono- or difluorination can be achieved by simply changing reaction conditions. The method shows excellent functional group tolerance and provides a straightforward way for the preparation of ortho-fluorinated benzoic acids.
The Journal of Chemical Physics, 1997
We present a general methodology for calculating free-energy profile of reaction in solution usin... more We present a general methodology for calculating free-energy profile of reaction in solution using quantum mechanical methods coupled with the dielectric continuum solvation approach. Particularly, the generalized conductorlike screening model ͑GCOSMO͒ was employed in this study, though any continuum model with existing free-energy derivatives could also be used. Free-energy profile is defined as the steepest descent path from the transition state to the reactant and product channels on the liquid-phase free-energy surface. Application of this methodology to calculate the free-energy profile of the Menshutkin NH 3 ϩCH 3 Cl reaction in water is discussed. The efficiency of the GCOSMO method allows characterization of stationary points and determination of reaction paths to be carried out at less than 20% additional computational cost compared to gas-phase calculations. Excellent agreement between the present results and previous Monte Carlo simulations using a combined quantum mechanical/molecular mechanics ͑QM/MM͒ potential confirms the accuracy and usefulness of the GCOSMO model.