Victor Dotsenko - Academia.edu (original) (raw)
Papers by Victor Dotsenko
Keywords: cyanoselenoacetamide, N-methylmorpholinium 1,4,5,6,7,8-hexahydroquinoline-2-selenolates... more Keywords: cyanoselenoacetamide, N-methylmorpholinium 1,4,5,6,7,8-hexahydroquinoline-2-selenolates, multicomponent cyclocondensation, Hantzsch synthesis.
![Research paper thumbnail of Synthesis of [1,2]dithiolo[3,4-b]pyridines via the reaction of dithiomalondianilide with arylmethylidenemalononitriles](https://attachments.academia-assets.com/45423213/thumbnails/1.jpg)
](Chemistry of Heterocyclic Compounds, 2015
![Research paper thumbnail of Multicomponent One-Pot Synthesis of Pyrido[3′,2′:4,5]thieno[3,2-b]pyridines as a Novel Approach to Condensed Pyridines](https://attachments.academia-assets.com/45423204/thumbnails/1.jpg)
](ChemInform, 2004
Multicomponent one-pot reactions of aromatic aldehydes, cyanothioacetamide, ethyl benzoylacetate,... more Multicomponent one-pot reactions of aromatic aldehydes, cyanothioacetamide, ethyl benzoylacetate, acetone and malononitrile in the presence of N-methylmorpholine or similar reactions of pyridinethiones or -thiolates with malononitrile and acetone afford the title compounds, which were unknown before.
![Research paper thumbnail of ChemInform Abstract: Azo-Coupling of Pyrazole-3(5)-diazonium Chlorides with Cyanothioacetamide: A Convenient Synthesis of Pyrazolo[5,1-c][1,2,4]triazine-3-carbothioamides](https://attachments.academia-assets.com/45423209/thumbnails/1.jpg)
](ChemInform, 2014
Cyanothioacetamide reacts with pyrazole-3(5)-diazonium chlorides to afford pyrazolo[5,1-c][1,2,4]... more Cyanothioacetamide reacts with pyrazole-3(5)-diazonium chlorides to afford pyrazolo[5,1-c][1,2,4]triazine-3-carbothioamides 5. The latter can be oxidized with H 2 O 2 to give either pyrazolo[5,1-c][1,2,4]triazine-3-carboxamides or 1,2,4-thiadiazole derivatives, depending on the reaction conditions. The
Russian Journal of Organic Chemistry, 2014
A number of 3,9-substituted 6-oxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-7-carbonitri... more A number of 3,9-substituted 6-oxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-7-carbonitriles were synthesized by reaction of 5-R-6-amino-2-oxo-1,2-dihydropyridine-3-carbonitriles with primary amines and excess formaldehyde.
[
Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dr... more Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dry ether afforded (Z ) 1 amino 3 aryl 2 (thiazol 2 yl)prop 1 ene derivatives in 15 to 40% yields. The structure of (Z ) 1 amino 3 (2 chlorophenyl) 2 [4 (4 methylphenyl)thiazol 2 yl]prop 1 ene was confirmed by X ray diffraction analysis.
ChemInform, 2014
Reaction of activated methylene compounds with 2-aminomethylene-1,3-dicarbonyl compounds as 1,3-b... more Reaction of activated methylene compounds with 2-aminomethylene-1,3-dicarbonyl compounds as 1,3-bis-electrophilic 3C-synthons is a very popular method for the synthesis of various azines (for reviews, see [1]). Amongst the most readily available enaminodicarbonyl substrates of this type are the 2-anilinomethylene derivatives of 1,3-dicarbonyl compounds which are readily synthesized through a three-component condensation of an activated methylene compound, triethylorthoformate, and aniline .
ChemInform, 2013
The recent published data on the chemistry of cyanoselenoacetamide, a prospective reagent for the... more The recent published data on the chemistry of cyanoselenoacetamide, a prospective reagent for the synthesis of various nitrogen-and selenium-containing heterocycles, are classified and summarized.
![Research paper thumbnail of ChemInform Abstract: New Approaches to Pyrimido[4,3-b][1,3,5]selenadiazines](https://attachments.academia-assets.com/45423208/thumbnails/1.jpg)
](ChemInform, 2013
The Mannich reactions of (arylmethylidene)(cyano)selenoacetamides with primary amines and formald... more The Mannich reactions of (arylmethylidene)(cyano)selenoacetamides with primary amines and formaldehyde gave 3,7 disubstituted 8 R 3,4,7,8 tetrahydro 2H,6H pyrimido[4,3 b] [1,3,5]selenadiazine 9 carbonitriles. Alternatively, these compounds can be obtained by reac tions of 4 R 2,6 diamino 4H selenopyran 3,5 dicarbonitriles with primary amines and form aldehyde or by multicomponent condensation of an appropriate aldehyde, cyanoselenoacet amide, a primary amine, and formaldehyde.
Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry, 2013
Russian Chemical Bulletin, 2005
Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dr... more Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dry ether afforded (Z ) 1 amino 3 aryl 2 (thiazol 2 yl)prop 1 ene derivatives in 15 to 40% yields. The structure of (Z ) 1 amino 3 (2 chlorophenyl) 2 [4 (4 methylphenyl)thiazol 2 yl]prop 1 ene was confirmed by X ray diffraction analysis.
Russian Chemical Bulletin, 2005
![Research paper thumbnail of Aminomethylation of N-methylmorpholinium 6-amino-4-aryl-3,5-dicyano-1,4-dihydropyridine-2-selenolates as an approach to the preparation of 3,5,7,11-tetraazatricyclo[7.3.1.02,7]tridec-2-ene-8-selenone derivatives](https://attachments.academia-assets.com/45423207/thumbnails/1.jpg)
](Russian Chemical Bulletin, 2013
Aminomethylation of N methylmorpholinium 6 amino 4 aryl 3,5 dicyano 1,4 dihydropyridine 2 selenol... more Aminomethylation of N methylmorpholinium 6 amino 4 aryl 3,5 dicyano 1,4 dihydropyridine 2 selenolates as an approach to the preparation of 3,5,7,11 tetraazatricyclo[7.3.1.0 2,7 ]tridec 2 ene 8 selenone derivatives A reaction of N methylmorpholinium 6 amino 4 aryl 3,5 dicyano 1,4 dihydropyridine 2 selenolates with primary amines and excess of formaldehyde leads to 3,5,7,11 tetra azatricyclo[7.3.1.0 2,7 ]tridec 2 ene 8 selenone derivatives. The same compounds were obtained by a multicomponent cascade cyclocondensation of benzaldehyde, cyanoselenoacetamide, primary amine, and excess of formaldehyde.
Russian Chemical Bulletin, 2007
Oxidation of (E) 3 (4 chlorophenyl) 2 cyanoprop 2 enethioamide with hydrogen per oxide or the H 2... more Oxidation of (E) 3 (4 chlorophenyl) 2 cyanoprop 2 enethioamide with hydrogen per oxide or the H 2 O 2 -KOH system gave 3 (4 chlorophenyl)oxirane 2,2 dicarboxamide. This compound was also obtained by an independent "one pot" synthesis from p chlorobenzaldehyde and 2 cyanoacetamide through in situ oxidation of their adduct (E) 3 (4 chlorophenyl) 2 cyanoprop 2 eneamide with the H 2 O 2 -KOH system. The structure of 3 (4 chlorophe nyl)oxirane 2,2 dicarboxamide was confirmed by X ray diffraction and spectroscopic data.
Keywords: cyanoselenoacetamide, N-methylmorpholinium 1,4,5,6,7,8-hexahydroquinoline-2-selenolates... more Keywords: cyanoselenoacetamide, N-methylmorpholinium 1,4,5,6,7,8-hexahydroquinoline-2-selenolates, multicomponent cyclocondensation, Hantzsch synthesis.
Chemistry of Heterocyclic Compounds, 2015
ChemInform, 2004
Multicomponent one-pot reactions of aromatic aldehydes, cyanothioacetamide, ethyl benzoylacetate,... more Multicomponent one-pot reactions of aromatic aldehydes, cyanothioacetamide, ethyl benzoylacetate, acetone and malononitrile in the presence of N-methylmorpholine or similar reactions of pyridinethiones or -thiolates with malononitrile and acetone afford the title compounds, which were unknown before.
ChemInform, 2014
Cyanothioacetamide reacts with pyrazole-3(5)-diazonium chlorides to afford pyrazolo[5,1-c][1,2,4]... more Cyanothioacetamide reacts with pyrazole-3(5)-diazonium chlorides to afford pyrazolo[5,1-c][1,2,4]triazine-3-carbothioamides 5. The latter can be oxidized with H 2 O 2 to give either pyrazolo[5,1-c][1,2,4]triazine-3-carboxamides or 1,2,4-thiadiazole derivatives, depending on the reaction conditions. The
Russian Journal of Organic Chemistry, 2014
A number of 3,9-substituted 6-oxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-7-carbonitri... more A number of 3,9-substituted 6-oxo-1,3,4,6-tetrahydro-2H-pyrido[1,2-a][1,3,5]triazine-7-carbonitriles were synthesized by reaction of 5-R-6-amino-2-oxo-1,2-dihydropyridine-3-carbonitriles with primary amines and excess formaldehyde.
[
Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dr... more Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dry ether afforded (Z ) 1 amino 3 aryl 2 (thiazol 2 yl)prop 1 ene derivatives in 15 to 40% yields. The structure of (Z ) 1 amino 3 (2 chlorophenyl) 2 [4 (4 methylphenyl)thiazol 2 yl]prop 1 ene was confirmed by X ray diffraction analysis.
ChemInform, 2014
Reaction of activated methylene compounds with 2-aminomethylene-1,3-dicarbonyl compounds as 1,3-b... more Reaction of activated methylene compounds with 2-aminomethylene-1,3-dicarbonyl compounds as 1,3-bis-electrophilic 3C-synthons is a very popular method for the synthesis of various azines (for reviews, see [1]). Amongst the most readily available enaminodicarbonyl substrates of this type are the 2-anilinomethylene derivatives of 1,3-dicarbonyl compounds which are readily synthesized through a three-component condensation of an activated methylene compound, triethylorthoformate, and aniline .
ChemInform, 2013
The recent published data on the chemistry of cyanoselenoacetamide, a prospective reagent for the... more The recent published data on the chemistry of cyanoselenoacetamide, a prospective reagent for the synthesis of various nitrogen-and selenium-containing heterocycles, are classified and summarized.
ChemInform, 2013
The Mannich reactions of (arylmethylidene)(cyano)selenoacetamides with primary amines and formald... more The Mannich reactions of (arylmethylidene)(cyano)selenoacetamides with primary amines and formaldehyde gave 3,7 disubstituted 8 R 3,4,7,8 tetrahydro 2H,6H pyrimido[4,3 b] [1,3,5]selenadiazine 9 carbonitriles. Alternatively, these compounds can be obtained by reac tions of 4 R 2,6 diamino 4H selenopyran 3,5 dicarbonitriles with primary amines and form aldehyde or by multicomponent condensation of an appropriate aldehyde, cyanoselenoacet amide, a primary amine, and formaldehyde.
Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry, 2013
Russian Chemical Bulletin, 2005
Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dr... more Reduction of (E) 3 aryl 2 (4 arylthiazol 2 yl)acrylonitriles with lithium aluminum hy dride in dry ether afforded (Z ) 1 amino 3 aryl 2 (thiazol 2 yl)prop 1 ene derivatives in 15 to 40% yields. The structure of (Z ) 1 amino 3 (2 chlorophenyl) 2 [4 (4 methylphenyl)thiazol 2 yl]prop 1 ene was confirmed by X ray diffraction analysis.
Russian Chemical Bulletin, 2005
Russian Chemical Bulletin, 2013
Aminomethylation of N methylmorpholinium 6 amino 4 aryl 3,5 dicyano 1,4 dihydropyridine 2 selenol... more Aminomethylation of N methylmorpholinium 6 amino 4 aryl 3,5 dicyano 1,4 dihydropyridine 2 selenolates as an approach to the preparation of 3,5,7,11 tetraazatricyclo[7.3.1.0 2,7 ]tridec 2 ene 8 selenone derivatives A reaction of N methylmorpholinium 6 amino 4 aryl 3,5 dicyano 1,4 dihydropyridine 2 selenolates with primary amines and excess of formaldehyde leads to 3,5,7,11 tetra azatricyclo[7.3.1.0 2,7 ]tridec 2 ene 8 selenone derivatives. The same compounds were obtained by a multicomponent cascade cyclocondensation of benzaldehyde, cyanoselenoacetamide, primary amine, and excess of formaldehyde.
Russian Chemical Bulletin, 2007
Oxidation of (E) 3 (4 chlorophenyl) 2 cyanoprop 2 enethioamide with hydrogen per oxide or the H 2... more Oxidation of (E) 3 (4 chlorophenyl) 2 cyanoprop 2 enethioamide with hydrogen per oxide or the H 2 O 2 -KOH system gave 3 (4 chlorophenyl)oxirane 2,2 dicarboxamide. This compound was also obtained by an independent "one pot" synthesis from p chlorobenzaldehyde and 2 cyanoacetamide through in situ oxidation of their adduct (E) 3 (4 chlorophenyl) 2 cyanoprop 2 eneamide with the H 2 O 2 -KOH system. The structure of 3 (4 chlorophe nyl)oxirane 2,2 dicarboxamide was confirmed by X ray diffraction and spectroscopic data.