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Papers by Vincent Miralles

Research paper thumbnail of An all-inclusive laboratory workflow for the development of surfactant/polymer formulations for EOR in harsh carbonates

Journal of Petroleum Science and Engineering

Research paper thumbnail of Investigating the role of a poorly soluble surfactant in a thermally driven 2D microfoam

Soft Matter, 2016

Foam drainage dynamics is known to be strongly affected by the nature of the surfactants stabilis... more Foam drainage dynamics is known to be strongly affected by the nature of the surfactants stabilising the liquid/gas interface. In the present work, we consider a 2D microfoam stabilized by both soluble (sodium dodecylsulfate) and poorly soluble (dodecanol) surfactants. The drainage dynamics is driven by a thermocapillary Marangoni stress at the liquid/gas interface [V. Miralles et al., Phys. Rev. Lett., 2014, 112, 238302] and the presence of dodecanol at the interface induces interface stress acting against the applied thermocapillary stress, which slows down the drainage dynamics. We define a damping parameter that we measure as a function of the geometrical characteristics of the foam. We compare it with predictions based on the interface rheological properties of the solution.

Research paper thumbnail of A versatile technology for droplet-based microfluidics: thermomechanical actuation

Lab on a chip, Jan 7, 2015

We report on a versatile technique for microfluidic droplet manipulation that proves effective at... more We report on a versatile technique for microfluidic droplet manipulation that proves effective at every step: from droplet generation to propulsion to sorting, rearrangement or break-up. Non-wetting droplets are thermomechanically actuated in a microfluidic chip using local heating resistors. Controlled temperature variation induces local dilation of the PDMS wall above the resistor, which drives the droplet away from the hot (i.e. constricted) region (B. Selva, I. Cantat and M.-C. Jullien, Phys. Fluids, 2011, 23, 052002). Adapted placing and actuation of such resistors thus allow us to push forward, stop, store and release, or even break up droplets, at the price of low electric power consumption (<150 mW). We believe this technically accessible method to provide a useful tool for droplet microfluidics.

Research paper thumbnail of Foam drainage control using thermocapillary stress in a two-dimensional microchamber

Physical review letters, Jan 13, 2014

We investigate the drainage of a 2D microfoam in a vertical Hele-Shaw cell, and show that the Mar... more We investigate the drainage of a 2D microfoam in a vertical Hele-Shaw cell, and show that the Marangoni stress at the air-water interface generated by a constant temperature gradient applied in situ can be tuned to control the drainage. The temperature gradient is applied in such a way that thermocapillarity and gravity have an antagonistic effect. We characterize the drainage over time by measuring the liquid volume fraction in the cell and find that thermocapillarity can overcome the effect of gravity, effectively draining the foam towards the top of the cell, or exactly compensate it, maintaining the liquid fraction at its initial value over at least 60 s. We quantify these results by solving the mass balance in the cell, and provide insight into the interplay between gravity, thermocapillarity, and capillary pressure governing the drainage dynamics.

Research paper thumbnail of A Review of Heating and Temperature Control in Microfluidic Systems: Techniques and Applications

Research paper thumbnail of Bubbles and foams in microfluidics

Research paper thumbnail of Energy versus Information Based Estimations of Dissipation Using a Pair of Magnetic Colloidal Particles

Physical Review Letters, 2014

Using the framework of stochastic thermodynamics, we present an experimental study of a doublet o... more Using the framework of stochastic thermodynamics, we present an experimental study of a doublet of magnetic colloidal particles that is manipulated by a time-dependent magnetic field. Because of hydrodynamic interactions, each bead experiences a state-dependent friction, which we characterize using a hydrodynamic model. In this work, we compare two estimates of the dissipation in this system: the first one is energy based since it relies on the measured interaction potential, while the second one is information based since it uses only the information content of the trajectories. While the latter only offers a lower bound of the former, we find it to be simple to implement and of general applicability to more complex systems.

Research paper thumbnail of Thermocapillary actuation by optimized resistor pattern: bubbles and droplets displacing, switching and trapping

Research paper thumbnail of Microfluidic preparation and self diffusion PFG-NMR analysis of monodisperse water-in-oil-in-water double emulsions

Journal of Colloid and Interface Science, 2013

Research paper thumbnail of An all-inclusive laboratory workflow for the development of surfactant/polymer formulations for EOR in harsh carbonates

Journal of Petroleum Science and Engineering

Research paper thumbnail of Investigating the role of a poorly soluble surfactant in a thermally driven 2D microfoam

Soft Matter, 2016

Foam drainage dynamics is known to be strongly affected by the nature of the surfactants stabilis... more Foam drainage dynamics is known to be strongly affected by the nature of the surfactants stabilising the liquid/gas interface. In the present work, we consider a 2D microfoam stabilized by both soluble (sodium dodecylsulfate) and poorly soluble (dodecanol) surfactants. The drainage dynamics is driven by a thermocapillary Marangoni stress at the liquid/gas interface [V. Miralles et al., Phys. Rev. Lett., 2014, 112, 238302] and the presence of dodecanol at the interface induces interface stress acting against the applied thermocapillary stress, which slows down the drainage dynamics. We define a damping parameter that we measure as a function of the geometrical characteristics of the foam. We compare it with predictions based on the interface rheological properties of the solution.

Research paper thumbnail of A versatile technology for droplet-based microfluidics: thermomechanical actuation

Lab on a chip, Jan 7, 2015

We report on a versatile technique for microfluidic droplet manipulation that proves effective at... more We report on a versatile technique for microfluidic droplet manipulation that proves effective at every step: from droplet generation to propulsion to sorting, rearrangement or break-up. Non-wetting droplets are thermomechanically actuated in a microfluidic chip using local heating resistors. Controlled temperature variation induces local dilation of the PDMS wall above the resistor, which drives the droplet away from the hot (i.e. constricted) region (B. Selva, I. Cantat and M.-C. Jullien, Phys. Fluids, 2011, 23, 052002). Adapted placing and actuation of such resistors thus allow us to push forward, stop, store and release, or even break up droplets, at the price of low electric power consumption (<150 mW). We believe this technically accessible method to provide a useful tool for droplet microfluidics.

Research paper thumbnail of Foam drainage control using thermocapillary stress in a two-dimensional microchamber

Physical review letters, Jan 13, 2014

We investigate the drainage of a 2D microfoam in a vertical Hele-Shaw cell, and show that the Mar... more We investigate the drainage of a 2D microfoam in a vertical Hele-Shaw cell, and show that the Marangoni stress at the air-water interface generated by a constant temperature gradient applied in situ can be tuned to control the drainage. The temperature gradient is applied in such a way that thermocapillarity and gravity have an antagonistic effect. We characterize the drainage over time by measuring the liquid volume fraction in the cell and find that thermocapillarity can overcome the effect of gravity, effectively draining the foam towards the top of the cell, or exactly compensate it, maintaining the liquid fraction at its initial value over at least 60 s. We quantify these results by solving the mass balance in the cell, and provide insight into the interplay between gravity, thermocapillarity, and capillary pressure governing the drainage dynamics.

Research paper thumbnail of A Review of Heating and Temperature Control in Microfluidic Systems: Techniques and Applications

Research paper thumbnail of Bubbles and foams in microfluidics

Research paper thumbnail of Energy versus Information Based Estimations of Dissipation Using a Pair of Magnetic Colloidal Particles

Physical Review Letters, 2014

Using the framework of stochastic thermodynamics, we present an experimental study of a doublet o... more Using the framework of stochastic thermodynamics, we present an experimental study of a doublet of magnetic colloidal particles that is manipulated by a time-dependent magnetic field. Because of hydrodynamic interactions, each bead experiences a state-dependent friction, which we characterize using a hydrodynamic model. In this work, we compare two estimates of the dissipation in this system: the first one is energy based since it relies on the measured interaction potential, while the second one is information based since it uses only the information content of the trajectories. While the latter only offers a lower bound of the former, we find it to be simple to implement and of general applicability to more complex systems.

Research paper thumbnail of Thermocapillary actuation by optimized resistor pattern: bubbles and droplets displacing, switching and trapping

Research paper thumbnail of Microfluidic preparation and self diffusion PFG-NMR analysis of monodisperse water-in-oil-in-water double emulsions

Journal of Colloid and Interface Science, 2013