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Desalination, 2011
In this manuscript, we are using sulfonated poly (ethersulfone) (SPES) based cation-exchange memb... more In this manuscript, we are using sulfonated poly (ethersulfone) (SPES) based cation-exchange membrane (CEM) and polyvinyl alcohol-4-vinylpyridine (4-VP) based cross-linked based anion-exchange membrane (AEM) for water desalination by electrodialysis (ED). These membranes were characterized for their electrochemical and physicochemical properties such as membrane conductivity, counter-ion transport number, ion-exchange capacity and water content. Prepared ion-exchange membranes (IEMs) showed good stabilities under severe conditions such as high temperature and strong oxidizing conditions. ED experiments in recirculation mode of operation were performed for water desalination. Energy consumption and current efficiency values confirmed suitability of these IEMs for desalination of water by ED.
Flameholding in supersonic flow depends on local conditions in the recirculation region, and on m... more Flameholding in supersonic flow depends on local conditions in the recirculation region, and on mass transfer into and out of this region. Large gradients in local gas composition and temperature exist in the recirculation region. Hence, stability parameter correlations developed for premixed flames cannot be used to determine blowout stability limits for non-premixed flames encountered in practical devices. In the present study, mixture samples were extracted at different locations in the recirculation region and the shear layer formed behind a rearward-facing step in supersonic flow, and analyzed by mass spectrometry to determine the species concentration distribution in the region. The point-wise mass spectrometer measurements were complemented by acetone planar laser-induced fluorescence (PLIF) measurements to get a planar distribution of fuel mole fraction in the recirculation region. Non-reacting flow tests and combustion experiments were performed by varying various fuel related parameters such as injection location, injection pressure and fuel type. Fuel injection upstream of the step was not effective in supplying enough fuel to the recirculation region and did not sustain the flame in combustion experiments. Fuel injection at the step base was effective in sustaining the flame. For base injection, the local fuel mole fraction in the recirculation region determined from experiments was an order of magnitude higher than the global fuel mole fraction based on total moles of air flowing through the test section and total fuel injected in the test section. This suggests substantial difference in flame stability curve for non-premixed conditions in the scramjet engine compared to premixed flow. For base injection, fuel remained in the recirculation region even at higher injection pressure. Due to slower diffusion rate, the heavier fuel had higher local mole fraction in the recirculation region compared to lighter fuel for a unit global fuel mole fraction injected in the test section. Hence fuel molecular weight will affect the non-premixed flame stability limits in scramjet engine; the heavier fuel will have better fuel-lean and worse fuel-rich stability limit compared to lighter fuel. This is in addition to the fact that a lighter fuel such as hydrogen has a much wider flame stability limit than a heavier fuel such as propane. The data obtained in the study can help develop a stability parameter for non-premixed flames and validate computational models.
Desalination, 2011
In this manuscript, we are using sulfonated poly (ethersulfone) (SPES) based cation-exchange memb... more In this manuscript, we are using sulfonated poly (ethersulfone) (SPES) based cation-exchange membrane (CEM) and polyvinyl alcohol-4-vinylpyridine (4-VP) based cross-linked based anion-exchange membrane (AEM) for water desalination by electrodialysis (ED). These membranes were characterized for their electrochemical and physicochemical properties such as membrane conductivity, counter-ion transport number, ion-exchange capacity and water content. Prepared ion-exchange membranes (IEMs) showed good stabilities under severe conditions such as high temperature and strong oxidizing conditions. ED experiments in recirculation mode of operation were performed for water desalination. Energy consumption and current efficiency values confirmed suitability of these IEMs for desalination of water by ED.
Flameholding in supersonic flow depends on local conditions in the recirculation region, and on m... more Flameholding in supersonic flow depends on local conditions in the recirculation region, and on mass transfer into and out of this region. Large gradients in local gas composition and temperature exist in the recirculation region. Hence, stability parameter correlations developed for premixed flames cannot be used to determine blowout stability limits for non-premixed flames encountered in practical devices. In the present study, mixture samples were extracted at different locations in the recirculation region and the shear layer formed behind a rearward-facing step in supersonic flow, and analyzed by mass spectrometry to determine the species concentration distribution in the region. The point-wise mass spectrometer measurements were complemented by acetone planar laser-induced fluorescence (PLIF) measurements to get a planar distribution of fuel mole fraction in the recirculation region. Non-reacting flow tests and combustion experiments were performed by varying various fuel related parameters such as injection location, injection pressure and fuel type. Fuel injection upstream of the step was not effective in supplying enough fuel to the recirculation region and did not sustain the flame in combustion experiments. Fuel injection at the step base was effective in sustaining the flame. For base injection, the local fuel mole fraction in the recirculation region determined from experiments was an order of magnitude higher than the global fuel mole fraction based on total moles of air flowing through the test section and total fuel injected in the test section. This suggests substantial difference in flame stability curve for non-premixed conditions in the scramjet engine compared to premixed flow. For base injection, fuel remained in the recirculation region even at higher injection pressure. Due to slower diffusion rate, the heavier fuel had higher local mole fraction in the recirculation region compared to lighter fuel for a unit global fuel mole fraction injected in the test section. Hence fuel molecular weight will affect the non-premixed flame stability limits in scramjet engine; the heavier fuel will have better fuel-lean and worse fuel-rich stability limit compared to lighter fuel. This is in addition to the fact that a lighter fuel such as hydrogen has a much wider flame stability limit than a heavier fuel such as propane. The data obtained in the study can help develop a stability parameter for non-premixed flames and validate computational models.