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Research paper thumbnail of Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat

Journal f�r Praktische Chemie/Chemiker-Zeitung, 1998

Di(pyrid-2-y1)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diproto... more Di(pyrid-2-y1)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-y1(2'-pyridinium) amine cation contains an intramolecular hydrogen bridge N@H...N and is slightly folded. The squarate salt dimer exhi

Research paper thumbnail of Wechselwirkungen in Kristallen. 136. Protonierte Di(pyrid-2-yl)amin-Salze mit verschiedenen Anionen: Monomeres Tetraphenylborat sowie Bis(trifluormethylsulfonat), dimeres Squarat und polymeres Chlorid-Dihydrat

Journal f�r Praktische Chemie/Chemiker-Zeitung, 1998

Di(pyrid-2-y1)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diproto... more Di(pyrid-2-y1)amine is monoprotonated by acetic, squaric as well as hydrochloric acid and diprotonated by trifluoromethylsulfonic acid. To explore the anion and hydrogen-bridge dependency of its salts, crystals of the monomeric tetraphenylborate, the dimeric squarate as well as the bis(trifluoromethylsulfonate) and the polymeric chloride hydrate have been grown and their structures determined: Separated by bulky tetraphenylborate anions, pyrid-2-y1(2'-pyridinium) amine cation contains an intramolecular hydrogen bridge N@H...N and is slightly folded. The squarate salt dimer exhi

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