suraya samejo - Academia.edu (original) (raw)
Papers by suraya samejo
Materials Chemistry and Physics
Analytical Methods
Magnesium oxide integrated chitosan nanocomposites based solid phase extraction for selective and... more Magnesium oxide integrated chitosan nanocomposites based solid phase extraction for selective and efficient detection of As, Cd, and Pb.
Arabian journal for science and engineering, Nov 23, 2022
The biosynthesis of the iron oxide nanoparticles was done using Ixoro coccinea leaf extract, foll... more The biosynthesis of the iron oxide nanoparticles was done using Ixoro coccinea leaf extract, followed by the fabrication of iron oxide nanobiocomposites (I-Fe 3 O 4-NBC) using chitosan biopolymer. Furthermore, the synthesized I-Fe 3 O 4-NPs and I-Fe 3 O 4-NBC were characterized, and I-Fe 3 O 4-NBC was applied to remove toxic metals (TMs: Cd, Ni, and Pb) from water. The characterization study confirmed that the nanostructure, porous, rough, crystalline structure, and different functional groups of chitosan and I-Fe 3 O 4-NPs in I-Fe 3 O 4-NBCs showed their feasibility for the application as excellent adsorbents for quantitative removal of TMs. The batch mode strategy as feasibility testing was done to optimize different adsorption parameters (pH, concentrations of TMs, dose of I-Fe 3 O 4-NBC, contact time, and temperature) for maximum removal of TMs from water by Fe 3 O 4-NBC. The maximum adsorption capacities using nanocomposites for Cd, Ni, and Pb were 66.0, 60.0, and 66.4 mg g −1 , respectively. The adsorption process follows the Freundlich isotherm model by I-Fe 3 O 4-NBC to remove Cd and Ni, while the Pb may be adsorption followed by multilayer surface coverage. The proposed adsorption process was best fitted to follow pseudo-second-order kinetics and showed an exothermic, favorable, and spontaneous nature. In addition, the I-Fe 3 O 4-NBC was applied to adsorption TMs from surface water (%recovery > 95%). Thus, it can be concluded that the proposed nanocomposite is most efficient in removing TMs from drinking water up to recommended permissible limit. Keywords I-Fe 3 O 4-NPs • I-Fe 3 O 4-NBC • Adsorption • Toxic metals • Kinetics • Thermodynamics • Surface water B Jameel Ahmed Baig
Pakistan Journal of Analytical & Environmental Chemistry
The effective desalination and purification devices for seawater/ brackish water treatment are cr... more The effective desalination and purification devices for seawater/ brackish water treatment are crucial in sustainable progress. Techniques that render high salt removal efficiency and water purification ability at low applied potentials play a central role in sustainable water supplies. One of them is capacitive deionization (CDI) which has drawn significant consideration as a promising deionization technology since the last decade. Desalination efficiency profoundly depends on the utilized electrode material. The most widely used CDI electrodes are carbons due to their cost effectiveness and good stability. However, to acquire high electrosorption capacity, extensive researches are reported with modified carbon materials. CDI cell architectures are equally important for practical high salt removal performance. This review focuses on carbon materials in CDI along with other emerging trends in diverse carbon types, e.g., carbon nanotubes and their composites. Various architectures re...
Applied Organometallic Chemistry
Environmental Science and Pollution Research
Materials Chemistry and Physics
Analytical Methods
Magnesium oxide integrated chitosan nanocomposites based solid phase extraction for selective and... more Magnesium oxide integrated chitosan nanocomposites based solid phase extraction for selective and efficient detection of As, Cd, and Pb.
Arabian journal for science and engineering, Nov 23, 2022
The biosynthesis of the iron oxide nanoparticles was done using Ixoro coccinea leaf extract, foll... more The biosynthesis of the iron oxide nanoparticles was done using Ixoro coccinea leaf extract, followed by the fabrication of iron oxide nanobiocomposites (I-Fe 3 O 4-NBC) using chitosan biopolymer. Furthermore, the synthesized I-Fe 3 O 4-NPs and I-Fe 3 O 4-NBC were characterized, and I-Fe 3 O 4-NBC was applied to remove toxic metals (TMs: Cd, Ni, and Pb) from water. The characterization study confirmed that the nanostructure, porous, rough, crystalline structure, and different functional groups of chitosan and I-Fe 3 O 4-NPs in I-Fe 3 O 4-NBCs showed their feasibility for the application as excellent adsorbents for quantitative removal of TMs. The batch mode strategy as feasibility testing was done to optimize different adsorption parameters (pH, concentrations of TMs, dose of I-Fe 3 O 4-NBC, contact time, and temperature) for maximum removal of TMs from water by Fe 3 O 4-NBC. The maximum adsorption capacities using nanocomposites for Cd, Ni, and Pb were 66.0, 60.0, and 66.4 mg g −1 , respectively. The adsorption process follows the Freundlich isotherm model by I-Fe 3 O 4-NBC to remove Cd and Ni, while the Pb may be adsorption followed by multilayer surface coverage. The proposed adsorption process was best fitted to follow pseudo-second-order kinetics and showed an exothermic, favorable, and spontaneous nature. In addition, the I-Fe 3 O 4-NBC was applied to adsorption TMs from surface water (%recovery > 95%). Thus, it can be concluded that the proposed nanocomposite is most efficient in removing TMs from drinking water up to recommended permissible limit. Keywords I-Fe 3 O 4-NPs • I-Fe 3 O 4-NBC • Adsorption • Toxic metals • Kinetics • Thermodynamics • Surface water B Jameel Ahmed Baig
Pakistan Journal of Analytical & Environmental Chemistry
The effective desalination and purification devices for seawater/ brackish water treatment are cr... more The effective desalination and purification devices for seawater/ brackish water treatment are crucial in sustainable progress. Techniques that render high salt removal efficiency and water purification ability at low applied potentials play a central role in sustainable water supplies. One of them is capacitive deionization (CDI) which has drawn significant consideration as a promising deionization technology since the last decade. Desalination efficiency profoundly depends on the utilized electrode material. The most widely used CDI electrodes are carbons due to their cost effectiveness and good stability. However, to acquire high electrosorption capacity, extensive researches are reported with modified carbon materials. CDI cell architectures are equally important for practical high salt removal performance. This review focuses on carbon materials in CDI along with other emerging trends in diverse carbon types, e.g., carbon nanotubes and their composites. Various architectures re...
Applied Organometallic Chemistry
Environmental Science and Pollution Research