Dina Abdaly | Al_Mustansiriyah - Academia.edu (original) (raw)
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Papers by Dina Abdaly
A new Schiff base [ N,N -bis(3-methyl-imidazilidene-2,6diamino-4-methyl pyrimidine ], (IP) have b... more A new Schiff base [ N,N -bis(3-methyl-imidazilidene-2,6diamino-4-methyl pyrimidine ], (IP) have been prepared and characterized by (FT-IR) Spectroscopy and elemental analysis (C.H.N) .(IP) has been used as a chelating ligand to prepare some complexes of ( Mn(П),Co(ІІ), Ni(П), Cu(П), Cr(Ш), Fe(Ш) and V(IV) ions .The prepared complexes were identified and their geometrical were suggested in solid state by using (FT-IR) and (UV-Vis) spectroscopy ,elemental analysis(C.H.N), Flame atomic absorption technique, in addition to magnetic susceptibility and conductivity measurements .The study of the nature of the complexes formed in ethanol following the mole ratio method, gave result which were compared successfully with those obtained from solid state studies . The apparent stability constant of the complexes have been studied with the time and their color were stable for more than (4hours), as well as the molar absorptivities have been calculated. The work also include a theoretical treatm...
A new Schiff base [ N,N -bis(3-methyl-imidazilidene-2,6diamino-4-methyl pyrimidine ], (IP) have b... more A new Schiff base [ N,N -bis(3-methyl-imidazilidene-2,6diamino-4-methyl pyrimidine ], (IP) have been prepared and characterized by (FT-IR) Spectroscopy and elemental analysis (C.H.N) .(IP) has been used as a chelating ligand to prepare some complexes of ( Mn(П),Co(ІІ), Ni(П), Cu(П), Cr(Ш), Fe(Ш) and V(IV) ions .The prepared complexes were identified and their geometrical were suggested in solid state by using (FT-IR) and (UV-Vis) spectroscopy ,elemental analysis(C.H.N), Flame atomic absorption technique, in addition to magnetic susceptibility and conductivity measurements .The study of the nature of the complexes formed in ethanol following the mole ratio method, gave result which were compared successfully with those obtained from solid state studies . The apparent stability constant of the complexes have been studied with the time and their color were stable for more than (4hours), as well as the molar absorptivities have been calculated. The work also include a theoretical treatm...