Andreas Lindblad | Uppsala University (original) (raw)
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Papers by Andreas Lindblad
The Journal of Physical Chemistry A
The Journal of Chemical Physics
Chemphyschem : a European journal of chemical physics and physical chemistry, May 16, 2018
Cross-linked polymers of elemental sulfur are of potential interest for electronic applications a... more Cross-linked polymers of elemental sulfur are of potential interest for electronic applications as they enable facile thin film processing of an abundant and cheap starting material. In this paper, we characterize the electronic structure of a cross-linked sulfur / diisopropenyl benzene (DIB) polymer by a combination of soft and hard X-ray photoelectron spectroscopy. Two different approaches for enhancing the conductivity of the polymer are compared: the addition of selenium in the polymer synthesis and the addition of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) during film preparation. For the former, we observe the incorporation of Se into the polymer structure resulting in a changed valence band structure. For the latter, a Fermi level shift in agreement with p-type doping of the polymer is observed but also the formation of a surface layer consisting mostly of TFSI anions.
Advances in Patterning Materials and Processes XXXIV
ACS applied materials & interfaces, Jan 19, 2017
Metal halide perovskites have emerged as materials of high interest for solar energy to electrici... more Metal halide perovskites have emerged as materials of high interest for solar energy to electricity conversion and in particular the use of mixed ion structures has led to high power conversion efficiencies and improved stability. For this reason, it is important develop means to obtain atomic level understanding of the photo-induced behaviour of these materials including processes such as photo-induced phase separation and ion migration. In this paper, we implement a new methodology combining visible laser illumination of a mixed-ion perovskite ((FAPbI3)0.85(MAPbBr3)0.15) with the element and chemical sensitivity of core-level photoelectron spectroscopy. By carrying out measurements at a synchrotron beamline optimised for low X-ray fluxes, we are able to avoid sample changes due to X-ray illumination and are therefore able to monitor what sample changes are induced by visible illumination only. We find that laser illumination causes partially reversible chemistry in the surface reg...
Journal of Chemical Physics, 2007
The Journal of Chemical Physics, Nov 14, 2006
Pccp Physical Chemistry Chemical Physics, Mar 3, 2009
Journal of Physics B Atomic Molecular and Optical Physics, Aug 7, 2006
The Journal of Physical Chemistry A
The Journal of Chemical Physics
Chemphyschem : a European journal of chemical physics and physical chemistry, May 16, 2018
Cross-linked polymers of elemental sulfur are of potential interest for electronic applications a... more Cross-linked polymers of elemental sulfur are of potential interest for electronic applications as they enable facile thin film processing of an abundant and cheap starting material. In this paper, we characterize the electronic structure of a cross-linked sulfur / diisopropenyl benzene (DIB) polymer by a combination of soft and hard X-ray photoelectron spectroscopy. Two different approaches for enhancing the conductivity of the polymer are compared: the addition of selenium in the polymer synthesis and the addition of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) during film preparation. For the former, we observe the incorporation of Se into the polymer structure resulting in a changed valence band structure. For the latter, a Fermi level shift in agreement with p-type doping of the polymer is observed but also the formation of a surface layer consisting mostly of TFSI anions.
Advances in Patterning Materials and Processes XXXIV
ACS applied materials & interfaces, Jan 19, 2017
Metal halide perovskites have emerged as materials of high interest for solar energy to electrici... more Metal halide perovskites have emerged as materials of high interest for solar energy to electricity conversion and in particular the use of mixed ion structures has led to high power conversion efficiencies and improved stability. For this reason, it is important develop means to obtain atomic level understanding of the photo-induced behaviour of these materials including processes such as photo-induced phase separation and ion migration. In this paper, we implement a new methodology combining visible laser illumination of a mixed-ion perovskite ((FAPbI3)0.85(MAPbBr3)0.15) with the element and chemical sensitivity of core-level photoelectron spectroscopy. By carrying out measurements at a synchrotron beamline optimised for low X-ray fluxes, we are able to avoid sample changes due to X-ray illumination and are therefore able to monitor what sample changes are induced by visible illumination only. We find that laser illumination causes partially reversible chemistry in the surface reg...
Journal of Chemical Physics, 2007
The Journal of Chemical Physics, Nov 14, 2006
Pccp Physical Chemistry Chemical Physics, Mar 3, 2009
Journal of Physics B Atomic Molecular and Optical Physics, Aug 7, 2006