Dipolar interactions and structural coherence in iron nanoparticle arrays (original) (raw)
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Magnetic Properties of Self-Assembled Fe Nanoparticle Arrays
MRS Proceedings, 2001
ABSTRACTThe magnetic properties of multilayer arrays of Fe nanoparticles were compared with those of frozen, dilute suspensions of the same particles. The array sample displayed larger coercivity in both hysteretic and remanent magnetization measurements. However, the derivative of the remanent magnetization curve shows a much broader switching field distribution for the arrays than for the dilute sample. Magnetic relaxation measurements show the convergence of the time dependent properties of the samples at large times, and much more rapid relaxation in the arrays at short times.
Effect of dipolar interaction observed in iron-based nanoparticles
Physical Review B, 2005
Spherical magnetic nanoparticles with narrow size distribution and organic capping were diluted in paraffin with different concentrations to verify the role of dipolar interactions on the macroscopic magnetic behavior. Increasing concentration of magnetic nanoparticles leads to higher blocking temperatures. The experimental data were analyzed by means of a recently proposed model that takes into account magnetic interactions of dipolar origin, and an excellent agreement was found. Considering the magnetic interaction among particles it was possible to obtain the real magnetic moment and estimate structural parameters that are consistent with the ones obtained by small angle x-ray scattering and transmission electron microscopy.
Magnetic properties of Fe-based nanoparticle assembly
Journal of Magnetism and Magnetic Materials, 2003
The magnetic properties of an assembly of very small Fe nanoparticles with an average diameter of the order of 3-5 nm are studied both experimentally and theoretically. The particles are dispersed in a polyethylene matrix with mass concentration 5%. The stray magnetic field of the samples with sizes 1 Â 1 Â 0.2 mm is measured by means of scanning SQUID microscope at 77 K as a function of external magnetic field. The presence of a weak remanent magnetization indicates a magnetic ordering in the samples studied at rather high temperatures. A distribution of the particle volumes or partial agglomeration of the particles within the assembly is suggested to be responsible for this unexpected behavior. r (S. Gudoshnikov). 0304-8853/03/$ -see front matter r 2002 Elsevier Science B.V. All rights reserved. PII: S 0 3 0 4 -8 8 5 3 ( 0 2 ) 0 1 0 1 1 -9
Defect‐Driven Magnetization Configuration of Isolated Linear Assemblies of Iron Oxide Nanoparticles
Advanced Functional Materials, 2019
The magnetization state of one-dimensional magnetic nanoparticle chains plays a key role for a wide range of applications ranging from diagnosis and therapy in medicine to actuators, sensors and quantum recording media. The interplay between the exact particle orientation and the magnetic anisotropy is in turn crucial for controlling the overall magnetization state with high precision. Here, we report on a three-dimensional description of the magnetic structure of one-NP-wide chains. In this aim, we combined two complementary experimental techniques, magnetic force microscopy (MFM) and electronic holography (EH) which are sensitive to out-of-plane and in-plane magnetization components, respectively. We extended our approach to micromagnetic simulations which provided results in good agreement with MFM and EH. The findings are at variance with the known results on unidirectional nanoparticle assemblies, and show that magnetization is rarely strictly collinear to the chain axis. The magnetic structure of one-NP-wide chains can be interpreted as head-to-head magnetic domain structures with off-axis magnetization components, which is very sensitive to morphological defects in the chain structure such as minute size variation of NPs, tiny misalignment of NPs and/or crystal orientation with respect to easy magnetization axis.
X-ray studies of magnetic nanoparticle assemblies
Journal of Applied Physics, 2003
Monodisperse FePt nanoparticles were prepared using high temperature solution phase synthesis. Polymer-mediated layer-by-layer growth leads to precise control of the particle self-assembly. The narrow particle size distribution (σ ≤ 5%) offers the potential for increased data storage density by utilizing a smaller mean particle size and ultimately storage of one bit per individual nanoparticle. We have studied self-assembled multilayers of magnetic FePt nanoparticles. The L1 0 phase of FePt has a very high magnetic anisotropy which allows the magnetization of particles of about 4 nm diameter to be thermally stable at room temperature. Magnetic measurements using vibrating sample magnetometer were combined with X-ray diffraction (XRD) and Near Edge Xray Absorption Fine Structure (NEXAFS) Spectroscopy to study the annealed FePt nanoparticle assemblies and to optimize annealing conditions. NEXAFS spectra showed that a fraction of the iron in the as-deposited particles was oxidized, and this fraction was reduced by annealing in inert or reducing atmospheres. A very thin layer (<0.4 nm) of oxide surrounding the particle is sufficient to explain the observed spectra. Structural analysis using XRD showed that a minimum temperature of 450°C was required to start the formation of the ordered ferromagnetic phase. Annealing for longer times and at
Journal of Applied Physics, 2008
The magnetic characteristics of iron nanoparticles embedded in an alumina thin film matrix have been studied as a function of spacer layer thickness. Alumina as well as iron nanoparticles were deposited in a multilayered geometry using sequential pulsed laser deposition. The role of spacer layer thickness was investigated by making layered thin film composites with three different spacer layer thicknesses (6, 12, and 18 nm) with fixed iron particle size of ~13 nm. Intralayer magnetic interactions being the same in each sample, the variation in coercivity and saturation magnetization is attributed to thickness dependent interlayer magnetic interactions of three types: exchange, strong dipolar, and weak dipolar. A thin film composite multilayer structure offers a continuously tunable strength of interparticle dipole-dipole interaction and is thus well suited for studies of the influence of interaction on the magnetic properties of small magnetic particle systems.
Direct Observation of Magnetic Metastability in Individual Iron Nanoparticles
Physical Review Letters, 2014
"X-ray photoemission electron microscopy combined with x-ray magnetic circular dichroism is used to study the magnetic properties of individual iron nanoparticles with sizes ranging from 20 down to 8 nm. While the magnetocrystalline anisotropy of bulk iron suggests superparamagnetic behavior in this size range, ferromagnetically blocked particles are also found at all sizes. Spontaneous transitions from the blocked state to the superparamagnetic state are observed in single particles and suggest that the enhanced magnetic energy barriers in"
Physical chemistry chemical physics : PCCP, 2016
Iron oxide nanoparticles have found an increasing number of biomedical applications as sensing or trapping platforms and therapeutic and/or diagnostic agents. Most of these applications are based on their magnetic properties, which may vary depending on the nanoparticle aggregation state and/or concentration. In this work, we assess the effect of the inter- and intra-aggregate magnetic dipolar interactions on the heat dissipation power and AC hysteresis loops upon increasing the nanoparticle concentration and the hydrodynamic aggregate size. We observe different effects produced by inter- (long distance) and intra-aggregate (short distance) interactions, resulting in magnetizing and demagnetizing effects, respectively. Consequently, the heat dissipation power under alternating magnetic fields strongly reflects such different interacting phenomena. The intra-aggregate interaction results were successfully modeled by numerical simulations. A better understanding of magnetic dipolar in...
2D to 3D crossover of the magnetic properties in ordered arrays of iron oxide nanocrystals
Nanoscale, 2013
The magnetic 2D to 3D crossover behavior of well-ordered arrays of monodomain g-Fe 2 O 3 spherical nanoparticles with different thicknesses has been investigated by magnetometry and Monte Carlo (MC) simulations. Using the structural information of the arrays obtained from grazing incidence small-angle X-ray scattering and scanning electron microscopy together with the experimentally determined values for the saturation magnetization and magnetic anisotropy of the nanoparticles, we show that MC simulations can reproduce the thickness-dependent magnetic behavior. The magnetic dipolar particle interactions induce a ferromagnetic coupling that increases in strength with decreasing thickness of the array. The 2D to 3D transition in the magnetic properties is mainly driven by a change in the orientation of the magnetic vortex states with increasing thickness, becoming more isotropic as the thickness of the array increases. Magnetic anisotropy prevents long-range ferromagnetic order from being established at low temperature and the nanoparticle magnetic moments instead freeze along directions defined by the distribution of easy magnetization directions.