Elastomeric properties of end-linked networks of high cross-link functionality. Accounting for possible changes in effective functionality with extent of reaction and chain-length distribution (original) (raw)

Colloid & Polymer Science, 1994

Abstract

... The mean positions of the junc-tions are affine in the strain, but the fluctuations about the mean positions are invariant with strain. The modulus is given by [8-10, 8-22] [f*]ph ~ RT02/3 = 2c , (3) where [18-22] = v,- #a = v-# (4) ...

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