Polycyclic aromatic hydrocarbons in air on small spatial and temporal scales – I. Levels and variabilities (original) (raw)
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Science of The Total Environment, 2010
Data concerning atmospheric lifetime and relative source contributions of polycyclic aromatic hydrocarbons (PAH) are fragmentary and contradictory. In this study, two datasets of measurements of atmospheric PAH (sum of particulate and gaseous phases), one from a national network, the other from a more local three-site study, were analysed and used to infer processes affecting PAH in the atmosphere, and their sources. PAH congener profiles measured at urban and rural locations were remarkably similar suggesting that atmospheric decay processes are relatively slow. This allows the use of such profiles to elucidate sources. A spatial analysis of two PAH datasets showed a clear influence of industry and road traffic upon local PAH concentrations. When Principal Component Analysis (PCA) was applied to UK national network data, it showed a clear influence of steel industry emissions and of home heating emissions from coal and oil in Northern Ireland. These sites also showed different winter/summer concentration ratios to the main group of sites. In the data from Birmingham (UK), PCA identified separate factors relating to gasoline and diesel vehicles, as well as the influence of wood combustion on "Bonfire night", and a factor related to home heating emissions which shows up only in the cold season.
Characterization of particulate polycyclic aromatic hydrocarbons in the east of France urban areas
Environmental Science and Pollution Research, 2011
Background Air samples collected on three different urban sites in East of France (Strasbourg, Besançon, and Spicheren), from April 2006 to January 2007, were characterized to measure the concentrations of polycyclic aromatic hydrocarbons (PAHs) in the particulate phase (PM 10) and to examine their seasonal variation, diurnal variations, and emission sources. Results The average concentrations of ΣPAHs were 12.6, 9.5, and 8.9 ng m −3 for the Strasbourg, Besançon, and Spicheren sites, respectively. Strong seasonal variations of individual PAH concentrations were found at the three sampling sites, with higher levels in the winter that gradually decreased to the lowest levels in the summer. The diurnal variations of PAH concentrations in summer presented highest concentrations during the morning (04:00-10:00) and the evening (16:00-22:00) times, indicating the important contribution from vehicle emissions, in the three sampling sites. Furthermore, the ratio of BaP/BeP suggests that the photochemical degradation of PAHs can suppress their concentrations in the midday/afternoon (10:00-16:00), time interval of highest global irradiance. In winter, concentrations of PAH were highest during the evening (16:00-22:00) time, suggesting that domestic heating can potentially be an important source for particulate PAH, for the three sampling sites. Conclusion Diagnostic ratios were used to identify potential sources of PAHs. Results showed that vehicle emissions may be the major source of PAHs, especially in summer, with a prevalent contribution of diesel engines rather than gasoline engines at the three sites studied, independently of the seasons.
Particle-size distribution of polycyclic aromatic hydrocarbons in urban air in southern Spain
Analytical and Bioanalytical Chemistry, 2005
The size distribution of polycyclic aromatic hydrocarbons (PAH) was determined for airborne particles from a large city with high vehicular traffic. The analytical method was optimised and validated using NIST standard reference material (SRM 1649a Urban Dust). The 16 priority PAH listed in the US-EPA were Soxhlet-extracted from filtered particulate matter and then fractionated using on-column chromatography. The aromatic fraction was quantified by gas chromatography-mass spectrometry. Real samples of particles collected in Seville (Spain) were analysed using the validated method. Values for the total concentration of PAH in the air, as well as the concentrations of each PAH in six particle-size ranges were obtained. Values of the PAH in TSP, PM10, PM2.5 and PM1 were assessed.
Chemosphere, 2007
Urban aerosol was collected in a summer and a winter campaign for 7 and 3 days, respectively. Low volume samples were taken with a time resolution of 160 min using a filter/sorption cartridge system extended by an ozone scrubber. Concentrations of mainly particle associated polycyclic aromatic hydrocarbons (PAH) and oxidised PAH (O-PAH) were determined by gas chromatography/high resolution mass spectrometry. The sampling site was located in the city centre of Augsburg, Germany, near major roads with high traffic volume. The daily concentrations and profiles were mainly governed by local emissions from traffic and domestic heating, as well as by the meteorological conditions. During the winter campaign, concentrations were more than 10 fold higher than during the summer campaign. Highest concentrations were found concurrent with low boundary layer heights and low wind speeds. Significant diurnal variation of the PAH profiles was observed. Enhanced influences of traffic related PAH on the PAH profiles were evident during daytime in summer, whereas emissions from hot water generation and domestic heating were obvious during the night time of both seasons. A general idea about the global meteorological situation was acquired using back trajectory calculations (NOAA ARL HYSPLIT4). Due to high local emissions in combination with low air exchange during the two sampling campaigns, effects of mesoscale transport were not clearly observable.
Polycyclic Aromatic Compounds, 2014
The concentrations of six PAHs (benzo[a]pyrene, benzo[b]fluoranthene, ideno[1,2,3.c,d]pyrene, benzo[a]anthracene, benzo[k]fluoranthene and fluoranthene), and lead have been measured systematically for six winter periods from 1977/78 to 1982/83 in the urban air of the city of Zagreb. The average mass concentrations of PAHs were ~ 10 ng m-3. The distribution of PAHs in urban air is discussed. The analytical method for PAH determination is based on filter extraction, two-dimensional thin-layer chromatography and fluorescence spectrometry; lead is measured by atomic absorption.
Atmospheric fine and coarse particles were collected in Teflon filters in three cities of the region of the Lower Sinos River Basin of Rio Grande do Sul in the year 2010. The filters were Soxhlet extracted, and 14 priority PAHs were analyzed using a gas chromatograph coupled to a mass spectrometer (GC/MS). The principal emission sources of these compounds were assessed by using diagnostic ratios and receptor model: positive matrix factorization (PMF 3.0) of the US Environmental Protection Agency. The results of PAHs concentration for the studied year showed significant levels of high molecular weight (HMW) PAH, Ind, and BghiP, in PM 2.5 in the winter season, showing the influence of mobile sources. The application of receptor model PMF 3.0 revealed that the main sources of PAHs were vehicle fleet (both diesel and gasoline), followed by coal combustion, wood combustion, and resuspension of dust. The results of the receptor modeling are in agreement with the data obtained by the ratio diagnostic. Environ Monit Assess (2013) 185:9587-9602 Author's personal copy Environ Monit Assess (2013) 185:9587-9602
Air Pollution and Health, 2016
Introduction : Polycyclic aromatic hydrocarbons are among the main pollutants in the urban and industrial atmosphere. An investigation on variation of PAHs in the urban and suburban atmosphere of Tabriz, Iran was conducted in this study. Materials and methods: TSP and PM10 (particulate matter with aerodynamic diameter <10μm) samples were collected at two sites between September 2013 to July 2014. PAHs were analyzed with GC–MS. Results: The concentrations of the total PAHs in TSP and PM10 were 47.87±17.28 and 36.69±6.71 ng/m3 in the urban site and 91.88±35.65 and 77.2±22.24 ng/m3 in the suburban sampling site, respectively. 4-5 ring PAHs (Chr, BaA, BghiA, Flu, Nap, and Phen) were the abundant PAHs compounds, which accounted for 75-80% of total PAHs in urban and 85-88% of total PAHs in suburban sampling sites. The ratio of carcinogenic PAHs (BaA, Chr, BbF, BkF, BaP, DahA and Ind) to ΣPAHs respectively ranged from 0.51-0.58 and 0.81-0.85 in urban and suburban sampling sites. Conclus...
Environmental Science and Pollution Research, 2015
Over 1-year period, 13 polycyclic aromatic hydrocarbons (PAHs) associated with particulate matter PM 10 have been monitored for the first time in the atmosphere of Ciudad Real, situated at the central-southern Spain. PM 10-bound PAHs were collected using a high-volume sampler from autumn 2012 to summer 2013 and were analyzed by HPLC with fluorescence detector. The most abundant PAHs were pyrene, chrysene, benzo[b]fluoranthene, dibenzo[a,h]anthracene and benzo[g,h,i]perylene. The ∑PAH concentrations in Ciudad Real were 888, 368, 259 and 382 pg m −3 for winter, spring, summer and autumn seasons, respectively. The diurnal variation of PAH was also investigated presenting the highest concentrations during the evening (19:00-23:00). Benzo[a]pyrene concentrations ranged from 2.4 to 110 pg m −3 , these values are lower than the target value proposed by the European legislation, 1 ng m −3. Diagnostic ratios were used to identify potential sources of PAHs. Results suggest that vehicle emissions are the major source of identified PAHs, with a higher contribution of diesel engines although other anthropogenic sources could also have an impact on the PAH levels.