Electron momentum distributions and atomic expectation values (original) (raw)

Physical Review A, 1982

Abstract

The <r/sup n/> expectation values have been extracted from the known electron momentum distributions for hydrogen, helium, argon, and krypton atoms with the use of a semiclassical approach. These values compare fairly well with their Hartree-Fock counterparts. This procedure provides a link between the distribution of electrons in the momentum space and that in the coordinate space.

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