Fixation of atmospheric CO2 as C1-feedstock by nickel(ii) complexes (original) (raw)

Fixation of atmospheric CO2 as C1-feedstock by nickel(ii) complexes

Dalton Transactions, 2021

Abstract

The Ni(ii) complexes of diazepane-based N3-ligands with a cis-β configuration showed the conversion of atmospheric or pure CO2 into cyclic carbonates under 1 atm pressure via a CO2-bound nickel(ii) intermediate.

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