Application of ZnO–Fe3O4 Nanocomposite on the Removal of Azo Dye from Aqueous Solutions: Kinetics and Equilibrium Studies (original) (raw)

Application of magnetite nanoparticles modified Azolla as an adsorbent for removal of reactive yellow dye from aqueous solutions

DESALINATION AND WATER TREATMENT, 2021

In this study, we aimed to remove reactive yellow 160 (RY 160) dye from aqueous solutions, and for this, collected Azolla was modified with magnetite nanoparticles. The size and structure of magnetite modified Azolla nanocomposite were studied by scanning electron microscopy and Fourier-transform infrared spectroscopy. The factors affecting the dye removal efficiency including pH, ionic strength, stirring time, solution volume, and adsorbent weight were investigated using Taguchi fractional orthogonal array design (OA 16). The results of adsorption kinetics at 50 and 100 mg L-1 under optimum conditions (pH = 2, ionic strength = no salt addition, the solution volume = 25 mL, stirring time = 10 min and adsorbent weight = 0.15 g) showed that removal of RY 160 was performed through a pseudo-second-order kinetic model (q e = 30.2 mg g-1 , R 2 = 1). Isotherm models at three contact times of 10, 25, and 50 min showed that adsorption follows the Freundlich model (n = 1.2, K F = 2.3). Reusability experiments under optimum conditions confirmed the removal efficiency of more than 95% after 16 repetitive adsorption usage. The results of real samples showed that this nanocomposite is an effective adsorbent for the rapid removal of RY 160. Low-cost, reusability and fast elimination have made the synthesized nanocomposite as a useful adsorbent in RY 160 removal.

Adsorptive removal of cationic dye from aqueous solutions by ZnO/ZnMn2O4 nanocomposite

Separation Science and Technology, 2018

The ZnO/ZnMn 2 O 4 nanocomposite (ZnMn) was used as adsorbent for the removal of cationic dye Basic Yellow 28 (BY28) from aqueous solutions. The adsorbent was characterized by X-ray diffraction, scanning electron microscope, TEM, Fourier transform infrared ray, BET, particle size distribution and zeta potential measurements. The adsorption parameters, such as temperature, pH and initial dye concentration, were studied. Kinetic adsorption data were analyzed using the pseudofirst-order, pseudo-second-order and intraparticle diffusion kinetic models. The Langmuir and Freundlich isotherm models were applied to fit the equilibrium data. The maximum adsorption capacity of BY28 was 48.8 mg g −1. Various thermodynamic parameters, such as ΔG°, ΔH°and ΔS°, were calculated.

Preferential and Enhanced Adsorption Ability of ZrO2 Nanoparticles for the Removal of Cationic, Anionic and Azo Dyes: Isotherm and Kinetic Studies

Journal of Nanoscience and Nanotechnology, 2019

Adsorption of Coomassie Brilliant Blue R-250, Congo Red and Acridine Orange from aqueous solution has been examined using ZrO2 nanoparticles, which proved to be a novel adsorbent. ZrO2 nanoparticles have been prepared by simple chemical precipitation method. The characterization of ZrO2 nanoparticles has been carried out by UV-vis spectroscopy, FTIR, XRD, TEM and FESEM. ZrO2 nanoparticles were found tetragonal in structure, spherical in morphology, and illustrated constricted size window (8–12 nm). The findings depicted that adsorbate removal on ZrO2 nanoparticles was affected significantly by change in adsorbent dose, pH and initial dye concentration w.r.t to contact time. The isotherms were well elaborated using Langmuir and Freundlich adsorption isotherms. The adsorptive kinetics was also investigated with pseudo-second-order to evaluate constant corresponding to rate. Moreover, the ZrO2 nanoparticles along with adsorbed dyes were desorbed. The identities of recovered nanoparticl...

Pb doped ZnO nanoparticles for the sorption of Reactive Black 5 textile azo dye

Water Science and Technology

In this study, Pb doped ZnO nanoparticles were synthesized by a sol-gel technique for the sorption of Reactive Black 5 (RB5) textile dye in aqueous solution. The ZnO:Pb (2 and 4%) nanoparticles have been characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy and cryogenic nitrogen adsorption method. The average size of the synthesized nanoparticles was less than 100 nm and the surface areas were 18.8 and 20.8 m2/g, respectively for ZnO:Pb 2% and ZnO:Pb 4%. Batch sorption experiments were performed for color removal of RB5 dye at ambient temperature and 30 mg/L dye concentration. The central composite design with response surface methodology was used to study the effect of sorption condition (pH, nanoparticles dose and contact time). The significance of independent variables and their interactions was tested by analysis of variance. The optimum conditions of color removal were pH = 7, 2 g/L...

Efficient Removal of Organic Dyes and Lead Ions With Eco-friendly Prepared Zinc Oxide Nanoparticles From Water&nbsp

Research Square (Research Square), 2021

In this research work, different ZnO NPs were prepared via eco-friendly green route using Ziziphus jujuba leaves extract assisted by microwave. Eco-friendly prepared ZnO NPs characterized by different techniques, and the results confirmed the preparation of hexagonal wurtzite ZnO nanoparticles with different particle sizes. The prepared ZnO NPs were then used for the adsorption and removal of two different azo dyes; methyl orange (MO), and methylene blue (MB), as well as toxic Pb(II) ions, from a model solution and real samples. Influence of experimental conditions was explored, and the results showed that most of the MB, MO and Pb(II) could be removed from the model solution within few minutes, at ambient conditions using 15 mg ZnO NPs. The removal of the MB, MO and Pb(II) using ZnO NPs was studied kinetically and thermodynamically, and the results showed that the experimental data were best fitted using the pseudo-second-order kinetic models. The thermodynamics study showed that the process was spontaneous, with exothermic nature. Finally, the prepared ZnO NPs were used for the removal of MB, MO and Pb(II) in real wastewater sample, and high removal efficiency was presented.

Adsorption of Dye by Nano-zinc oxide

2020

Nano–zinc oxide (ZnO) has recently achieved special attention because of its unique optical, electrical and chemical properties. Zinc sulfate heptahydrate and ammonium hydroxide wereused as precursor materials for the preparation of Nano–zinc oxide. The current study aimed to investigate the effect of period of contact on the rate of adsorption of Nano-zinc oxide, the impact of interactionperiod on the percentage removal, the effect of pH and the effect of adsorbent dose. Central composite design (CCD) in response surface methodology (RSM) was used to proposed design and augment the elimination of dyes againstinitial dyes concentration, pH, adsorbent mass and time, in addition to study the potential relations among these variables. It was found in this study that when the concentration of Methylene Blue in waste water increases, the percentage removal decreases. Equilibrium concentration is reached after 40 minutes. The isotherm and kinetics estimations demonstrated that Freundlich ...

Efficient Removal of Organic Dyes and Lead Ions With Eco-friendly Prepared Zinc Oxide Nanoparticles From Water

2021

In this research work, different ZnO NPs were prepared via eco-friendly green route using Ziziphus jujuba leaves extract assisted by microwave. Eco-friendly prepared ZnO NPs characterized by different techniques, and the results confirmed the preparation of hexagonal wurtzite ZnO nanoparticles with different particle sizes. The prepared ZnO NPs were then used for the adsorption and removal of two different azo dyes; methyl orange (MO), and methylene blue (MB), as well as toxic Pb(II) ions, from a model solution and real samples. Influence of experimental conditions was explored, and the results showed that most of the MB, MO and Pb(II) could be removed from the model solution within few minutes, at ambient conditions using 15 mg ZnO NPs. The removal of the MB, MO and Pb(II) using ZnO NPs was studied kinetically and thermodynamically, and the results showed that the experimental data were best fitted using the pseudo-second-order kinetic models. The thermodynamics study showed that t...

Adsorption of Acid Red 88 Anionic Dye from Aqueous Solution onto ZnO/ZnMn2O4 Nanocomposite: Equilibrium, Kinetics, and Thermodynamics

Polish Journal of Environmental Studies

Dyes are synthetic organic compounds that are increasingly being produced and used extensively in the paper, leather, textile, plastic, cosmetic, and other industries. Approximately 70,000 ton of dyestuffs are discharged into waste streams each year by the textile industry [1]. The presence of even very low concentrations of dyes in water reduces light penetration through the water surface, precluding photosynthesis of the aqueous flora. Additionally, many dyes or their metabolites have toxic as well as carcinogenic, mutagenic, and teratogenic effects on aquatic life and humans. Hence, the removal of dyes from aquatic wastewater has became environmentally important. Various methods including photocatalysis [2], chemical oxidation [3], coagulation [4], electrochemical [5], and adsorption [6] techniques have been applied for the removal of dyes from aqueous solutions. Among these methods, adsorption has been found to be superior

Removal of methylene blue and acid orange 7 from aqueous solutions by activated carbon coated with zinc oxide (ZnO) nanoparticles: equilibrium, kinetic, and thermodynamic study

Desalination and Water Treatment, 2014

Various industries like textile, plastic, pulp, and paper produce dye containing wastewaters that have harmful effects on the environment as well as human health. The aim of this study was to investigate the effect of granular activated carbon (AC) coated by zinc oxide nanoparticles (ZnO-np) in the removal of dyes, methylene blue (MB) and acid orange 7 (AO7), from aqueous solutions. The morphology of the AC and AC-ZnO was determined by SEM and the FTIR spectra confirmed the strong interaction between AC and ZnO. The effect of various parameters, such as nanoparticles loading onto the AC, pH, contact time, dye concentration, ion strength, temperature, and adsorbent regeneration, was studied on the adsorption. The results showed that the surface structure of the raw AC was porous and had irregular shapes, but the surface of the modified AC (AC-ZnO) due to the homogenous coating of the ZnO-np onto the AC was approximately uniform and regular. The sorption capacity and optimum contact time for the removal of MB (32.22 mg/g) and AO7 (32.13 mg/g) by AC-ZnO were obtained as 32.22 mg/g during 120 min and 32.13 mg/g over 150 min, respectively. The optimum pH for the sorption of MB occurred at pH 11 and for AO7 was obtained at pH 3. The results also showed that Langmuir isotherm and pseudosecond-order kinetic models fitted the experimental data better than other isotherm and kinetic models. It is obviously clear that AC-ZnO, in comparison with raw AC, was more efficient sorbent for the removal of MB and AO7 and it can be proposed for the removal of these dyes from aqueous solutions.

ADSORPTION KINETICS FOR REMOVAL OF METHYL ORANGE DYE USING SYNTHESIZED ZnO NANOPARTICLES

2018

Nano-sized crystals of zinc oxide (ZnO) were synthesized, with a size of 26 nm. The products have been subjected to thorough characterization with Fourier Transform Infra Red spectroscopic techniques as well as X-ray diffraction analysis. These investigations confirm the formation of zinc oxide nanoparticles. The nano-particles showed remarkable adsorption efficiency in removal of methylorange dye. For the evaluating the adsorption kinetics of methyl orange on ZnO nanoparticles, the data was treated with Lagergren first order model. Thusthis studyaimed at assessing the nature of adsorption kinetics resulting from photo degradation of methylorange dye using ZnO nanoparticles. Precipitation technique was used to synthesize ZnO nanoparticles. The values obtained for Lagergren second order plot of methyl orange adsorption under sunlight and fluorescent conditions were higher than those of Lagergren first order. This suggests that the process followed the pseudo second order kinetics. Fu...