Confirmation and Prediction of Far Infrared Laser Emissions from Excited Torsional States of Methyl Alcohol (original) (raw)

Journal of Molecular Spectroscopy, 1993

Abstract

ABSTRACT In this paper, detailed analysis of the high-resolution Fourier transform spectra of the infrared (IR) C-O stretch and far-infrared (FIR) torsion-rotation bands of methyl alcohol has been applied to predict 30 potential FIR laser lines and to confirm previously proposed assignments of FIR emission lines optically pumped in the second and third excited torsional states of the C-O stretch mode. The combination loop closure technique provided accurate wavenumbers for the observed and predicted FIR laser transitions.

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