Electron‐Rich Vaska‐Type Complexes trans ‐[Ir(CO)Cl(2‐Ph 2 PC 6 H 4 COOMe) 2 ] and trans ‐[Ir(CO)Cl(2‐Ph 2 PC 6 H 4 OMe) 2 ]: Synthesis, Characterisation and Reactivity (original) (raw)

Computational, Spectroscopic, and Crystallographic Determination of the Molecular Structures of CO Adducts of Vaska-Type Complexes trans-IrL2(CO)2X

Faraj Hasanayn, Karsten Krogh-Jespersen

Organometallics, 1994

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Synthesis and Characterization of New Square Planar Iridium Complexes [trans-Ir(CO)L2X] (L = PCy3, X = OH or OCH3; L = P(p-tolyl)3, X = OCH2C6H5 or O(pC6H4CH3)): Crystal and Molecular Structures of trans-Ir(CO)(OH)(PCy3)2, trans-Ir(CO)(OCH2C6H5)(P(p-tolyl)3)2, and trans-Ir(CO)(OpC6H4CH3)(P(p-toly...

Thomas Janik

Organometallics, 1994

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Oxidative addition of halogens to thiolato-bridged dinuclear iridium(I) complexes. Preparation of several iridium(II) and iridium(III) species. X-ray structure of Ir2(.mu.-Me3CS)2(CO)2(PMe2Ph)2I2

Philippe Kalck

Organometallics, 1982

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Iridium(I), Iridium(III), and Iridium(V) Complexes Containing the (2-Methoxyethyl)cyclopentadienyl Ligand †

Francisco J. Fernández-Alvarez

Organometallics, 2006

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Ab Initio Molecular Orbital Study of Substituent Effects in Vaska Type Complexes (trans-IrL2(CO)X): Electron Affinities, Ionization Potentials, Carbonyl Stretch Frequencies and the Thermodynamics of H2 Dissociative Addition

Karsten Krogh-Jespersen

Inorganic Chemistry, 1994

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Energetics of the oxidative addition of I 2 to [Ir (Μ-L)(CO) 2] 2 (L= S t Bu, 3, 5-Me 2 pz, 7-aza) complexes. X-ray structures of Ir (Μ-S t Bu)(I)(CO) 2] 2 and [Ir (Μ-3, 5-Me 2 …

Palmira Silva

Structural …, 1996

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Chemistry of (.eta.5-C5Me5)Ir(CO)2. 1. Metal-metal bond formation employing a basic metal center

Victor Day

Organometallics, 1986

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Complexes of Ir 3 (CO) 3 (η 5 -C 9 H 7 ) 3 with Metal Fragment Electrophiles

John Shapley

Organometallics, 1997

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Synthesis and characterization of a bimetallic iridium complex with a ten sp2-carbon chain bridge

Dhananjay Kumar

Dalton Transactions, 2007

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Dinuclear Iridium Complexes Containing Cp* and Carbonyl Ligands: Synthesis, Structure, and Reactivity

Werner Kaminsky

Organometallics, 2009

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The use of half-sandwich iridium dithiolate and diselenolate complexes, Cp*Ir(L)(ER)2 (L=CO, PMe3, PPh3; ER=SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of Cp*Ir(CO)(μ-SePh)2[Mo(CO)4]

Max Herberhold

Journal of Organometallic Chemistry, 1998

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Binuclear rhodium(III) and iridium(III) monoselenocarboxylates: Synthesis, spectroscopy and structure of an ortho-metallated iridium complex featuring an IrCCC(μ-Se) chelate ring

amey wadawale

Inorganic Chemistry Communications, 2010

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Synthesis and structure of the first monomeric iridium–siloxide complexes

Ireneusz Kownacki

Inorganica Chimica Acta, 2002

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New cationic rhodium(I)-iridium(III) complexes with bridging hydride and chloride ligands. Synthesis and x-ray crystal structure of [(diphos)Rh(.mu.-H)(.mu.-Cl)IrCl(PEt3)3]BF4 and [(diphos)Rh(.mu.-H)(.mu.-Cl)IrH(PEt3)3]BF4

Dominique MATT

Inorganic Chemistry, 1984

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Preparation and characterization of the dimetallo ketone complexes Ir2(.mu.-S-tert-Bu)2(.mu.-CO)L2(CO)2I2: crystal and molecular structure of the [iridium] complex where L = trimethylphosphine

Philippe Kalck

Inorganic Chemistry, 1987

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Ab initio molecular orbital study of substituent effects in vaska type complexes (trans-IrLâ(CO)X): Electron affinities, ionization potentials, carbonyl stretch frequencies, and the thermodynamics of Hâ dissociative addition

Alan Goldman

Inorganic Chemistry, 1994

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New cationic rhodium(I)-iridium(III) complexes with bridging hydride and chloride ligands. Synthesis and X-ray crystal structure of [(diphos)Rh(μ-H)(μ-Cl)IrCl(PEt3)3]BF4 and [(diphos)Rh(μ-H)(μ-Cl)IrH(PEt3)3]BF4

Dominique MATT

Inorganic Chemistry, 1984

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Heterobimetallic (ferrocenyl)indenyl iridium complexes. Synthesis, crystal structure, reactivity and oxidative activation

Mauro Tiso, Laura Crociani

Inorganica Chimica Acta, 2003

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Syntheses and crystal structures of the first iridium complexes with m- and p-terphenyl (tp). {Ir2(p-tp)(cod)22·2CH2Cl2}3 and Ir(m-tp)(η5-C5Me5)2

Yusaku Suenaga

Inorganica Chimica Acta, 2004

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Synthesis and reactivity investigation of iridium maleonitriledithiolate complexes. Redox studies and extended Hückel molecular orbital calculations on Cp∗ IrL(mnt) (where L = PMe3, PPh3, CN-t-Bu)

Deepak Sharma

Journal of Organometallic Chemistry, 1995

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Electrochemical Investigations Give Some Insights into the Coordination Chemistry of New Stable Iridium(+1), Iridium(0), and Iridium(−1) Complexes

Marina Mlakar

Electroanalysis, 2003

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Cyclometallated Iridium and Platinum Complexes with Noninnocent Ligands

Petter Persson, William Goddard

Inorganic Chemistry, 2007

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Structure and Reactivity of New Iridium Complexes with Bis(Oxazoline)-Phosphonito Ligands

Pierre Braunstein

Inorganic Chemistry, 2009

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Synthesis and structures of di- and trinuclear di-tert-butylphosphido and di-tert-butylarsenido complexes of iridium. X-ray crystal structures of [Ir(.mu.-tert-Bu2E)(CO)2]2 (E = P, As), [Ir(tert-Bu2PH)(CO)]2(.mu.-H)(.mu.-tert-Bu2P), [Ir(tert-Bu2PH)(CO)(.mu.-H)]2(H)(.mu.-tert-Bu2P), and Ir3(.mu.-t...

Jerry Atwood

Inorganic Chemistry, 1987

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Cyclometalated Iridium(III) Complexes Containing Hydroxide/Chloride Ligands: Isolation of Heterobridged Dinuclear Iridium(III) Compounds Containing μ-OH and μ-Pyrazole Ligands

kelvin chen

Inorganic Chemistry, 2012

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The migratory insertion of carbon monoxide in pentamethylcyclopentadienyliridium (III) complexes. Structural effects on reactivity and mechanism for rhodium and iridium systems

Peter Maitlis, Mauro Bassetti, Anthony Haynes

Inorganica Chimica Acta, 1995

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