Evaluation of atmospheric benzene concentrations in the Helsinki Metropolitan Area in 2000–2003 using diffusive sampling and atmospheric dispersion modelling (original) (raw)
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Benzene exposure and the effect of traffic pollution in Copenhagen, Denmark
Atmospheric Environment, 2001
Benzene is a carcinogenic compound, which is emitted from petrol-fuelled cars and thus is found ubiquitous in all cities. As part of the project Monitoring of Atmospheric Concentrations of Benzene in European Towns and Homes (MACBETH) six campaigns were carried out in the Municipality of Copenhagen, Denmark. The campaigns were distributed over 1 year. In each campaign, the personal exposure to benzene of 50 volunteers (non-smokers living in non-smoking families) living and working in Copenhagen was measured. Simultaneously, benzene was measured in their homes and in an urban network distributed over the municipality. The Radiello di!usive sampler was applied to sample 5 days averages of benzene and other hydrocarbons. Comparison of the results with those from a BTX-monitor showed excellent agreement. The exposure and the concentrations in homes and in the urban area were found to be close to log-normal distribution. The annual averages of the geometrical mean values were 5.22, 4.30 and 2.90 g m\ for personal exposure, home concentrations and urban concentrations, respectively. Two main parameters are controlling the general level of benzene in Copenhagen: "rstly, the emission from tra$c and secondly, dispersion due to wind speed. The general level of exposure to benzene and home concentrations of benzene were strongly correlated with the outdoor level of benzene, which indicated that tra$c is an important source for indoor concentrations of benzene and for the exposure to benzene.
Benzene from traffic Fuel content and ambient air concentrations
2000
The measurements of benzene showed very clear decreasing trends in the air concentrations and the emissions since 1994. At the same time the measurements of CO and NOx also showed a decreasing trend, but not so strong as for benzene. The general decreasing trend is explained by the increasing number of petrol vehicles with three way catalysts, 60-70% in 1999. The very steep decreasing trend for benzene at the beginning of the period from 1994 was explained by the combination of more catalyst vehicles and reduced benzene content in Danish petrol. The total amount of aromatics in petrol, including toluene, increased only weakly. The analyses of air concentrations were confirmed by analyses of petrol sold in Denmark. The concentration of benzene at Jagtvej in Copenhagen is still in 1998 above the expected new EU limit value, 5 μg/m as annual average. However, the reduced content of benzene in petrol from 1998 and the increasing number of vehicles with catalysts will probably lead to co...
Intake fraction distributions for benzene from vehicles in the Helsinki metropolitan area
Atmospheric Environment, 2009
The intake fraction (iF) gives a measure of the portion of a source's emissions that is inhaled by an exposed population over a defined period of time. This study examines spatial and population-based iF distributions of a known human carcinogen, benzene, from a ubiquitous urban source, local vehicular traffic, in the Helsinki Metropolitan Area using three computational methods. The first method uses the EXPAND model (EXPosure to Air pollution, especially to Nitrogen Dioxide and particulate matter), which incorporates spatial and temporal information on population activity patterns as well as urban-scale and street canyon dispersion models to predict spatial population exposure distributions. The second method uses data from the personal monitoring study EXPOLIS (Air Pollution Exposure Distributions of Adult Urban Populations in Europe) to estimate the intake fractions for individuals in the study. The third method, a one-compartment box model provides estimates within an order-of-magnitude or better for non-reactive agents in an urban area. Population intake fractions are higher using the personal monitoring data method (median iF 30 per million, mean iF 39 per million) compared with the spatial model (annual mean iF 10 per million) and the box model (median iF 4 per million, mean iF 7 per million). In particular, this study presents detailed intake fraction distributions on several different levels (spatial, individual, and generic) for the same urban area.
Heliyon, 2019
Benzene is a proven carcinogen. Its synergistic action with other pollutants can damage different components of the biosphere. Literature comparing the air quality standards of benzene, its monitoring methods and global concentrations are sparse. This study compiles the worldwide available air quality standards for benzene and highlights the importance of strict and uniform standards all over the world. It was found that out of the 193 United Nation member states, only 53 countries, including the European Union member states, have ambient air quality standard for benzene. Even where standards were available, in most cases, they were not protective of public health. An extensive literature review was conducted to compile the available monitoring and analysis methods for benzene, and found that the most preferred method, i.e, analyzing by Gas Chromatography and Mass spectroscopy is not cost effective and not suitable for real-time continuous monitoring. The study compared the concentrations of benzene in the indoor and outdoor air reported from different countries. Though the higher concentrations of benzene noticed in the survey were mostly from Asian countries, both in the case of indoor and outdoor air, the concentrations were not statistically different across the various continents. Based on the analyzed data, the average benzene level in the ambient air of Asian countries (371 μg/m 3) was approximately 3.5 times higher than the indoor benzene levels (111 μg/m 3). Similarly, the outdoor to the indoor ratio of benzene level in European and North American Countries were found to be 1.2 and 7.7, respectively. This compilation will help the policymakers to include/revise the standards for benzene in future air quality guideline amendments.
Population exposure to benzene: One day cross-sections in six European cities
Atmospheric Environment, 2006
This paper describes the experimental methodology and basic results of the PEOPLE project (Population Exposure to Air Pollutants in Europe). Simultaneous diffusive measurements of outdoor, indoor and human exposure benzene concentrations were made during one day campaigns. Six cities were assessed, namely: Brussels and Lisbon (). In general, human exposure to benzene was higher than concentrations reported at urban background monitoring sites. Traffic was the dominant source of benzene in all the six cities that were studied. The highest exposure levels from the commuting groups were car users. The control group, with no influence from commuting or smoking, reported concentrations closer to the background level of the city. The smoking group had the highest level of exposure. The level of exposure of school children was similar to that of the commuting groups. Indoor locations that were influenced by smoking sources, or with free access to busy streets, reported relatively high concentrations. The highest indoor concentrations were measured in bars and inside motor vehicles. When considering the six cities together, a linear relationship was evident between ambient levels and human exposure. Daily median values of human exposure for non-smoking commuters were 1.5 times the level of urban background and 0.6 times the maximum outdoor value (hotspot).
Annali dell'Istituto superiore di sanità, 2010
In step with the need to develop statistical procedures to manage small-size environmental samples, in this work we have used concentration values of benzene (C6H6), concurrently detected by seven outdoor and indoor monitoring stations over 12 000 minutes, in order to assess the representativeness of collected data and the impact of the pollutant on indoor environment. Clearly, the former issue is strictly connected to sampling-site geometry, which proves critical to correctly retrieving information from analysis of pollutants of sanitary interest. Therefore, according to current criteria for network-planning, single stations have been interpreted as nodes of a set of adjoining triangles; then, a) node pairs have been taken into account in order to estimate pollutant stationarity on triangle sides, as well as b) node triplets, to statistically associate data from air-monitoring with the corresponding territory area, and c) node sextuplets, to assess the impact probability of the out...
Indoor and outdoor personal exposure to benzene in Athens, Greece
Science of the total environment, 2005
Objective: To evaluate the exposure of urban inhabitants to atmospheric benzene in Athens, Greece. Methods: Fifty non-smoker volunteers from selected occupational groups and their homes were monitored by passive air samplers for six 5-day periods during a year. An activity diary was completed during each sampling period and relevant data were collected by a questionnaire at the beginning of the study. Additional data on urban levels on benzene were also available. Results: Average benzene home and personal levels in six monitoring campaigns varied between 6.0-13.4 and 13.1-24.6 lg/ m 3 , respectively. Urban levels varied between 15.4 and 27.9 lg/m 3 with an annual mean of 20.4 lg/m 3 . Wind speed seems to determine largely home levels and personal exposure. Proximity to busy road holds also an important influence on indoor benzene levels. Adjusted for seasonal or climate variation, other significant prognostic factors of personal exposure were home levels, total time spent outdoors and transportation mean. Time spent outdoors explains the strong relationship between occupation and personal levels of exposure. Wind had similar effect in clearing indoor and urban pollution in Athens; lessen personal exposure and home levels about 2-2.5 lg/m 3 per 1 m/s increase in speed. Conclusions: Factors related to climate (use of non-absorbent materials for wall and floor covering and frequent ventilation) might be one explanation for homes' high clearing rate. Our exposure pattern, which suggests that outdoors work give the greater contribution to benzene exposure of Athens citizens, is uncommon in northern towns of Europe. Policy makers have to take in account these differences in establishing guidelines for ambient benzene exposure. D
Air Quality Atmosphere Health, 2011
Benzene is classified as carcinogenic compound which is emitted mainly from cars. In this study, benzene was measured at various sites in Nibong Tebal (urban, suburban, town, and rural) of different traffic volume, and traffic counts were performed simultaneously. Monitoring was carried out during the morning and afternoon traffic peaks. The aim of this study is to monitor benzene concentration at several development sites with different traffic flow. The monitoring was done by using indoor air quality meter. The results obtained from monitoring show that the mean concentrations of benzene ranged from 54.7 ppb in the suburban area to 115.1 ppb in the town area. Multiple linear regression analysis correlated the benzene concentrations with traffic volume, temperature, humidity, and time of monitoring as predictors. The results show that R 2 of the model was 0.97 in Taman Cowin site, and it was 0.47 in Taman Nibong Tebal Jaya site. Negative correlation was found between benzene concentration and temperature while there was positive correlation with humidity being found through the study. Pearson's correlation indicates that gasoline vehicular exhaust could be the major source of benzene. The UK Air Quality Standards stipulated that the annual mean of ambient benzene should not exceed 5 ppb or 16.25 μg/m 3 . The results show that the current concentrations of benzene exceeded the permissible limits set by the UK standards.