The Corrosion Inhibition of Montmorillonite Nanoclay for Steel in Acidic Solution (original) (raw)
Related papers
Montmorillonite as corrosion protective pigment
Corrosion Science, 2018
MMTs are not inert; rather, they may act as smart pigments with complementary properties being activated as the coating is damped with corrosive medium. Beyond barrier properties, montmorillonites (MMTs) may improve coatings performance by active corrosion inhibition. Also, regulation of pH suggests smart anticorrosive action of hydrophylic MMTs for acid media. Organophilization treatments of MMTs may have collateral effects on coatings performance. Benefits may depend on testing conditions, MMT type and content.
Journal of the Taiwan Institute of Chemical Engineers, 2018
An organic/inorganic couple based on halloysite nanotubes (HNT) was employed to provide active corrosion protection on mild steel in 3.5 wt% sodium chloride solution. The HNT impregnated with green aqueous extract of Basil (BNC) was used as active host of corrosion inhibitors. The chemical characterization of BNC was done by field emission-scanning electron microscopy (FE-SEM), Fourier transformation infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA). Also, the time-dependent release of corrosion inhibitors was confirmed through ultraviolet-visible spectroscopy (UV-vis). The significant corrosion inhibition efficiency of the active system (about 98%) was proved by electrochemical analyses. The synergistic effect based on formation of chelate between inhibitor molecules and Zn 2 + cations, leading to surface film formation, was proposed as the main mechanism for considerable long-term corrosion protection of bi-component system.
A comprehensive comparative study of some corrosion inhibitors using different techniques
Hybrid Advances, 2023
Corrosion is a serious problem in industry of metals particularly in the areas which possess high amount of moisture. Due to this reason scientists and researchers have been investigated several methods to overcome this issue. They have discovered many inhibitors to reduce the hazards of corrosion to metals. Throughout history many changes and developments have been done to increase the quality of these corrosion inhibitors. In this study some corrosion inhibitors from different works and researches have been analyzed through the comparisons of the practical data obtained from the techniques such as TEM, XPS and Langmuir adsorption isotherm. The inhibitors involved: Novel nitrogen doped carbon dots (NCDs), imidazole-citric acid-based carbon dots and Novel N-doped carbon dots (CDs) were synthesized via pyrolysis of ammonium citrate. The inhibitors, with various ratios, were applied to the surface of Q235 carbon steel in various intervals of times in the presence absence of hydrochloric acid solution. All of results reveal to improvement and reducing the corrosion on metals. The inhibitors have shown physical and chemical adsorption based on the Langmuir adsorption model. The reason behind selecting specific researches in this work was to analyze the progress of the carbon dot-based corrosion inhibitors and assisting researchers and industries to choose the most effective scientific approach.
Synthesis of green corrosion inhibitor for mild steel in acidic environment
Indian Chemical Engineer, 2019
The inhibitive potential of Mondia whittei roots extract (MWE) on corrosion of Mild Steel coupons in 0.5 M HCl solution was investigated by weight loss, depth of attack and surface analysis. Effect of various parameters, such as concentration of MWE, immersion time and temperature on inhibition efficiency was studied. The identification of the constituents of MWE and characteristics of the test solution and adsorbed film on the test coupon were evaluated by Gas Chromatography/Mass Spectrophotometer (GC-MS) and Fourier Transform Infra-Red (FTIR) Spectrophotometer. The surface morphology and topographical features of the corroded mild steels were done by the scanning electron microscope (SEM). The main constituents responsible for corrosion inhibition properties of MS were found to be guaiacol, vanillin, 9, 12octadecadienoic acid and phenol, 2, 6-dimethoxyl among many other components which contain C, H and O. A maximum corrosion inhibition efficiency of 89.47% was obtained with 1.0 g/L in 0.5M HCl at 60°C after 9 h and volumearea ratio of 40 mL/cm 2. Polarisation curves reveal that the inhibition efficiency according to depth of attack given by R a and R z increased with increasing inhibitor concentration, temperature, time and volumearea ratio.
Review: Eco-Friendly Corrosion Inhibitors on Mild Steel in Acidic Medium
IRJET, 2022
Eco friendly corrosion inhibitors were chosen for this review, and their corrosion inhibition tendency was examined. The inhibitory property of these inhibitors on mild steel (MS) in an acidic environment are being explored. It was determined the rate of corrosion by the applications of chemical and electrochemical systems. Corrosion inhibition rises with inhibition efficiency and decreases with temperature, according to these studies. In all of these papers, on mechanisms of adsorption and thermodynamics were explored. Scanning Electron Microscopic investigations were used to discuss surface morphology. Few academics have recently published theoretical studies such as quantum studies. In this paper, all of the works have been discussed.
Nano-composite as corrosion inhibitors for steel alloys in different corrosive media
The application of nanotechnology in the corrosion protection of metals has recently gained momentum; Environmental impact can improved by utilizing nanostructure particulates in corrosion inhibition, Nano composites have also proven to be an effective alternative to other hazardous and toxic compounds, the present article reports some of the preliminary investigations on the corrosion-resistance performance of Nano-composite.
2018
In this study, the effect of new corrosion inhibitor namely Pithecollobium Dulce (PCD) extract on the protection of mild steel (MS) in 3.5% sodium chloride (NaCl) and 1 M hydrochloric acid (HCl) solutions were investigated using weight loss measurements and electrochemical techniques. Weight loss method proved that a significant decrease in the corrosion rate of MS was observed in the presence of inhibitor. Electrochemical measurements showed that the inhibition efficiencies increased with increasing inhibitor concentration. The UV-Vis spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis were carried out to characterize the surface film.
International Journal of Corrosion and Scale Inhibition, 2019
A new benzylidene derivative, namely N-benzylidene-5-phenyl-1,3,4-thiadiazol-2-amine (BPTA), has been synthesized and instrumentally confirmed with Elemental Analysis (CHN), Nuclear Magnetic Resonance (NMR), and Fourier Transform Infrared Spectroscopy (FT-IR). Titanium Dioxide (TiO 2) nanoparticles (NPs) were synthesized and characterized by X-ray. The mutualistic complementary dependence of BPTA with TiO 2 nanoparticles as anti-corrosive inhibitor on mild steel (MS) in 1.0 M hydrochloric acid has been tested at various concentrations and various temperatures. The methodological work was achieved by gravimetric measurement methods complemented with surface analysis. The synthesized inhibitor concentrations were 0.1 mM to 0.5 mM and the temperatures ranging from 303-333 K. The BPTA with TiO 2-NP as a synergistic inhibitor becomes superior inhibitive effects with more than 96% inhibition competence of MS coupons in a harsh acidic medium. The efficiency of the inhibition improved with increasing BPTA content and also increase with the Synergistic effects of BPTA with TiO 2-NP. The excellent effectiveness was performed with the 0.5 mM concentration of BPTA and become higher with adding of TiO 2-NP rising to the maximum inhibition efficiency (IE). However, the inhibition efficacy declined as the temperature rises. Results of BPTA as corrosion inhibitor indicated the obedience of the adsorption of the inhibitor of mixed type on the surface of MS to Langmuir adsorption isotherm. It was found that the BPTA and performance depend on the Synergistic effects, concentrations of the TiO 2-NP and BPTA, in addition to the solution temperature. Nevertheless, the quantum calculations have confirmed the direct correlation of the electronic characteristics of BPTA with the corrosive inhibitive influence.
Mediterranean Journal of Chemistry
We report two new different synthesis strategies of an eco-friendly organic dye 3-oxo-3H-spiro[isobenzofuran-1,9'-xanthene]-3',6'-diyl diacetate. These methods were based on the reaction of fluorescein with acetic anhydride under different experimental conditions. The synthesized heterocyclic system obtained with excellent yield was characterized by FT-IR, 1H N.M.R., 13C N.M.R., and mass spectrometry. This reaction has also been studied theoretically using Gaussian 09 based on the DFT method at B3LYP/6-31G (d, p). The results obtained are in good correlation with those obtained experimentally. The inhibition behavior of the synthetic product has been studied using absorbance difference measurement, the percentage of inhibition efficiency attains 90% at 10-4M of NAR3 inhibitor. The surface analysis of mild steel was investigated using scanning electron microscopy (S.E.M.) and Energy Dispersive X-ray (E.D.X.) methods and show the adsorption behavior of inhibitor on the sur...
Development of new corrosion inhibitor tested on mild steel supported by electrochemical study
Results in Physics, 2018
Mild steel is a metal which is commonly used in industrials and manufacturing of equipment for most industries round the world. It is cheaper cost compared with the other metals and its durable, hard and easy-to-wear physical properties make it a major choice in the manufacture of equipment parts. The main problem through the uses of mild steel in industry is its resistance against corrosion, especially in acidic solutions. This case led to raise the cost of maintenance of equipment that used mild steel and as a result increased costs for the company. Organic corrosive inhibitors that also act as green chemicals, 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazolhave been synthesized. This inhibitor is tested as corrosion inhibitor on a mild steel sample MS in 1M hydrochloric acid solution (HCl) using electrochemical measurements test includes PD (Potentiodynamic), EIS (Electrochemical impedance spectroscopy), OCP (Open circuit potential) and EFM (electrochemical frequency modulation). The obtained results indicate that 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazol acts as a good corrosion inhibitor for mild steel sample in HCl solution with efficiency above 90%. Changes in the impedance parameters postulated adsorption on the mild steel specimens' surfaces of, which it going to the formation of protective coating layer. It also shows that 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazolcorrosion inhibitors are 2 effective in helping to reduce and slow down the corrosion process that occurs on mild steel surface in hydrochloric acid solution. Increase of corrosion inhibitor concentration provides a protective layer of mild steel. However, this protective layer becomes weak when the temperature of the solution increases.