EPR study of the radical polymerization of 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate (original) (raw)

Polymer, 2001

Abstract

The kinetics of the radical polymerization of 3-[tris(trimethylsilyloxy)silyl]propyl methacrylate was studied in benzene and dioxane/hexane solutions at different conditions of temperature, monomer and initiator concentrations by using ultraviolet and electron paramagnetic resonance spectroscopic techniques. The values of the ratios between the propagation rate constant and the square root of the termination rate constant (kp/kt1/2) were determined by UV spectroscopy by

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