Thermal degradation of poly(methyl methacrylate). 3. Polymer with head-to-head linkages (original) (raw)

Thermal degradation of poly(methyl methacrylate). 3. Polymer with head-to-head linkages

Macromolecules, 1989

Abstract

L'incorporation de liaisons «tete a tete» dans une chaine de PMMA reduit la temperature de degradation en facilitant la rupture homolytique de la chaine. Lorsque le degre de polymerisation du polymere est superieur a 200, cet effet est reduit par la recombinaison de cage

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