Direct C(sp³)−O Reductive Elimination of Olefin Oxides from Pt^IV-Oxetanes Prepared by Aerobic Oxidation of Pt^II Olefin Derivatives (Olefin = cis-Cyclooctene, Norbornene) (original) (raw)

Journal of the American Chemical Society, 2008

Abstract

ABSTRACT Internal olefins, cis-cyclooctene and norbornene, react with (dpms)Pt-II(OH)(ethene) in water to produce Pt-II oxetanes (norbornene) or hydroxo olefin complexes (cis-cyclooctene); both produce anionic Pt-II oxetanes in basic solutions; their subsequent aerobic oxidation cleanly furnishes corresponding Pt-II oxetanes that undergo direct C(sp(3))-O reductive elimination of olefin oxides in various solvents and in the solid-state that is unprecedented for Pt-IV.

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Direct C(sp3)−O Reductive Elimination of Olefin Oxides from PtIV-Oxetanes Prepared by Aerobic Oxidation of PtII Olefin Derivatives (Olefin = cis-Cyclooctene, Norbornene) (original) (raw)

Direct C(sp³)−O Reductive Elimination of Olefin Oxides from Pt^IV-Oxetanes Prepared by Aerobic Oxidation of Pt^II Olefin Derivatives (Olefin = cis-Cyclooctene, Norbornene) (original) (raw)