Experimental and theoretical investigation of first hyperpolarizability in aminophenols (original) (raw)

Journal of Molecular Structure, 2008

Abstract

This work reports theoretical and experimental studies on the first hyperpolarizability (β) of aminophenols, evaluating the influence of the NH2 group position relative to the OH group on the hyperpolarizability. A new extension of hyper-Rayleigh scattering technique using picosecond pulse trains was employed to obtain the experimental absolute values of (β). The theoretical static β(0) values were calculated using AM1

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