Second virial coefficients of alkali vapours (original) (raw)
Second virial coefficients of alkali vapours
Molecular Physics, 1976
Abstract
The virial equation of state is generally written in the form ... PV/RT = 1 + B( T)/V + C( T)/V 2 +..., ... B (~)(T) = B e (i)(T) + Bq (~)(T). ... Here Bc(i)(T) is the classical second virial coefficient and Bq(i)(T) is a relatively small correction term due to quantum effects. For atoms or ...
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