Dielectric and electrical properties of PANI composite films (original) (raw)

2014 North African Workshop on Dielectic Materials for Photovoltaic Systems (NAWDMPV), 2014

Abstract

The present work deals with the preparation of films from polymeric core-shell particles. Our approach is based on the chemical polymerization of a very thin layer of polyaniline (PANI) around particles of transparent polymers (polyamide and polystyrene). Films are then obtained by dissolving the two type synthesized core-shell powders in dichloromethane and m-Cresol respectively. Electrical properties were investigated using a dielectric relaxation spectrometer. Both composite films exhibited a percolative behaviour and a well established dc conductivity for high PANI concentration related to the conductive properties of the PANI spanning clusters. This property allows using such films in semi-conductive applications. For polyamide films, high dielectric constants were obtained at 5 wt. % of PANI allowing their use as high k-dielectrics compatibles with organic printed circuit boards.

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