Structural investigations on green culms and charcoal of Bambusa multiplex (original) (raw)
Related papers
Techno (Jurnal Fakultas Teknik, Universitas Muhammadiyah Purwokerto), 2021
Activated carbon also known as activated charcoal is a common term for carbon materials, which comprises charcoal. Activated carbon has a good adsorption capacity against gases and pollutants in liquids because of its wide surface. The material used in this research was tropical black bamboo, with the variation of particle size -10+20 mesh, -20+40 mesh, -40+60 mesh and -60+80 mesh. There are 2 processes to produce activated carbon, i.e. carbonation and activation. In this research, the carbonation is set at 380°C in 1 hour. Then, each size of carbon was activated by H3PO4 9.8% along 24 hours. The analysis conducted were moisture content, ash content, iodine number, and functional group analysis using Fourier Transform Infrared Spectroscopy (FTIR). The smaller particle size, the more pores will be produced and it caused the surface area higher. The results showed that variation of particle size had effect on the characterization and quality of activated carbon, where moisture conten...
Revista Brasileira de Energias Renováveis
The search for sustainable fuels has become important for the development of energy generation in balance with the environment. Brazil has climatic conditions and a vast territory for the production of forest biomass. The research produced in the laboratory determines the gravimetric yield, upper calorific value, percentages of fixed carbon, volatile and ashes of the charcoals of bamboo species: Bambusa vulgaris var vittatta, Dendrocalamus asper and Phyllostachys pubescens. For the carbonization process, small pieces of bamboo were obtained, were dried in the stove at 100°C for 24 hours, the dried mass was weighed and added in a carbonizer heated to 150°C for 45 minutes, heated to 180°C for 45 minutes and heated to 210°C for 30 minutes, this charcoal was then cooled and weighed to calculate the gravimetric yield. The samples were pulverized in a pot mill, the upper calorific value in a calorimeter was determined. The volatile, fixed carbon and ash contents were determined according...
IOP Conference Series: Materials Science and Engineering, 2019
Activated carbon is a versatile porous material that widely applied to purify, deodorize, decolorize, remove or reduce some gases harmful constituents and storage of gas. For different application different characteristics of activated carbon is required. This paper concerns to find out the characteristics of activated carbons derived from tabah bamboo (Gigantochloc nigrociliata) that physically activated with different activation holding time. Prepared tabah bamboo was carbonized by heating up to the temperature of 800 °C for two hours. The char produced was powdered and then activated physically by heating up to 800 °C, soaked at that temperature during each 1, 1.5 and 2 hours under 100 mL/min N2flow. Activated carbons manufactured were characterized by proximate and ultimate analyses and SEM observation. The results show that the highest fix carbon (82.52%) and lowest ash (5.91 %) was obtained at 1 hour soaking time with moisture and volatile contents were 3.56% and 8.00 % respec...
2019
This research aims to determine the effect of activation temperature the crystal structure of activated charcoal. The material used activated charcoal bunches (Arengga Pinnate Merr). The process of making activated charcoal divided into two, namely the carbonization stage at a temperature of 250- 400 oC and the activation stage at a temperature variation of 600 - 800 ̊C. To find the crystal structure, the sample characterized by X-Ray Diffraction. The results of analysis the dominant elements diamond before activation with a percentage of 90.2% and an orthorhombic crystalline structure, where the lattice parameter a = 4.12700 Å; b = 4.93700 Å; c = 4.81900 Å. Peak Carbon has a hexagonal crystal structure in all temperature variations. Peak Graphite an orthorhombic crystal structure and at a temperature of 700 oC a hexagonal crystal structure formed. Therefore, giving temperature variations the activated charcoal of the bunches affects the structure of the formed Crystal. Wherein incr...
Journal of Molecular Structure, 2021
Here, carbon nanotubes (CNTs), carbon nanochains (CNCs) and carbon quantum dots (CQDs) were synthesized using charcoal powder in a mixture of concentrated H 2 SO 4 /HNO 3 acidic solvent with the help of NaOH. It is demonstrated that the lower alkaline or basic environment is favourable to enhance the effectiveness for the formation of CNTs and CNCs whereas the higher alkaline or basic environment is effective for the formation of CQDs. The Raman measurements confirm the graphitic nature of the samples and also approve the structural changes in charcoal powder upon chemical treatment. The TEM measurement provides an evidence for the formation of CNTs, CNCs and CQDs from charcoal power as a result of varying pH of the reaction medium. The FTIR and XPS results further supports the chemical modification of charcoal powder by approving the appropriate bonding composition. The optical absorption behavior of the prepared samples was carried out with the help of UV-Vis. absorption spectra. The TG analysis shows the effect of chemical treatment on the thermal stability of the samples. Moreover, we have tried to provide an explanation to the experimental observations. This study not only provides insightful direction to synthesize CNTs, CNCs and CQDs in a facile way but also could lead to new developments in charcoal chemistries.
Charcoal properties of Malaysian bamboo charcoal carbonized at 750 °C
BioResources
The carbonization of five Malaysian bamboo species, namely Bambusa vulgaris, Dendrocalamus asper, Gigantochloa hasskarliana, Gigantochloa levis, and Schizostachyum brachycladum, was conducted to investigate the charcoal properties and compare the quality of bamboo charcoal produced based on proximate analysis. Carbonization at 750 °C using a modified Iwasaki steel drum kiln was successful for all bamboo species. Bamboo morphological features varied and basic density increased with culm height. A charcoal yield of more than 30% was recorded in all bamboo species except for B. vulgaris and D. asper. Charcoals made from D. asper and G. hasskarliana could serve as the alternative raw material for charcoal production in charcoal industries due to their low moisture, low volatile matter, low ash, and high fixed carbon content. All species had a mean gross calorific value between 24.4 and 29.2 MJ/kg. Among different culm sections, the bottom section produced the best quality charcoal. The ...
International Journal of Applied Pharmaceutics, 2019
Objective: Rice straw is an agricultural waste material which has a negative impact on the environmental. This study’s aim was to prepare high-performance rice straw activated charcoal (RSAC) for cosmetic and pharmaceutical applications using chemical activation technique.Methods: Three cultivars of rice straw namely Dok Mali 105 (DM105), RD6 and Niaw San-Pah-Tawng were selected to determine the lignin content. The rice straw with the highest lignin content was selected to produce rice straw activated charcoal. The particle of size 20, 40 and 60 mesh was carbonized at 200, 300, 400, 500 and 600 °C for 1, 2, and 3 h. The obtained charcoal with the highest iodine number was then refluxed using potassium hydroxide and phosphoric acid as an activating agent in the ratios of 1:10 w/v at 70, 80, 90, and 100 °C for 2 (KOH) and 3 (H3PO4) h. The adsorption ability on iodine, methylene blue, acetaminophen, and aflatoxin B1 was investigated. Additionally, pore structure, pore size, and surface...
Journal of Chemical Engineering and Industrial Biotechnology
Bamboo has a very rapid growth rate and has been considered a promising non-wood biomass material that has the potential as a feedstock for charcoal production. This study was carried out to elucidate the physico-chemical and energy characteristic of bamboo charcoal produced from two (2) different species which were Aur Kuning Bamboo and Beting Bamboo. Each bamboo was carbonized at a temperature of 300 to 400oC for a duration of two hours. It was found that the density and volatile matter content of bamboo charcoal have decreased, while the ash content, fixed carbon (FC) content and calorific value (CV) have increased after being converted into charcoal. The results show that Aur Kuning Bamboo has good quality bamboo charcoal in comparison with Beting Bamboo in terms of its FC and CV content. Based on the average value, the FC (82.10%) and CV of Aur Kuning Bamboo (27.23%) were higher than FC (70.42%) and CV (26.05%) of Beting Bamboo with 16.59% (FC) and 4.53% (CV) different. Statist...
Scholars international journal of chemistry and material sciences, 2022
Activated Carbons (ACs) were prepared from jute stick charcoal by chemical activation using H 2 SO 4 and H 3 PO 4 ranging temperature from 300 0 C to 350 0. The activated carbons and charcoal prepared from jute sticks were characterized by evaluating the surface chemistry, structural features and surface morphology. The properties of the carbons were characterized by Scanning Electron Microscope (SEM), Brunauer-Emmett-Teller (BET), X-Ray Diffraction (XRD) and the FT-IR method. The jute sticks were converted to activated carbons with the highest surface area (135-245m 2 /g) and largest mesopores volume (0.14-0.16 cm 3 /g). The FT-IR spectra exhibited that the pyrolysis of jute stick resulted in the release of aliphatic and O-containing functional groups by thermal effect. However, the release of functional groups is effect of chemical reaction in the ZnCl 2 , H 3 PO 4 , and H 2 SO 4 activation process. A honeycomb carbon structure in activated carbon was formed as observed on SEM images. Although charcoal and activated carbon were prepared at 300 0 C to 350 0 , the activated carbon exhibited much lower Raman sensitivity due to the formation of condensed aromatic ring systems. Due to high surface area and high porous structure with abundance of functional groups, the activated carbon prepared from jute sticks charcoal absorbed molecules with much higher than those of other activated carbon.