Total Synthesis of (−)-Phomoarcherin C (original) (raw)

Journal of Organic Chemistry, 2019

Abstract

A full account on the first total synthesis of chroman meroterpenoid, (-)-phomoarcherin C has been described. Key synthetic transformations include phenyl boronic acid mediated 6π-electrocyclization reaction, a stereospecific hydrogenation driven by thermodynamic, conformational stability of the product and regioselective formylation. The strategy employed is considerably short, atom economical and can open the doors to provide access to various other natural products of the kind.

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